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排序方式: 共有145条查询结果,搜索用时 15 毫秒
1.
Laura Montanaro K. Belgacem P. Llewellyn F. Rouquerol F. Merlo Paola Palmero 《Journal of Thermal Analysis and Calorimetry》2007,88(3):789-793
Wet chemical synthesis of precursor oxide ceramics is a method to obtain small particulate powders. Such powders are far more
prone to ageing in air than more traditional precursors. Thermogravimetric analysis is used to highlight the species responsible
for the ageing of ceramic precursors. Indeed water and carbon dioxide are observed to evolve from aged powders. Ceramics obtained
from aged precursors can reach a very low final density with respect to the theoretical value. A large degree of the original
sintering properties can be recovered after washing the aged powders with ethanol in a basic medium. 相似文献
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Hydroxy-terminated polybutadiene/isophorone diisocyanate (HTPB/IPDI) polyurethane rubber which was aged in air at elevated temperatures has been studied by infrared microspectroscopy. Spectra were collected in transmission mode on microtomed samples. Analysis of sets of spectra taken across the sectioned material showed that most of the degradation occurred in the polybutadiene part of the polymer and that the urethane linkage was essentially unchanged. The trans isomer of the polybutadiene appears to be preferentially degraded compared with the vinyl isomer. The IR technique does not provide significant information about the cis isomer. The IR spectra indicated that likely degradation products included acids, esters, alcohols, and small amounts of other products containing a carbonyl functional group. Band area ratios, supported by a principal components analysis, were used to derive degradation profiles for the material. These profiles were steep-sided indicating an oxygen diffusion limited process. 相似文献
4.
Isotherms and differential enthalpies of adsorption are obtained for nitrogen at ambient temperature on monovalent (Li(+), Na(+), K(+)) and divalent (Ca(2+), Ba(2+), Sr(2+), Mn(2+)) substituted X-faujasite systems by microcalorimetry measurements. These experimental data are compared with those obtained by combining grand canonical Monte Carlo simulations and newly derived force fields for describing the interactions between the extra-framework cations and the adsorbates obtained from a simple model based only on the intrinsic properties of the cations. It is the first time that such good qualitative agreement is reported between experiment and simulation for a series of both monovalent and divalent cations. 相似文献
5.
A new high: Cannabis as a budding source of carbon-based materials for electrochemical power sources
Zahra I. Rana Ami R. Shah Alice V. Llewellyn Katrina Mazloomian Patricia McAlernon Thomas S. Miller Patrick L. Cullen Paul R. Shearing Dan J.L. Brett 《Current Opinion in Electrochemistry》2022
Cannabis sativa L., a low-cost, fast-growing herbaceous plant, is seeing a resurgence in widespread cultivation as a result of new policies and product drive. Its biodegradable and environmentally benign nature coupled with its high specific surface area and three-dimensional hierarchal structure makes it an excellent candidate for use as a biomass-derived carbon material for electrochemical power sources. It is proposed that this ‘wonder crop’ could have an important role in the energy transition by providing high-functioning carbon-based materials for electrochemistry. In this article, all instances of C. sativa usage in batteries, fuel cells and supercapacitors are discussed with a focus on highlighting the high capacity, rate capability, capacitance, current density and half-wave potential that can be achieved with its utilisation in the field. 相似文献
6.
C. Llewellyn Smith 《The European physical journal. Special topics》2009,176(1):167-178
Fusion, which powers the sun and stars, is potentially an environmentally responsible and intrinsically safe source of essentially
limitless energy. The Joint European Torus (JET) has produced 16 MW of fusion power, and construction of a power station sized
device called ITER (International Tokamak Experimental Reactor), which should produce at least 500 MW, is about to begin.
Further work on fusion technologies is also needed, including construction of the proposed International Fusion Materials
Irradiation Facility (IFMIF) which will test materials that will have to stand up to years of intense neutron bombardment
in a fusion power station. Given i) its potential attractions (which include essentially limitless fuel, and the absence of
green-house gas and of long-lived radio-active by-products), and that ii) it looks as if the economics of fusion power will
be acceptable, the time has come to develop fusion as rapidly as reasonably possible. The status and potential advantages
of fusion are being described, together with the outstanding challenges, the remaining steps and a timetable for developing
fusion power. 相似文献
7.
Sébastien Michelin Stefan G. Llewellyn Smith 《Theoretical and Computational Fluid Dynamics》2010,24(1-4):195-200
A reduced-order model for the two-dimensional interaction of a sharp-edged solid body and a high-Reynolds number flow is presented, based on the inviscid representation of the solid’s wake as point vortices with unsteady intensity. This model is applied to the fall of a rigid card in a fluid and to the flapping instability of a flexible membrane forced by a parallel flow. 相似文献
8.
Ridgway MC Giulian R Sprouster DJ Kluth P Araujo LL Llewellyn DJ Byrne AP Kremer F Fichtner PF Rizza G Amekura H Toulemonde M 《Physical review letters》2011,106(9):095505
Swift heavy-ion irradiation of elemental metal nanoparticles (NPs) embedded in amorphous SiO(2) induces a spherical to rodlike shape transformation with the direction of NP elongation aligned to that of the incident ion. Large, once-spherical NPs become progressively more rodlike while small NPs below a critical diameter do not elongate but dissolve in the matrix. We examine this shape transformation for ten metals under a common irradiation condition to achieve mechanistic insight into the transformation process. Subtle differences are apparent including the saturation of the elongated NP width at a minimum sustainable, metal-specific value. Elongated NPs of lesser width are unstable and subject to vaporization. Furthermore, we demonstrate the elongation process is governed by the formation of a molten ion-track in amorphous SiO(2) such that upon saturation the elongated NP width never exceeds the molten ion-track diameter. 相似文献
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10.
Field experiments to investigate the attenuation of noise from single vehicles over short grass indicate that for a microphone height of 1·2 m and a source/receiver distance <30 m, the rate of attenuation is 4·8 dB(A) per doubling of distance. Some evidence is presented to suggest that for source/receiver distances >30 m the rate of attenuation increases with distance. 相似文献