A Hybrid Ring‐Opening Metathesis Polymerization Catalyst Based on an Engineered Variant of the β‐Barrel Protein FhuA

A β‐barrel protein hybrid catalyst was prepared by covalently anchoring a Grubbs–Hoveyda type olefin metathesis catalyst at a single accessible cysteine amino acid in the barrel interior of a variant of β‐barrel transmembrane protein ferric hydroxamate uptake protein component A (FhuA). Activity of this hybrid catalyst type was demonstrated by ring‐opening metathesis polymerization of a 7‐oxanorbornene derivative in aqueous solution.     

Numerical simulation of transpiration cooling through porous material

Transpiration cooling using ceramic matrix composite materials is an innovative concept for cooling rocket thrust chambers. The coolant (air) is driven through the porous material by a pressure difference between the coolant reservoir and the turbulent hot gas flow. The effectiveness of such cooling strategies relies on a proper choice of the involved process parameters such as injection pressure, blowing ratios, and material structure parameters, to name only a few. In view of the limited experimental access to the subtle processes occurring at the interface between hot gas flow and porous medium, reliable and accurate simulations become an increasingly important design tool. In order to facilitate such numerical simulations for a carbon/carbon material mounted in the side wall of a hot gas channel that are able to capture a spatially varying interplay between the hot gas flow and the coolant at the interface, we formulate a model for the porous medium flow of Darcy–Forchheimer type. A finite‐element solver for the corresponding porous medium flow is presented and coupled with a finite‐volume solver for the compressible Reynolds‐averaged Navier–Stokes equations. The two‐dimensional and three‐dimensional results at Mach number Ma = 0.5 and hot gas temperature T_HG=540 K for different blowing ratios are compared with experimental data. Copyright © 2014 John Wiley & Sons, Ltd.     

Populationsmodelle

Zusammenfassung  Wie werden mathematische Modelle gebildet und wie kann dieser Entstehungsprozess so dargestellt werden, dass er von Schülern im Mathematikunterricht nacherlebt und bisweilen sogar selbst?ndig durchgeführt werden kann? Der vorliegende Artikel gibt auf diese Fragen exemplarisch Antworten. Anhand einer Population unter dem Einfluss intraspezifischer Konkurrenz werden die einzelnen Stationen bei der Entwicklung eines passenden mathematischen Modells vorgestellt. Der Weg von der Motivation und Problemstellung zum Konzeptmodell, das Einbeziehen von Computersimulationen und die mathematische Analyse werden pr?sentiert und diskutiert. Für die Analyse reichen Mittel der Schulmathematik aus. Eine direkte unterrichtliche Umsetzung wird nicht angeboten, jedoch werden M?glichkeiten hierfür skizziert.     

Micro- and nano-thermal analysis applied to multi-layered biaxially-oriented polypropylene films

In this paper we compare Wollaston and silicon probes for localized thermal analysis measurements (LTA) on biaxially oriented polypropylene (BOPP) films. Up till now, no real comparison was reported in literature between the different transition temperatures measured using Wollaston and silicon probes. Using different types of probes for studying the same material proves to be very interesting. Using the Wollaston probe, the thermal properties and thickness of a 1 μm thick skin layer can be determined by through-thickness local thermal analysis measurements. The improved resolution of the silicon probes, enables the measurement of thermal properties of individual layers in a cross-sectioned film, even for layers of only 1 μm thickness. Based on the results, the silicon probes seem to be more sensitive toward the start of the melting process, since the silicon probe already penetrates at lower temperature, as compared to the Wollaston probes. This sensitivity can be exploited for studying the effect of variations in thermal history between or within samples.     

Recent results on hadron spectroscopy from BES

The BES-Ⅲ Detector is a very versatile multipurpose device located at the Institute of High Energy Physics （IHEP） in Beijing, China. Concerning the physics program it ties stringently up to the past BES and BES-Ⅱ experiments. Since start of the data taking in the middle of 2008 the accumulated dataset of 200.10^6 J/ψ events and 100.10^6 ψ＇ events already exceeds the world data on these resonances. In addition to studies of the charmonium systems the data offers great opportunity for investigations in the light hadron sector. In detail it will be reported about the confirmation of the enhancement in pp invariant mass in radiative J/ψ decays, the search for decays Y（2175） → K＊0K＊0, observation of a charged K^± in K^±π^0 and observation of a new excited baryon N＊（2065） decaying to pπ^0 and charged onjugate. The first result is based on data taken by BES-Ⅱ and BES-Ⅲ, the latter three on data collected by BES-Ⅱ only.     

Phase Behavior in Blends of Ethylene Oxide–Propylene Oxide Copolymer and Poly(ether sulfone) Studied by Modulated-Temperature DSC and NMR Relaxometry

The state diagram of a blend consisting of a copolymer containing ethylene oxide and propylene oxide, P(EO-ran-PO), and poly(ether sulfone), PES, is constructed by using modulated-temperature differential scanning calorimetry (MTDSC), T₂ NMR relaxometry, and light scattering. The apparent heat capacity signal in MTDSC is used for the characterization of polymer miscibility and morphology development. T₂ NMR relaxometry is used to detect the onset of phase separation, which is in good agreement with the onset of phase separation in the apparent heat capacity from MTDSC and the cloud-point temperature as determined from light scattering. The coexistence curve can be constructed from T₂ values at various temperatures by using a few blends with well-chosen compositions. These T₂ values also allow the detection of the boundary between the demixing zones with and without interference of partial vitrification and are in good agreement with stepwise quasi-isothermal MTDSC heat capacity measurements. Important interphases are detected in the heterogeneous P(EO-ran-PO)/PES blends.