全文获取类型
收费全文 | 12558篇 |
免费 | 2360篇 |
国内免费 | 2044篇 |
专业分类
化学 | 9074篇 |
晶体学 | 239篇 |
力学 | 793篇 |
综合类 | 176篇 |
数学 | 1296篇 |
物理学 | 5384篇 |
出版年
2024年 | 29篇 |
2023年 | 225篇 |
2022年 | 419篇 |
2021年 | 454篇 |
2020年 | 513篇 |
2019年 | 501篇 |
2018年 | 454篇 |
2017年 | 457篇 |
2016年 | 636篇 |
2015年 | 662篇 |
2014年 | 788篇 |
2013年 | 998篇 |
2012年 | 1238篇 |
2011年 | 1297篇 |
2010年 | 912篇 |
2009年 | 924篇 |
2008年 | 901篇 |
2007年 | 838篇 |
2006年 | 821篇 |
2005年 | 698篇 |
2004年 | 525篇 |
2003年 | 359篇 |
2002年 | 376篇 |
2001年 | 312篇 |
2000年 | 252篇 |
1999年 | 222篇 |
1998年 | 195篇 |
1997年 | 145篇 |
1996年 | 125篇 |
1995年 | 108篇 |
1994年 | 92篇 |
1993年 | 84篇 |
1992年 | 81篇 |
1991年 | 72篇 |
1990年 | 52篇 |
1989年 | 41篇 |
1988年 | 34篇 |
1987年 | 18篇 |
1986年 | 17篇 |
1985年 | 20篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1973年 | 4篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Ji-Dong Lou Chun-Ling Gao Li Li Zhi-Gang Fang 《Monatshefte für Chemie / Chemical Monthly》2006,41(10):1071-1074
A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate
supported on aluminum silicate at room temperature under solvent-free conditions and shaking is reported. 相似文献
2.
The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data. 相似文献
3.
4.
Wang Qing-Lun Zhao Bin Liao Dai-Zheng Yan Shi-Ping Cheng Peng Jiang Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer. 相似文献
5.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
6.
三种群食物链交错扩散模型的整体 总被引:1,自引:0,他引:1
本文应用能量估计方法和Gagliardo-Nirenberg型不等式证明了一类强耦合反应扩散系统整体解的存在性和一致有界性,该系统是带自扩散和交错扩散项的三种群Lotka-Volterra食物链模型.通过构造Lyapunov函数给出了该模型正平衡点全局渐近稳定的充分条件. 相似文献
7.
For vertical-cavity surface-emitting lasers (VCSELs) with polarization-rotated feedback, there exist several synchronization
types such as synchronizations between total powers and synchronizations between separate polarization modes. Based on the
two-mode rate equations, we study and compare numerically the performances of different synchronization types. Our results
show that three synchronization types exhibit good performances when their synchronization conditions are satisfied. They
are the complete synchronization between total powers, complete synchronization between x-polarized modes, and generalized synchronization between x-polarized and y-polarized modes. The former two types are sensitive to the injection rate and spontaneous emission, while the third type
is contrary. Synchronization type with the best performance may switch from one to another, with changing of injection rate
and spontaneous emission factor. 相似文献
8.
Bing Yong HSIE 《数学学报(英文版)》2006,22(2):507-514
This paper gives a p-adic analogue of the Mackey theory, which relates representations of a group of type G - H × t A to systems of imprimitivity. 相似文献
9.
We discuss the matrix model in a class of 11D time dependent supersymmetric backgrounds as obtained in [B. Chen, Phys. Lett. B 632 (2006) 393, hep-th/0508191]. We construct the matrix model action through the matrix regularization of the membrane action in the background. We show that the action is exact to all orders of fermionic coordinates. Furthermore we discuss the fuzzy sphere solutions in this background. 相似文献
10.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献