Universal nature of particle displacements close to glass and jamming transitions

We examine the structure of the distribution of single particle displacements (van Hove function) in a broad class of materials close to glass and jamming transitions. In a wide time window comprising structural relaxation, van Hove functions reflect the coexistence of slow and fast particles (dynamic heterogeneity). The tails of the distributions exhibit exponential, rather than Gaussian, decay. We argue that this behavior is universal in glassy materials and should be considered the analog, in space, of the stretched exponential decay of time correlation functions. We introduce a dynamical model that describes quantitatively numerical and experimental data in supercooled liquids, colloidal hard spheres, and granular materials. The tails of the distributions directly explain the decoupling between translational diffusion and structural relaxation observed in glassy materials.     

Laser–Induced Fluorescence Detection of Carbamates Traces in Water

The absorption and fluorescence spectra of carbaryl (CB), carbofuran (CF) and carbendazim (MBC) have been studied. Fluorescence lifetime and fluorescence quantum yields are also reported as well as the influence of pH, solvent and presence of humic acids on fluorescence. The limit of detection (LD) of the three compounds has been measured by direct analysis by laser-induced fluorescence (LIF) using a pulsed YAG laser with an Optical Parametric Oscillator (OPO) as excitation source and an Intensified Charged Coupled Device (ICCD) camera for the fluorescence detection. Instrumental LD found for CB, for MBC and for CF are respectively 4, 50 and 1000 ng L⁻¹. In tap water, the LD obtained is 800 ng L⁻¹ for MBC and 20,000 ng L⁻¹ for CF. For CB, the use of a time shift between excitation and emission allows to reach a LD of 20 ng L⁻¹ in tap water.     

Suppressed compressibility at large scale in jammed packings of size-disperse spheres

We analyze the large-scale structure and fluctuations of jammed packings of size-disperse spheres, produced in a granular experiment as well as numerically. While the structure factor of the packings reveals no unusual behavior for small wave vectors, the compressibility displays an anomalous linear dependence at low wave vectors and vanishes when q→0. We show that such behavior occurs because jammed packings of size-disperse spheres have no bulk fluctuations of the volume fraction and are thus hyperuniform, a property not observed experimentally before. Our results apply to arbitrary particle size distributions. For continuous distributions, we derive a perturbative expression for the compressibility that is accurate for polydispersity up to about 30%.     

Shearing a glassy material: numerical tests of nonequilibrium mode-coupling approaches and experimental proposals

The predictions of a nonequilibrium schematic mode-coupling theory developed to describe the nonlinear rheology of soft glassy materials have been numerically tested in a sheared binary Lennard-Jones mixture. In this Letter, we focus on the existence, behavior, and properties of an effective temperature T(eff) for the slow modes of the fluid, as defined from a generalized fluctuation-dissipation theorem. New, simple experimental protocols to access T(eff) are proposed, and one such experiment is numerically performed. Our results give strong support to the thermodynamic interpretation of T(eff) and make it experimentally accessible in a very direct way.     

Characterization of a sCMOS‐based high‐resolution imaging system

The detection system is a key part of any imaging station. Here the performance of the novel sCMOS‐based detection system installed at the ID17 biomedical beamline of the European Synchrotron Radiation Facility and dedicated to high‐resolution computed‐tomography imaging is analysed. The system consists of an X‐ray–visible‐light converter, a visible‐light optics and a PCO.Edge5.5 sCMOS detector. Measurements of the optical characteristics, the linearity of the system, the detection lag, the modulation transfer function, the normalized power spectrum, the detective quantum efficiency and the photon transfer curve are presented and discussed. The study was carried out at two different X‐ray energies (35 and 50 keV) using both 2× and 1× optical magnification systems. The final pixel size resulted in 3.1 and 6.2 µm, respectively. The measured characteristic parameters of the PCO.Edge5.5 are in good agreement with the manufacturer specifications. Fast imaging can be achieved using this detection system, but at the price of unavoidable losses in terms of image quality. The way in which the X‐ray beam inhomogeneity limited some of the performances of the system is also discussed.     

Comparison of the angular selectivity characteristics for an off-axis holographic storage system calculated by Born approximation and coupled-wave theory

The first Born approximation is applied to calculate the angular selectivity for different positions on the reconstructed image as a function of the object beam's optical axis angle theta(ob) and reference beam angle theta(rw) for a holographic data storage system that records the Fourier transform holograms in a medium with an infinite plane-wave reference beam. Results are compared with those calculated by the coupled-wave theory.     

Spectroscopic Properties and Laser Induced Fluorescence Determination of Some Endocrine Disrupting Compounds

This work presents spectroscopic properties of some Endocrine Disrupting Compounds (EDCs), frequently found in food and in natural water. Studied molecules belong to the groups of phenolic and phthalate EDCs. In a first part, we have examined their absorption and fluorescence properties. Fluorescence emission wavelengths are about 300 nm for phenolic compounds and 360 nm for phtalate compounds; main excitation wavelengths being comprised between 210 nm and 230 nm. Fluorescence lifetimes measured are short (about 4 ns) and the fluorescence quantum yield has been determined. In a second part, to avoid the time consuming solvent extraction step, an analytical application to evaluate the performance of a direct analysis by laser induced fluorescence spectroscopy of ECDs traces in tap water and in raw water is presented. Good detection limits have been obtained, i.e.: 0.35 μg.L⁻¹ of chlorophenol in tap water, which are always lower than the reported Predictive Non Efficient Concentration (PNEC).