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A. N. Nesmeyanov V. A. Sazonova V. N. Postnov N. M. Shchepalina V. V. Stekol'nikov 《Russian Chemical Bulletin》1978,27(9):1921-1923
Conclusions The reactions of the tetraphenylborates of some phenylogs of -ferrocenylcarbonium ions with piperidine were studied.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2175–2177, September, 1978. 相似文献
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A. N. Nesmeyanov I. B. Zlotina M. A. Khomutov I. F. Leshcheva N. E. Kolobova K. N. Anisimov 《Russian Chemical Bulletin》1977,26(3):642-643
Conclusions The cis-trans isomers of the vinylic fluorine substitution product were isolated and characterized when Na[5-C5H5Fe(CO)2] is reacted with ethyl perfluoromethacrylate.Deceased.The authors express their gratitude to E. M. Rokhlin and U. Utebaev for supplying the ethyl perfluoromethacrylate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 705–706, March, 1977. 相似文献
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A.N. Nesmeyanov E.V. Leonova N.S. Kochetkova A.I. Malkova 《Journal of organometallic chemistry》1975,96(2):271-274
A method is described for the preparation of 1,2-diacetylferrocene, in which ferrocene is acetylated with acetyl chloride in the presence of AlCl3 in methylene chloride. Addition of the ferrocene to an excess of the acetylation mixture over a prolonged period was found to be most favourable. The 1,2-diacetylferrocene formed proved to be free of the 1,3-isomer. It was reduced with LiAlH4/AlCl3 to 1,2-diethylferrocene. 相似文献
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A.N. Nesmeyanov V.V. Krivykh P.V. Petrovskii V.S. Kaganovich M.I. Rybinskaya 《Journal of organometallic chemistry》1978,162(3):323-342
Irradiation of alkenylarene tricarbonyl-chromium, -molybdenum, and -tungsten compounds in which the double bond is separated from the arene moiety by a two- or three-atom bridge results in intramolecular cyclization to give stable chelate alkenylarenedicarbonylmetal complexes. Chelate complexes containing four-atom bridges have low stabilities, and those with monoatomic bridges were not formed at all. Irradiation of styrenetricarbonyl-chromium and -molybdenum leads to dinuclear tricarbonylmetal—dicarbonylmetal complexes. The chelate complexes obtained have been studied by IR, proton NMR, and 13C NMR spectroscopy. The electron density distributions and the stereochemistry of the complexes are discussed. With nonsymmetric arenes, diastereoisomers are formed; the predominant isomers have been isolated in the pure form. According to the proton NMR data the double bond in alkenylarenechromium chelates is parallel of nearly parallel to the arene ring plane. 相似文献
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Conclusions The synthesis of 1,1-(acetoxy)chloromercuryferrocene, di-1(1-acetoxyferrocenyl)mercury, 1,1-(methoxy)chloromercuryferrocene, and di-1-(1-methoxyferrocenyl)mercury from ferrocenylboric acids was described.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2574–2575, November, 1967. 相似文献
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A.N. Nesmeyanov D.V. Zagorevskii Yu.S. Nekrasov V.F. Sizoi V.M. Postnov A.M. Baran E.I. Klimova 《Journal of organometallic chemistry》1979,169(1):77-81
The main processes of the electron-impact induced fragmentation of the ferrocenyl and cymantrenyl analogues of chalcones RCOCH=CHR′ (R, R′ = C5H4FeC5H5, C5H4Mn(CO)3, or aryl) involve a cleavage of the metalligand bond. A “chalcone” mode of fragmentation is weakly pronounced, due to the fact that the positive charge is localized preferably on the metal atom. 相似文献