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1.
Mohammad Ali Karimi Zarchi Mojgan Nejabat 《Journal of the Iranian Chemical Society》2012,9(5):767-774
Alkyl halides are efficiently converted to their corresponding S-alkyl thioacetates under mild and nonaqueous conditions, using polymer-supported sodium thioacetate as a new polymeric reagent at room temperature in high yields and purity. The spent polymeric reagent can be removed quantitatively by filtration and pure products can be obtained by evaporation of the solvent. The spent polymeric reagent can be regenerated and reused several times without its activity changing appreciably. 相似文献
2.
3.
Deformed photon-added entangled squeezed vacuum and one-photon states: Entanglement,polarization, and nonclassical properties 下载免费PDF全文
In this paper, after a brief review on the entangled squeezed states, we produce a new class of the continuous-variabletype entangled states, namely, deformed photon-added entangled squeezed states. These states are obtained via the iterated action of the f-deformed creation operator A = f(n)aon the entangled squeezed states. In the continuation, by studying the criteria such as the degree of entanglement, quantum polarization as well as sub-Poissonian photon statistics, the twomode correlation function, one-mode and two-mode squeezing, we investigate the nonclassical behaviors of the introduced states in detail by choosing a particular f-deformation function. It is revealed that the above-mentioned physical properties can be affected and so may be tuned by justifying the excitation number, after choosing a nonlinearity function. Finally, to generate the introduced states, we propose a theoretical scheme using the nonlinear Jaynes–Cummings model. 相似文献
4.
Cascade parametric amplification in a regular domain structure is examined theoretically taking the variations in phase of
all the interacting waves in a dissipative medium into account. Analytic expressions are obtained for the conversion efficiency
of the laser energy with low-frequency pumping. The dependence of the parametric amplification efficiency on the number of
layers is given. Ways of increasing the frequency conversion efficiency are discussed. The presence of a nonzero input intensity
at the sum frequency is found to cause a nonlinear increase in the high-frequency signal at the output of the structure. As
the losses of the interacting waves increase, both the frequency conversion efficiency and the optimum domain length decrease. 相似文献
5.
Z. Karimi 《Applied Surface Science》2010,256(14):4473-9
SBA-15 mesoporous silica is synthesized using triblock copolymer P123 surfactant and chemically modified by aminopropyl, thiol, ammonium and sulfonic acid functional groups. Functionalization is performed via post synthesize method using 3-aminopropyltriethoxysilane (APTES) or 3-mercatopropyl trimethoxysilane (MPTMS) precursor. The as synthesized mesoporous systems are applied for immobilization of cyanocobalamine. Functionalization effectively improves sorption properties of the supports, while different functional groups exert different effects. The organic-inorganic mesoporous materials are characterized via X-ray diffraction (XRD), nitrogen adsorption and desorption, transmission electron microscopy (TEM), FT-IR and inductively coupled plasma-optical emission (ICP). The newly synthesized systems exhibit high catalytic activity for heterogeneous epoxidation of cyclooctene in presence of hydrogen peroxide. Reaction conditions are optimized, effect of functional groups on performance of the catalysts is taken into consideration and reusability of the designed heterogeneous systems is studied. Systems with chemically modified supports are shown to be more efficient and stable catalysts however; chemical nature of functional groups plays a crucial role. 相似文献
6.
A. A. Karimi Zarchi N. Mokhtari M. Arfan T. Rehman M. Ali M. Amini R. Faridi Majidi A. R. Shahverdi 《Applied Physics A: Materials Science & Processing》2011,103(2):349-353
In this study a sunlight-induced method for rapid synthesis of silver nanoparticles using an ethanol extract of Andrachnea chordifolia is described. The silver nitrate solutions (1 mM) containing the ethanol extract of Andrachnea chordifolia were irradiated by both sunlight radiation and by sunlight radiation passed through different colored filters (red, yellow
or green). The smallest size of silver nanoparticles was obtained when a silver ion solution was irradiated for 5 minutes
by direct sunlight radiation. Further examination of the shape and size and of the surface chemistry of these biogenic silver
nanoparticles, which were prepared under sunlight radiation, was carried out using transmission electron microscopy and infrared
spectroscopy, respectively. Transmission electron microscopy images show spherical particles with an average size of 3.4 nm.
Hydroxyl residues were also detected on the surface of these biogenic silver nanoparticles fabricated using plant extract
of Andrachnea chordifolia under sunlight radiation. Our study on the reduction of silver ions by this plant extract in darkness shows that the synthesis
process can take place under dark conditions at much longer incubations (48 hours). Larger silver polydispersed nanoparticles
ranging in size from 3 to 30 nm were obtained when the silver ions were treated with the ethanol extract of Andrachnea chordifolia under dark conditions for 48 hours. 相似文献
7.
The optical properties of the asymmetric double semi-parabolic quantum wells (DSPQWs) are investigated numerically for typical GaAs/AlxGa1−xAs. Optical properties are obtained using the compact density matrix approach. In this work, effects of the structure parameters such as the barrier width and the well widths on the optical properties of the asymmetric DSPQWs are investigated. The results show that the linear and nonlinear optical properties of asymmetric DSPQW are non-monotonic functions of these structure parameters. The behavior of the refractive index changes of asymmetric DSPQW with the variation of the barrier width is different substantially with that of symmetric DSPQW. Results reveal that the resonant peak values of the total absorption coefficient of asymmetric DSPQW is usually greater than that of symmetric DSPQW. Our calculations also show that the total absorption coefficient of asymmetric DSPQW is larger than that of asymmetric double square quantum well. 相似文献
8.
A growing interest exists currently in the analysis of time series by the complex network theory. Here we present a simple and quick way for mapping time series to complex networks. Using a simple rule allows us to transform time series into a textual sequence then we divide it into words with fixed size. Distinct words are nodes of the network, and we have complete control on the network scale by adjusting the word size. Two nodes are linked if their associated words co-occur in sequence. We show that the network topological measures quantify the persistence and the long range correlations in fractional Brownian processes. For a particular word size we assume some relations between the topological measures and the Hurst exponent which characterised the persistence in fractional Brownian processes. 相似文献
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10.
M. Karimi N. Granpayeh M.K. Morraveg Farshi 《Applied physics. B, Lasers and optics》2004,78(3-4):387-396
A rhodamine-B-doped polymer optical fiber amplifier (RBDPOFA) has been successfully fabricated and tested. In this paper, all parameters affecting the gain of the RBDPOFA are recognized. The time-dependent and time-independent rate equations are solved. By using Runge–Kutta and finite-element methods, different conditions are described and fluctuations of the fiber laser are analyzed. From the time-dependent rate equations, the gain and level-density variations with time can be predicted. These fiber amplifiers have unstable conditions. In experiments, the decay of dye dopants in the high pump power regime has been observed. For example, in a high pump power rhodamine-B is converted from the zwitterion isomer to the colorless lactone isomer [1]. Therefore, for complete coincidence of theoretical and experimental results, this effect must be included in the analysis, which is however beyond the scope of this paper and will be discussed in the near future. PACS 42.60.Da; 42.81.Wg; 31.15.Fx; 33.80.-b; 42.55.WdAn erratum to this article can be found at 相似文献