首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   558篇
  免费   9篇
化学   316篇
晶体学   19篇
力学   14篇
数学   87篇
物理学   131篇
  2023年   1篇
  2022年   1篇
  2021年   9篇
  2020年   13篇
  2019年   12篇
  2018年   15篇
  2017年   12篇
  2016年   15篇
  2015年   13篇
  2014年   23篇
  2013年   34篇
  2012年   35篇
  2011年   44篇
  2010年   41篇
  2009年   34篇
  2008年   43篇
  2007年   34篇
  2006年   31篇
  2005年   28篇
  2004年   14篇
  2003年   15篇
  2002年   7篇
  2001年   6篇
  2000年   10篇
  1999年   4篇
  1998年   4篇
  1997年   5篇
  1996年   5篇
  1995年   5篇
  1994年   6篇
  1993年   1篇
  1992年   4篇
  1991年   2篇
  1990年   2篇
  1989年   4篇
  1987年   6篇
  1986年   2篇
  1985年   4篇
  1984年   4篇
  1983年   1篇
  1981年   3篇
  1980年   7篇
  1979年   1篇
  1978年   2篇
  1977年   1篇
  1976年   1篇
  1934年   1篇
  1930年   2篇
排序方式: 共有567条查询结果,搜索用时 15 毫秒
1.
2.
Correspondence is established between sigma models, minimal surfaces and the Monge–Ampére equation. The Lax pairs of the minimality condition of the minimal surfaces and the Monge–Ampére equations are given. Existence of infinitely many nonlocal conservation laws is shown and some Bäcklund transformations are also given.  相似文献   
3.
We extend the previously found accelerated Kerr-Schild metrics for Einstein-Maxwell-null dust and Einstein-Born-Infeld-null dust equations to the cases including the cosmological constant. This way we obtain the generalization of the charged de Sitter metrics in static space-times. We also give a generalization of the zero acceleration limit of our previous Einstein-Maxwell and Einstein-Born-Infeld solutions.  相似文献   
4.
On a sequence of embedded nonuniform grids, chains of embedded spaces of minimal splines (not necessarily polynomial) are constructed. The wavelet decomposition is given. The basis wavelets are compactly supported and admit simple analytic representation. The corresponding decomposition and reconstruction formulas are derived. The variety of spaces under consideration is identified with the variety of complete sequences of points of the direct product of an interval and a projective plane. Bibliography: 20 titles. __________ Translated from Problemy Matematicheskogo Analiza, No. 35, 2007, pp. 15–31  相似文献   
5.
6.
12 , 169 (1987). Reasonably good agreements in the peak output power and laser efficiency have been achieved. Model calculations also predict that an efficiency as high as 2.7% can be obtained once the conditions of the above-mentioned experiments have been optimized. From the consideration that the skin depth effectively limits the absorption length of the microwave pumping and hence the excitable volume, it is concluded that high input power densities (>2 MW/cm3) and higher gas pressures (between 3 and 10 atm) are the preferable conditions to achieve higher efficiency. Preliminary calculations on CCl4 containing XeCl gas mixtures show that improvement in laser efficiency by several folds may be achieved as a result of the higher intrinsic efficiency of excimer formation. Received: 23 September 1996 / Revised version: 25 March 1997  相似文献   
7.
8.
The synthesis and thermal bromination of octahydropentalene was studied. The reaction afforded 1a,3a,4b,6b-tetrabromo-1,2,3,4,5,6-hexahydropentalene (14) with remarkable regio- and stereospecificity. The structure of the product was determined by 1H and 13C NMR data and single X-ray structural analysis. The treatment of octahydropentalene with tenfold bromine gave the octabromopentalene derivative. The formation mechanism of the products is discussed.  相似文献   
9.
Treatment of 3-bromo-6,7-benzobicyclo [3.2.1] octa-2,3-diene (9) with potassium tert.-butoxide produces the strained bicyclic allene (10) which is trapped by 1,3-diphenylbenzo[c]furan (DBI) to give five isomeric cycloadducts. In the absence of DBI, allene (10) gave rise to enol ether (18) by addition of tert.-butanol.  相似文献   
10.
[reaction: see text] endo- and exo-2,3,4,7-tetrahydro-1H-1,4-methanobenzocycloheptene-7-carboxylic acid ethyl esters have been synthesized, and their Diels-Alder cycloaddition reactions with maleic anhydride, dimethyl acetylenedicarboxylate and singlet oxygen have been investigated. The X-ray analysis of four adducts indicated the pyramidalization of the central double bond. Density functional theory calculations on the isolated products and model compounds showed excellent agreement between the experimental and theoretical determined butterfly angles. Furthermore, it has been shown that a cyclopropyl group fused to [2.2.2] system decreases significantly the degree of the pyramidalization which is attributed to the steric interactions between the cyclopropyl group and ethano bridge of the norbornene systems. Due to the instability of the bicyclic endoperoxides, their X-ray analysis could not be carried out. DFT calculations on model compounds showed increased bending in the case of the product obtained by the addition of singlet oxygen to endo-2,3,4,7-tetrahydro-1H-1,4-methanobenzocycloheptene-7-carboxylic acid ethyl ester.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号