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1.
The influence of different referencing methods on the accuracy of δ13C value measurement of ethanol fuel by gas chromatography/combustion/isotope ratio mass spectrometry 下载免费PDF全文
2.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
3.
Mariano J. Valderrama 《商业与工业应用随机模型》1991,7(1):93-106
Alternative procedures for representing a stochastic signal as a denumerable series with uncorrelated terms are developed. The study includes considerations about parametric rescaling and its repercussions on the orthogonal expansion, as well as numerical techniques for approaching such an expansion. In addition, applications to the Gaussian characterization of stochastic signals, filtering and stochastic modelling are treated. 相似文献
4.
Aminonaphthols are easily transformed into a variety of 1- and 2-naphthyl piperazines using a sequence of diazotization, iodide substitution and Pd(0) catalyzed coupling reactions. 相似文献
5.
Marcos Almeida Bezerra Sérgio Mitihiro do Nascimento Maêda Eliane Padua Oliveira Maria de Fátima Batista de Carvalho Ricardo Erthal Santelli 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. 相似文献
6.
Joaquin Barbera Anne-Marie Levelut Mercedes Marcos Pilar Romero Jose Luis Serrano 《Liquid crystals》1991,10(1):119-126
We present a comparative study of various metallomesogenic complexes, using X-ray diffraction methods. For a given ligand linked to different metal atoms (Cu, Ni, VO), the nature of this central atom influences mainly the magnetic susceptibilities of the mesophases. With different ligands, which keep the close neighbourhood of the metal atom unchanged, the apparent length of the mesogenic unit is longer for short ligands than for longer ones. This unexpected behaviour is qualitatively well explained by taking into account the global shape of the different complexes. 相似文献
7.
Carlos E. Alciaturi Thais Montero Carlos De La Cruz Marcos E. Escobar 《Analytica chimica acta》1997,340(1-3):233-240
Reduction of the representation of infrared spectra from coal samples by osculating polynomials of degree nine is discussed. The reduced representation contains polynomial coefficients of order zero to four. Mathematical models of the original spectra are obtained by linear combination of the coefficients. These compressed models are statistically correlated to coal properties, namely, volatile matter, fixed carbon, ash content, heating value, hydrogen, carbon, sulphur, nitrogen, and maximum vitrinite reflectance, and the results are compared with those previously obtained from second derivatives of the same spectra. The use of compressed data, while giving slightly better correlations for some of the properties, has the advantage of requiring less computational time. 相似文献
8.
We prove global existence of solutions to the continuous nonhomogeneous Smoluchowski equation for coagulation rates satisfying a more general structure condition than the Galkin–Tupchiev monotony hypothesis considered in (Ph. Laurençot, S. Mischler, Arch. Rational Mech. Anal. 162 (1) (2002) 45–99). The Smoluchowski coagulation rate fulfils this condition as well as some rates which vanish on the diagonal. Under the condition of positivity of the coagulation rate outside of the diagonal we prove that solutions tend to 0 in the large time asymptotic. These results depend on a new estimate from below for the dissipation rate of the Lp-norm, p>1. To cite this article: S. Mischler, M. Rodriguez Ricard, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
9.
The Gaussian property of the Brownian bridge is characterized as an application of Ramachandran's theorem in terms of the independence of the random variables that appear in the Karhunen-Loéve expansion of the process. A reference about the construction of the Brownian bridge by means of functional transformations is also included. 相似文献
10.
Marcos F. de Campos Marília Emura Fernando J.G. Landgraf 《Journal of magnetism and magnetic materials》2006
Electrical steels, when submitted to operation, present continuous decrease of their magnetic properties, depending on the carbon content. This effect is attributed to the increase of the size of carbides, a process also known as coarsening or Ostwald Ripening. Loss separation can offer a better understanding of this phenomenon. Experimental results show that all effect of aging is inside the hysteresis loss component, with the excess losses unaffected. The carbon content in electrical steels should be less than 25 ppm to avoid magnetic aging. 相似文献