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In this paper dry reforming of methane (DRM) was carried out over nanocrystalline MgAl2O4-supported Ni catalysts with various Ni loadings. Nanocrystalline MgAl2O4 spinel with high specific surface area was synthesized by a co-precipitation method with the addition of pluronic P123 triblock copolymer as surfactant, and employed as catalyst support. The prepared samples were characterized by X-ray diffraction (XRD), N2 adsorption, H2 chemisorption, temperature-programmed reduction (TPR), temperature-programmed oxidation (TPO), temperature- programmed desorption (TPD) and transmission and scanning electron microscopies (TEM, SEM) techniques. The obtained results showed that the catalyst support has a nanocrystalline structure (crystal size: about 5 nm) with a high specific surface area (175 m2 g-1) and a mesoporous structure. Increasing in nickel content decreased the specific surface area and nickel dispersion. The prepared catalysts showed high catalytic activity and stability during the reaction. SEM analysis revealed that whisker type carbon deposited over the spent catalysts and increasing in nickel loading increased the amount of deposited carbon. The nickel catalyst with 7 wt% of nickel showed the highest catalytic activity. 相似文献
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Meshkani Fereshteh Golesorkh Sayyede Fateme Rezaei Mehran Andache Mahmood 《Research on Chemical Intermediates》2017,43(1):545-559
Research on Chemical Intermediates - Mesoporous MgAl2O4 nanopowders were synthesized via the homogenous precipitation method and employed as a support for Ni catalysts in the dry reforming... 相似文献
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MgO-modified Ni/Al2O3 catalysts with different Ni loadings were prepared and employed in dry reforming of methane (DRM). The effect of Ni loadings on the activity and coke formation of Ni/MgO-A1203 catalysts were investigated. The synthesized catalysts were characterized by XRD, N2 adsorption-desorption, SEM, TPO and TPR techniques. The obtained results showed that increasing nickel loading decreased the BET surface area and increased the catalytic activity and amount of deposited carbon. In addition, the effect of gas hourly space velocity (GHSV) and feed ratio were studied. 相似文献
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Mohammad Hossein Aboonasr Shiraz Mehran Rezaei Fereshteh Meshkani 《Research on Chemical Intermediates》2016,42(8):6627-6642
Mesoporous nano-crystalline γ-Al2O3 with high surface area prepared by a microemulsion (ME) method was employed as carrier for nickel catalysts in dry reforming of methane for syngas production. The structural properties of the catalysts were characterized by X-ray diffraction, Brunauer–Emmett–Teller surface area analysis, temperature programmed reduction and oxidation and scanning electron microscopy techniques. Microemulsion showed it to be a promising way for the production of nano-crystalline aluminum oxide, and the nickel catalysts prepared with this support have significant features and properties to use in the dry reforming reaction. The results revealed that the prepared γ-Al2O3 exhibited a nano-crystalline structure (crystal size: c.4.8 nm) with a high specific surface area (308 m2 g?1). In addition, the catalysts with different nickel contents exhibited high catalytic activity in the dry reforming reaction. The results also showed that an increase in Ni loading from 5 to 15 wt% caused a decrease in the specific surface area and nickel dispersion. 相似文献
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S. Yaser Samadi L. Billard M. R. Meshkani A. Khodadadi 《Computational Statistics》2017,32(3):1191-1212
With contemporary data collection capacity, data sets containing large numbers of different multivariate time series relating to a common entity (e.g., fMRI, financial stocks) are becoming more prevalent. One pervasive question is whether or not there are patterns or groups of series within the larger data set (e.g., disease patterns in brain scans, mining stocks may be internally similar but themselves may be distinct from banking stocks). There is a relatively large body of literature centered on clustering methods for univariate and multivariate time series, though most do not utilize the time dependencies inherent to time series. This paper develops an exploratory data methodology which in addition to the time dependencies, utilizes the dependency information between S series themselves as well as the dependency information between p variables within the series simultaneously while still retaining the distinctiveness of the two types of variables. This is achieved by combining the principles of both canonical correlation analysis and principal component analysis for time series to obtain a new type of covariance/correlation matrix for a principal component analysis to produce a so-called “principal component time series”. The results are illustrated on two data sets. 相似文献
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CO2 reforming of methane (CDRM) was carried out over MgO supported Ni catalysts with various Ni loadings. The preparation of MgO supported Ni catalysts via surfactant-assisted precipitation method led to the formation of a nanocrystalline carrier for nickel catalysts. The synthesized samples were characterized by XRD, N2 adsorption-desorption, H2 chemisorption, TPR, TPO and SEM techniques. It was found that the high catalytic activity and stability of the prepared catalysts could be attributable to high dispersion of reduced Ni species and basicity of support surface. In addition, the effect of feed ratio, nickel loading and GHSV on the catalytic performance of CDRM over the catalysts were investigated. 相似文献
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Ghiassee Mojtaba Rezaei Mehran Meshkani Fereshteh Mobini Sajad 《Research on Chemical Intermediates》2019,45(9):4501-4515
Research on Chemical Intermediates - The MnCo2O4 powders were prepared using a coprecipitation method and employed in low temperature CO oxidation. The preparation parameters in the coprecipitation... 相似文献