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1.
Zhong‐Zhen Yu Mingshu Yang Qingxin Zhang Chungui Zhao Yiu‐Wing Mai 《Journal of Polymer Science.Polymer Physics》2003,41(11):1234-1243
Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with an alkyl ammonium surfactant pretreated montmorillonite (MMT). The thermal stability of the organic MMT powders was measured by thermogravimetric analysis. The decomposition of the surfactant on the MMT occurred from 200 to 500 °C. The low onset decomposition temperature of the organic MMT is one shortcoming when it is used to prepare polymer nanocomposites at high melt‐compounding temperatures. To provide greater property enhancement and better thermal stability of the polymer/MMT nanocomposites, it is necessary to develop MMT modified with more thermally stable surfactants. The dispersion and spatial distribution of the organic MMT layers in the nylon‐66 matrix were characterized by X‐ray diffraction. The organic MMT layers were exfoliated but not randomly dispersed in the nylon‐66 matrix. A model was proposed to describe the spatial distribution of the organic MMT layers in an injection‐molded rectangular bar of nylon‐66/organic MMT nanocomposites. Most organic MMT layers were oriented in the injection‐molding direction. Layers near the four surfaces of the bar were parallel to their corresponding surfaces; whereas those in the bulk differed from the near‐surface layers and rotated themselves about the injection‐molding direction. The influence of the spatial distribution of the organic MMT on crystallization of nylon‐66 was also investigated. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1234–1243, 2003 相似文献
2.
Wing-Sum Cheung Patricia J.Y. Wong 《Journal of Mathematical Analysis and Applications》2007,329(2):851-869
We consider a system of focal boundary value problems where the nonlinearities may be singular in the independent variable and may also be singular in the dependent arguments. Using Schauder fixed point theorem, we establish criteria such that the system of boundary value problems has at least one fixed-sign solution. 相似文献
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In this paper, we establish some new nonlinear integral inequalities of the Gronwall–Bellman–Ou-Iang-type in two variables. These on the one hand generalizes and on the other hand furnish a handy tool for the study of qualitative as well as quantitative properties of solutions of differential equations. We illustrate this by applying our new results to certain boundary value problem. 相似文献
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Mary Cheung Alex B. Young Alex G. Harrison 《Journal of the American Society for Mass Spectrometry》1994,5(6):553-557
O? and OH? react with fatty acid methyl esters (FAMES) under chemical ionization conditions both as Bronsted bases to form [M - H]? and as nucleophiles to form the carboxylate ion RCOO?. O? shows a much greater tendency to react as a nucleophile than does OH?. The [M - H]? ions fragment by elimination of CH3OH, with unsaturation in certain positions in the fatty acid hydrocarbon chain promoting this elimination for unknown reasons. The reaction of O? and OH? with triacylglycerols leads to [M - H]?, characteristic of the molecular mass, and to carboxylate ions characteristic of the fatty acid(s) present in the lipid. The presence of the three ester functions in the lipids greatly enhances the formation of carboxylate ions compared to the FAMES. 相似文献
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A. A. Mak E. A. Viktorov O. A. Orlov V. I. Ustyugov 《Radiophysics and Quantum Electronics》2004,47(10-11):743-746
We present the results of experiments with a CW single-mode Nd:YAG laser, tunable in the vicinity of 1064 nm, with an intracavity narrow-band Cs 2 vapor saturable absorber. It is shown that the laser dynamics is determined by both the pump level and detuning of the laser frequency from the absorption-line center. 相似文献
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