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1.
2.
The paper provides significant simplifications and extensions of results obtained by Gorsich, Genton, and Strang (J. Multivariate Anal. 80 (2002) 138) on the structure of spatial design matrices. These are the matrices implicitly defined by quadratic forms that arise naturally in modelling intrinsically stationary and isotropic spatial processes. We give concise structural formulae for these matrices, and simple generating functions for them. The generating functions provide formulae for the cumulants of the quadratic forms of interest when the process is Gaussian, second-order stationary and isotropic. We use these to study the statistical properties of the associated quadratic forms, in particular those of the classical variogram estimator, under several assumptions about the actual variogram. 相似文献
3.
It was argued by Schramm and Smirnov that the critical site percolation exploration path on the triangular lattice converges
in distribution to the trace of chordal SLE
6. We provide here a detailed proof, which relies on Smirnov’s theorem that crossing probabilities have a conformally invariant
scaling limit (given by Cardy’s formula). The version of convergence to SLE
6 that we prove suffices for the Smirnov–Werner derivation of certain critical percolation crossing exponents and for our analysis
of the critical percolation full scaling limit as a process of continuum nonsimple loops.
Research of Charles M.Newman was partially supported by the US NSF under grants DMS-01-04278 and DMS-06-06696. 相似文献
4.
A one-dimensional model of filtration through a saturated porous medium with a mutual action between the solid matrix and
the flow is investigated. The substances removed from the porous soil are both particles transported by the liquid flow and
substances which diffuse in the fluid.
Received June 30, 1997 相似文献
5.
Ionic elastomers based on carboxylated nitrile rubber (XNBR) crosslinked with magnesium oxide (OMg) and filled with layered nanoclays have been prepared. Two types of nanofillers were employed: a commercial one (Cloisite 15 A) and the other prepared in our laboratory (BCA-ODA). The properties of raw and vulcanized compounds have been studied in order to elucidate the effect of layered nanoclays. X-ray diffraction analysis shows that during compounding and crosslinking the macromolecular chains of rubber were intercalated in a commercial nanofiller, whilst our nanoclay was exfoliated. However, this fact does not affect the properties of compounds homogeneously. Vulcanization parameters, Mooney viscosity and decay and rheological properties were affected depending on the filler type. Mechanical properties were not significantly varied, but glass transition temperature and ionic transition temperature were shifted in comparison with those of the unfilled compound. 相似文献
6.
Angel L. Esteban Maria P. Galache Francisco Mora Ernesto Diez Jesus San Fabian 《Journal of computational chemistry》1989,10(7):887-895
An equation is formulated on the basis of theoretical INDO/FPT calculations which describes the angular dependence of the propanic long-range coupling constant 4JMeH in substituted HCCCH3 fragments. This equation is a truncated Fourier series in the torsion angle ?, HCCMe, which takes into account the dependence of the Fourier coefficients on the bond angle θ, CCMe. The substituent effects are assumed to be additive. Some parameters in the equation may be obtained from the 4JMeH couplings in propane and neopentane derivatives. The calculated effect upon 4JMeH of changes in the bond angle θ is significant and it seems to be in part the cause of some effects which have been attributed to conformational dependence. 相似文献
7.
Bagno A Butts C Chiappe C D'Amico F Lord JC Pieraccini D Rastrelli F 《Organic & biomolecular chemistry》2005,3(9):1624-1630
Low viscosity, high density trihalide-based 1-n-butyl-3-methylimidazolium ionic liquids have been prepared and characterised. Key physical properties (density, conductivity, melting point, refractive index, surface tension and diffusion coefficient) of the ionic liquids have been determined and are compared with those of other 1,3-dialkylimidazolium molten salts. The relationship between anion identity and the physical properties of the ionic liquids under investigation is discussed. 相似文献
8.
Polo F Antonello S Formaggio F Toniolo C Maran F 《Journal of the American Chemical Society》2005,127(2):492-493
The rate constant of intramolecular electron transfer through oligopeptides based on the alpha-aminoisobutyric acid residue was determined as a function of the peptide length and found to depend weakly on the donor-acceptor separation. By measuring the electron-transfer activation energy and estimating the energy gap between donor and bridge, we were able to discard the electron hopping mechanism. 相似文献
9.
10.
Mateja
ikovec Mladen Franko Federico G. Cruz Sidney A. Katz 《Analytica chimica acta》1996,330(2-3):245-250
The applicability of thermal lens spectrometry (TLS) for quantification and routine determination of hexavalent chromium was investigated by using a collinear dual beam thermal lens spectrometer. In aqueous solutions the LOD of 0.1 μg l−1 was obtained for Cr(VI) by using 160 mW laser power. The performance of the technique was verified by the determination of hexavalent chromium in standard reference water samples (NIST SRM 1643a and NIST SRM 1643c) and comparing the results for Cr(VI) in CCA (Cr, Cu, As)-treated timber extracts to concentrations obtained by atomic absorption spectrometry (AAS). Good agreement between the TLS results and reported values for Cr(VI) in SRMs as well as AAS results for Cr(VI) in CCA-treated timbers confirmed that TLS is a reliable and accurate analytical technique applicable for the determination of Cr(VI) in aqueous solutions at concentration levels 0.5–100 μg l−1. 相似文献