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1.
Nakatsuji S Dobrosavljević V Tanasković D Minakata M Fukazawa H Maeno Y 《Physical review letters》2004,93(14):146401
By using a combination of detailed experimental studies and simple theoretical arguments, we identify a novel mechanism characterizing the hopping transport in the Mott insulating phase of Ca2-xSrxRuO4 near the metal-insulator transition. The hopping exponent alpha shows a systematic evolution from a value of alpha=1/2 deeper in the insulator to the conventional Mott value alpha=1/3 closer to the transition. This behavior, which we argue to be a universal feature of disordered Mott systems close to the metal-insulator transition, is shown to reflect the gradual emergence of disorder-induced localized electronic states populating the Mott-Hubbard gap. 相似文献
2.
Damascelli A Lu DH Shen KM Armitage NP Ronning F Feng DL Kim C Shen ZX Kimura T Tokura Y Mao ZQ Maeno Y 《Physical review letters》2000,85(24):5194-5197
The electronic structure of Sr2RuO4 is investigated by high angular resolution ARPES at several incident photon energies. We address the controversial issues of the Fermi surface (FS) topology and the van Hove singularity at the M point, showing that a surface state and the replica of the primary FS due to sqrt[2]xsqrt[2] surface reconstruction are responsible for previous conflicting interpretations. The FS thus determined by ARPES is consistent with the de Haas-van Alphen results, and it provides additional information on the detailed shape of the alpha, beta, and gamma sheets. 相似文献
3.
Dr. Chong Liu Hiroe Kubota Takehiro Amada Dr. Kenichi Kon Dr. Takashi Toyao Dr. Zen Maeno Dr. Kakuya Ueda Dr. Junya Ohyama Prof. Atsushi Satsuma Takuya Tanigawa Dr. Nao Tsunoji Prof. Tsuneji Sano Prof. Ken-ichi Shimizu 《ChemCatChem》2020,12(11):3050-3059
The selective catalytic reduction of NO with ammonia (NH3−SCR) catalyzed by Cu−CHA zeolites is thoroughly investigated using in situ spectroscopic experiments combined with on-line mass spectroscopy (MS) under steady-state NH3−SCR conditions and transient conditions for Cu(II)/Cu(I) redox cycles. Quantitative analysis of the in situ XANES spectra of Cu−CHA under steady-state conditions of NH3−SCR show that NH3-coordinated Cu(II) species is the dominant Cu species at low temperatures (100–150 °C). At higher temperatures, Cu(II) species and [Cu(NH3)2]+ complex coexist, possibly because the rate of the Cu(II)→Cu(I) reduction step is comparable to that of the Cu(I)→Cu(II) oxidation step. In situ XANES, IR/MS, and UV-vis/MS experiments on the reduction half cycle demonstrate that the reduction of Cu(II) species occurs via the reaction of NH3-liganded Cu(II) with NO to yield N2 and H2O. For the oxidation half cycle, in situ XANES experiments of Cu(I) oxidation in 10 % O2 at 200 °C indicate that an increased density in CHA zeolite exhibits a higher oxidation rate. In situ UV-vis experiments of Cu(I) reoxidation using different mixtures of oxidant feed gas demonstrate the key role of O2 in the oxidation cycle. It is suggested that the reoxidation of Cu(I) to Cu(II) species occurs with only O2 as the oxidant, and a high Cu density in CHA zeolite promotes SCR activity by enhancing the oxidative activation of Cu(I) to Cu(II) during the catalytic cycle. 相似文献
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5.
Nonequilibrium radiation phenomena behind strong shock waves in low-density air are observed by using a couple of CCD camera systems in a shock tube experiment. The simultaneous observation for total radiation and its spectral radiation is carried out in order to elucidate spaced-ependent contribution of an individual radiation spectrum to the total radiation intensity. The results are shown for the shock velocity range from 9.0 km/s to 12.1 km/s at the initial pressure 13.3 Pa. Wavelength range is selected from 300 nm to 445 nm to investigate mainly the contributions from UV radiation. It is found that the band spectra due to the molecular species N2+ and CN mainly contribute to the first-peak, while the spectra due to the atomic species O+ and N mainly contribute to the formation of the second-peak. It is also found that the Balmer series in H spectra strongly contributes to the second-peak. The radiation along the tube wall surfaces is composed of the same constituents as those around the tube axis as well as the spectra coming from the impurities. 相似文献
6.
