全文获取类型
收费全文 | 1633篇 |
免费 | 73篇 |
国内免费 | 4篇 |
专业分类
化学 | 1066篇 |
晶体学 | 10篇 |
力学 | 26篇 |
数学 | 237篇 |
物理学 | 371篇 |
出版年
2023年 | 16篇 |
2022年 | 25篇 |
2021年 | 30篇 |
2020年 | 44篇 |
2019年 | 48篇 |
2018年 | 51篇 |
2017年 | 44篇 |
2016年 | 96篇 |
2015年 | 65篇 |
2014年 | 51篇 |
2013年 | 102篇 |
2012年 | 132篇 |
2011年 | 113篇 |
2010年 | 73篇 |
2009年 | 68篇 |
2008年 | 88篇 |
2007年 | 95篇 |
2006年 | 77篇 |
2005年 | 77篇 |
2004年 | 40篇 |
2003年 | 31篇 |
2002年 | 38篇 |
2001年 | 32篇 |
2000年 | 21篇 |
1999年 | 17篇 |
1998年 | 20篇 |
1997年 | 16篇 |
1996年 | 13篇 |
1995年 | 9篇 |
1994年 | 17篇 |
1993年 | 21篇 |
1992年 | 14篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1988年 | 9篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1974年 | 7篇 |
1973年 | 5篇 |
1964年 | 4篇 |
1958年 | 3篇 |
1938年 | 2篇 |
排序方式: 共有1710条查询结果,搜索用时 31 毫秒
1.
Dominik Vítek Prof. Aleš Růžička Lise Vermeersch Dr. Libor Dostál Dr. Jan Turek Prof. Roman Jambor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202202639
Reactivity studies of the GeII→B complex L(Cl)Ge⋅BH3 ( 1 ; L=2-Et2NCH2-4,6-tBu2-C6H2) were performed to determine the effect on the GeII→B donation. N-coordinated compounds L(OtBu)Ge⋅BH3 ( 2 ) and [LGe⋅BH3]2 ( 3 ) were prepared. The possible tuning of the GeII→B interaction was proved experimentally, yielding compounds 1-PPh2-8-(LGe)-C10H6 ( 4 ) and L(Cl)Ge⋅GaCl3 ( 5 ) without a GeII→B interaction. In 5 , an unprecedented GeII→Ga coordination was revealed. The experimental results were complemented by a theoretical study focusing on the bonding in 1 − 5 . The different strength of the GeII→E (E=B, Ga) donation was evaluated by using energy decomposition analysis. The basicity of different L(X)Ge groups through proton affinity is also assessed. 相似文献
2.
Guizellini Filipe Corrêa Franzin Bruno Trevizan da Silva Matheus Antonio Abra Luciana Mazotti Hojo Ossamu Pastre Iêda Aparecida Ribeiro Clóvis Augusto Paiva-Santos Carlos de Oliveira Fertonani Fernando Luis 《Journal of Thermal Analysis and Calorimetry》2021,143(1):47-60
Journal of Thermal Analysis and Calorimetry - The aim of this work is to synthesize and characterize a new structured silver–clay dried, calcined or sintered at different temperatures... 相似文献
3.
Mejía Hugo Fernando Giraldo Jiménez-Piqué Emilio Valdés Matías Procaccini Raúl Pellice Sergio 《Journal of Solid State Electrochemistry》2020,24(10):2451-2460
Journal of Solid State Electrochemistry - A novel material was developed using sol-gel chemistry and an environmental-friendly grafting process of clay nanoparticles. In a previous work of our... 相似文献
4.
Libor Barto 《Journal of Pure and Applied Algebra》2007,211(3):721-731
A category is said to be alg-universal if every category of universal algebras can be fully embedded into it. We prove here that the category of varieties and interpretations, or in other words, the category of abstract clones and clone homomorphisms, is alg-universal. 相似文献
5.
