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Ahmad Alshammari Naif Alarifi Marzook Alshammari Manzar Sohail Rashid Altamimi 《Journal of Saudi Chemical Society》2019,23(7):999-1005
The development of base metal catalysts for industrially important reactions continues to be an important goal of catalysis research. Herein, the effects of pyrolysis temperature on the textural, structural, surface, magnetics properties and catalytic properties of silica-supported nickel nanoparticles (NiNPs) were thoroughly investigated. Mono-dispersed NiNPs encapsulated in graphitic shells were first successfully obtained and were characterized using a variety of methods such as BET surface area measurement, CO-pulse chemisorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (HR-TEM), and superconducting quantum interference device (SQUID) measurement. The findings showed that all catalysts’ properties were considerably altered with change in pyrolysis temperature. Hydrogenation of diphenylacetylene was then selected as the model reaction for the evaluation of the catalytic performance of the graphitic-shelled NiNPs. After testing, pyrolysis of a nickel at 800 °C (catalyst A) displayed tremendous activity and selectivity to produce >94% of stilbene with selectivities of 99% for the Z-isomer. 相似文献
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Nanoparticles of organosilane-based nitrite ionic liquid immobilized on silica, 1-butyl-3-methylimidazolium nitrite, and 1-(3-trimethoxysilylpropyl)-3-methylimidazolium nitrite were used as effective reagents for the preparation of benzotriazole derivatives from 1,2-diaminobenzenes at room temperature under mild solvent-free conditions. These ionic liquids play as nitrosonium sources in this procedure.1,2-Diaminobenzene derivatives have been treated with ionic liquids to give the related diaminobenzenes in very good to excellent yields in short reaction times.
Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the full experimental and spectral details. 相似文献
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We report on room temperature ferromagnetism in C-doped ZnO thin films prepared by electron beam evaporation. Magnetization, Hall effect, X-ray photoemission spectroscopy (XPS) and X-ray diffraction studies have been conducted to investigate the source and nature of ferromagnetism in C-doped ZnO. The samples were observed to have n-type conduction with the carrier concentration increasing with C doping. XPS does not give any evidence for C substituted at the O site, and is more consistent with the formation of C-O bonds and with the presence of C primarily in the +4 state. It is suggested that the ferromagnetism originates in the development of Zn vacancies that are stabilized due to the incorporation of C in a high valence state (C4+). 相似文献
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Mohammad Fallahian Behzad Pourabbas Mehdi Sharif Kamran Froutani Mehrnoosh Mahmoodian Mahdi Mohammadizadeh 《Polymer Science Series B》2017,59(3):308-319
In this study polypyrrole (PPy) nanoparticles were deposited as a thin film on the modified surface of polyethyleneterephthalate (PET) by in situ chemical polymerization in the presence of sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (DBSNa) and mixture of them as the surfactant. The surface of PET was modified by KOH before deposition and was investigated for conductivity and adhesion of PPy nanoparticles to PET. Resulting conductive flexible films were characterized by UV–Vis spectroscopy, fieldemission scanning electron microscopy, contact angle measurements and four-point-probe technique for conductivity. Direct morphological observation (FESEM) and electrical measurements indicated that the morphology, conductivity and the nature of deposited PPy films depend on surfactant, surface modification of PET and monomer concentration. In optimized process condition, uniform conductive films of PPy were obtained with good adhesion to PET. 相似文献
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A two-fold multi-set triple system is a collection of triples chosen, possibly with repetitions, from av-set in such a way that each pair (whether distinct or not) occurs precisely two times. For instance the triplex, x, y (which we shall write asxxy) contains the pairxx once and the pairxy twice. Such a design has v(v + l)/3 blocks, and a necessary and sufficient condition for existence is thatv = 0 or 2 (mod 3) and y≥5. The design is called simple if it contains no repeated blocks. Let I2(v) denote the set of non-negative integerss such that there exist two simple two-fold multi-set triple systems of orderv with preciselys blocks in common. In this paper we determine I2(v) for all admissiblev. 相似文献
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Md. Rajibul Akanda Manzar Sohail Md. Abdul Aziz Abdel‐Nasser Kawde 《Electroanalysis》2016,28(3):408-424
Pencil graphite electrodes (PGEs) have several advantages over other carbon‐based or commercial metal electrodes, including widespread availability, very low cost, and ease of modification. To make the best use of PGEs in electroanalysis, significant recent advances in the development of different nanomaterial‐PGEs have been observed. The literature published up to mid‐2015 is summarized in the present review, with a focus on the various methodologies used to readily modify graphite pencil electrodes using nanomaterials. This review also touches on the surface characterization of these electrodes and their potential applications in a variety of electrochemical detection applications. The review outlines the scope for further research in this area and discusses the importance of surface modifications of conventional PGE electrodes using nanomaterials or a combination of nanomaterials and electroactive polymers. 相似文献
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Sangsu Park Seungjae Jung Manzar Siddik Minseok Jo Jubong Park Seonghyun Kim Wootae Lee Jungho Shin Daeseok Lee Godeuni Choi Jiyong Woo Euijun Cha Byoung Hun Lee Hyunsang Hwang 《固体物理学:研究快报》2012,6(11):454-456
We propose a selector‐less Pr0.7Ca0.3MnO3 (PCMO) based resistive‐switching RAM (RRAM) for high‐density cross‐point memory array applications. First, we investigate the inhomogeneous barrier with an effective barrier height (Φeff), i.e., self‐formed Schottky barrier. In addition, a scalable 4F2 selector‐less cross‐point 1 kb RRAM array has been successfully fabricated, demonstrating set, reset, and read operation for high cell efficiency and high‐density memory applications. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Aimen Zafar Shaan Bibi Jaffri Manzar Sohail 《Phosphorus, sulfur, and silicon and the related elements》2021,196(1):36-46
Abstract This work reports the first investigation on the physical vapor deposition of thin films of tin sulfide doped lead sulfide (SnS:PbS). In-situ synthesis route using diethyldithiocarbamate (DTC) ligand was adopted for SnS-DTC, PbS-DTC and SnS:PbS-DTC complex formation. PbS-DTC and SnS:PbS-DTC expressed an average crystallite size of 30.98 and 29.74?nm, respectively shown by X-ray diffraction (XRD) analysis. A face centered cubic geometry was revealed from XRD. Ultraviolet visible spectrophotometry expressed a direct and indirect band gap of 3.4 and 3.2?eV, respectively for SnS:PbS-DTC. A smooth morphology with presence of larger agglomerated particles was disclosed by scanning electron microscopy for SnS:PbS-DTC thin films with 615?nm thickness. SnS:PbS-DTC thin films expressed remarkable electrochemical behavior explored via cyclic voltammetry, linear sweep voltammetry and chronoamperometry showing an improvement in the photo-current response upon potential bias increment. The results of the current research indicated the potential of SnS:PbS-DTC thin films for utilization in different types of photovoltaic devices. 相似文献
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JETP Letters - A two-dimensional Wigner cluster (2DWC) with the number of electrons up to 200 in a parabolic potential well has been studied numerically and analytically. It has been shown that the... 相似文献