Using a microwave cavity perturbation technique, we have succeeded in observing cyclotron resonances in the layered Perovskite superconductor Sr2RuO4. Three cyclotron masses are deduced, corresponding to mcγ=9.7me, mcβ=5.8me and mc=4.3 me. A comparison between these values and the effective masses deduced from other techniques provides us with a unique means of gauging the role of Coulomb correlations in the title compound. 相似文献
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8.
Yoshimune Nonomura Takaharu Fujii Yuichiro Arashi Taku Miura Takashi Maeno Kaoru Tashiro Yasuhisa Kamikawa Rie Monchi 《Colloids and surfaces. B, Biointerfaces》2009,69(2):1-267
Water has a unique touch as well as characteristic physical properties. However, nobody knows the real identity of its touch. Here, we show that water creates a stick-slip feel when a small amount is rubbed using fingertip on an artificial skin that mimics the structure of human skin. The results of frictional analyses predict that this stick-slip feel is caused by a drastic change in frictional resistance. The present result is valuable for biologists and robot engineers as well as cognitive scientists and tribologists, because it is a new example of stick-slip phenomena on biological surfaces. The tactile texture of this most familiar material could also be applied to consumer products or virtual reality systems. 相似文献
9.
For any finite Coxeter system (W,S) we construct a certain noncommutative algebra, the so-called bracket algebra, together with a family of commuting elements, the so-called Dunkl elements. The Dunkl elements conjecturally generate an algebra which is canonically isomorphic to the coinvariant algebra of the Coxeter group W. We prove this conjecture for classical Coxeter groups and I2(m). We define a “quantization” and a multiparameter deformation of our construction and show that for Lie groups of classical type and G2, the algebra generated by Dunkl’s elements in the quantized bracket algebra is canonically isomorphic to the small quantum cohomology ring of the corresponding flag variety, as described by B. Kim. For crystallographic Coxeter systems we define the so-called quantum Bruhat representation of the corresponding bracket algebra. We study in more detail the structure of the relations in Bn-, Dn- and G2-bracket algebras, and as an application, discover a Pieri-type formula in the Bn-bracket algebra. As a corollary, we obtain a Pieri-type formula for multiplication of an arbitrary Bn-Schubert class by some special ones. Our Pieri-type formula is a generalization of Pieri’s formulas obtained by A. Lascoux and M.-P. Schützenberger for flag varieties of type A. We also introduce a super-version of the bracket algebra together with a family of pairwise anticommutative elements, the so-called flat connections with constant coefficients, which describes “a noncommutative differential geometry on a finite Coxeter group” in the sense of S. Majid. 相似文献
10.
K. Yoshida F. Nakamura Y. Tanaka Y. Maeno T. Fujita 《Physica C: Superconductivity and its Applications》1994,230(3-4):371-377
A structural transition to a low-temperature tetragonal (TLT) phase occurs below Td2≈60 K in La2−xBaxCuO4 only around x=0.125, accompanied by sharp suppression of superconductivity. In this study we investigated the effects of partial substitution of smaller divalent cations for Ba2+ ions (Ba2+ > Sr2+ > Ca2+) on these anomalous low-temperature properties. The suppression of superconductivity is strongly affected by the appearance of the TLT phase for this carrier concentration. We also show that the variations of Td2 and Tc are quantitatively scaled by the averaged size of cations at the La site. This dependence can be interpreted as chemical effects acting effectively as applied pressure. We discuss how our observation is related to recent reports which claim that the TLT structure itself does not necessarily destroy the superconductivity. 相似文献