Mat Rasol Awang Hassan Hamdani Mutaat Mohd. Shukri Mahmud Wan Badrin Wan Husain Tajuddin Osman Khomsaton Abu Bakar Asmahwati Kassim Zal U''yun Wan Mahmud Ishak ManafTamikazu Kume Shoji Hashimoto 《Radiation Physics and Chemistry》1993,42(4-6):611-616
In solid state fermentation, Pleurotus sajor-caju has been found to be able to degrade at least 30% oil palm empty Fruit Bunch (EFB) fibre leaving 70 % useful materials. Conditions under which fermentation carried out were investigated. It was found that, in the temperature range between 25– 28 °C, relative ph between 6–8, moisture between 60–70 % and medium composition of CaCO3: rice bran 2 %: 5 % were the optimum conditions. The results showed in fermented products that, there were substantial reduction in cellulosic component such as Crude Fiber (CF, 18 %); Acid Detergent Fibre (ADF, 45 %), Neutral Detergent Fibre (NDF, 61 %) and Acid Detergent Lignin (ADL, 14 %). However, Crude Protein (CP, 10%) increased resulted from single cell protein enrichment of mycelial microbial mass. The mass reductions of substrate in fermentation process corresponds to the CO2 released during fermentation. Hence, attributable to the decreased in content of CF, ADF, NDF, and ADL. The digestibility study has also been carried out to determine the useful level of this product to ruminant. Aflatoxin content was detected low in both the initial substrates and products. Based on nutritional value and low content of aflatoxin, the product is useful as a source of roughage to ruminant. 相似文献
6.
F.F. Karpeshin J. da Providência C. Providência J. da Providência Jr 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):319-326
Two types of extreme collective motion, large-amplitude many-phonon vibration of the ionic core and rotation of the cluster
with high angular momenta, are considered. The interplay between vibration and collective motion towards fission is discussed.
A new mechanism of formation and rupture of the neck is proposed which is based on the Franck-Condon principle, and accounts
for the interplay between vibration and fission. Under rotation, the change of the shape of the cluster and a phase transition
from axially symmetric to triaxial ellipsoid are predicted. For studying the effects, vibrational motion can be induced by
laser radiation. Rotational motion may arise in collisions of clusters.
Received 26 April 2001 and Received in final form 15 October 2001 相似文献
7.
V. Yu. Mat’ev 《Technical Physics》2003,48(3):303-310
The distribution of the two-dimensional gas velocity inside ion-irradiated laser cells is considered for low ion energy deposits into the gas. It is shown that, if the energy deposit is smoothly nonuniform, the twodimensional motion has two quasi-one-dimensional components: the longitudinal gas velocity is practically uniform across the cell and depends on the transversely averaged energy deposit, while the transverse velocity component depends on the difference between the local energy deposit and energy deposit averaged over the transverse direction. 相似文献
8.
B. Vizoso I. R. Matías M. López-Amo M. A. Muriel J. M. López-Higuera 《Optical and Quantum Electronics》1995,27(10):847-857
The design of a double-parallel amplified recirculating optical delay line utilizing an erbium-doped fibre amplifier for a fibre optical bus is described. This structure is used for amplifying, equalizing and filtering multicarrier signals coming from optoelectronic units attached to fibre couplers. The use of this structure for a hybrid multimode-singlemode fibre bus that includes optoelectronic units for sensors is also demonstrated. 相似文献
9.
J.P. Jay E. Jêdryka M. Wójcik J. Dekoster G. Langouche P. Panissod 《Zeitschrift für Physik B Condensed Matter》1997,101(3):329-337
While RHEED observations show that 10 to 11 As is the stability limit for an open bcc Co layer when grown on an Fe substrate, our XRD and NMR studies have shown that, in MBE grown Co/Fe superlattices, cobalt can be stabilised in a bcc structure up to a critical Co thickness of 21 Ås. In order to understand this apparent discrepancy, NMR experiments have been carried out in Cox/Fey multilayers with thickness varying in the range 5 Å < x < 42 Å and 24 Å < y < 60 Å, grown on GaAs (1 1 0) as well as on MgO (1 0 0) substrates. The analysis of the chemical short range order by NMR concludes that the larger bcc Co thickness observed in superlattices results from the formation of a rather homogeneous CoFe20% bcc alloy which contains the supplementary 10–11 As of Co and which coexists with pure Co grains. The concentration of about 20% Fe in the alloyed part of the Co layer happens to be close to the stability limit for a bcc structure in the equilibrium phase diagram of bulk CoFe alloys. However, while a mixture of bcc and fcc phases is observed in bulk alloys, the bcc structure is preserved in all phases under the MBE growth conditions and below the critical thickness. Above the critical thickness amixture of bcc Co, bcc CoFe and hcp Co is observed. 相似文献
10.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献