全文获取类型
收费全文 | 23020篇 |
免费 | 3967篇 |
国内免费 | 2838篇 |
专业分类
化学 | 16775篇 |
晶体学 | 345篇 |
力学 | 1302篇 |
综合类 | 180篇 |
数学 | 2729篇 |
物理学 | 8494篇 |
出版年
2024年 | 84篇 |
2023年 | 479篇 |
2022年 | 873篇 |
2021年 | 818篇 |
2020年 | 870篇 |
2019年 | 935篇 |
2018年 | 764篇 |
2017年 | 758篇 |
2016年 | 1121篇 |
2015年 | 1127篇 |
2014年 | 1445篇 |
2013年 | 1793篇 |
2012年 | 2156篇 |
2011年 | 2285篇 |
2010年 | 1514篇 |
2009年 | 1446篇 |
2008年 | 1507篇 |
2007年 | 1378篇 |
2006年 | 1192篇 |
2005年 | 1045篇 |
2004年 | 893篇 |
2003年 | 673篇 |
2002年 | 632篇 |
2001年 | 528篇 |
2000年 | 452篇 |
1999年 | 437篇 |
1998年 | 332篇 |
1997年 | 262篇 |
1996年 | 294篇 |
1995年 | 258篇 |
1994年 | 246篇 |
1993年 | 174篇 |
1992年 | 172篇 |
1991年 | 151篇 |
1990年 | 154篇 |
1989年 | 122篇 |
1988年 | 73篇 |
1987年 | 62篇 |
1986年 | 71篇 |
1985年 | 54篇 |
1984年 | 43篇 |
1983年 | 30篇 |
1982年 | 14篇 |
1981年 | 20篇 |
1980年 | 8篇 |
1979年 | 14篇 |
1977年 | 8篇 |
1976年 | 10篇 |
1975年 | 8篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
High Energy Chemistry - Modification of Polyvinylidene fluoride (PVDF) by radiation grafting is a research hotspot in recent years. In this study, the monomer 2-Hydroxyethyl methacrylate (HEMA) was... 相似文献
2.
Journal of Optimization Theory and Applications - We distinguish two kinds of piecewise linear functions and provide an interesting representation for a piecewise linear function between two normed... 相似文献
3.
Li Y. Shi W. H. Dong L. M. Xu S. X. Huang H. J. Yin J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,... 相似文献
4.
A graphic sequence π =(d1, d2,..., dn) is said to be forcibly k-edge-connected if every realization of π is k-edge-connected. In this paper, we obtain a new sufficient degree condition for π to be forcibly k-edgeconnected. We also show that this new sufficient degree condition implies a strongest monotone degree condition for π to be forcibly 2-edge-connected and a conjecture about a strongest monotone degree condition for π to be forcibly 3-edge-connected due to... 相似文献
5.
6.
Donglei Wei Huili Li Chuanqing Yang Jianmin Fu Hou Chen Liangjiu Bai Wenxiang Wang Huawei Yang Lixia Yang Ying Liang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1588-1594
Acridone as a new kind of visible light photocatalyst has been developed to catalyze metal free atom transfer radical polymerization (ATRP). The photocatalyst possess low excited state potential as can undergo an oxidative quenching pathway to initiate ATRP of vinyl monomers. Kinetic study and light on/off reaction demonstrate the “living”/controlled nature of the polymerization by light. Block copolymers can be achieved by using PMMA as macroinitiator to reinitiate polymerization of other vinyl monomers, which shows highly preserved Br chain-end functionality in the synthesized polymers. Moreover, the polymerization can be conducted under air atmosphere as most photocatalysts need anaerobic condition, which may give inspiration of further application of this kind of photocatalyst. 相似文献
7.
Liang Zhao 《Journal of Differential Equations》2019,266(9):5615-5624
In this paper, let be n-dimensional noncompact metric measure space which satisfies Poincaré inequality with some Ricci curvature condition. We obtain a Liouville theorem for positive weak solutions to weighted p-Lichnerowicz equation where are real constants. 相似文献
8.
Xinghua Li Yuqin Yang Junjie Miao Zhendong Yin Yijing Zhai Hongmei Shi Zengning Li 《Electrophoresis》2020,41(18-19):1584-1591
In the present research, field-amplified sample injection–CZE (FASI–CZE) coupled with a diode array detector was established to determine trace level sulfa antibiotic. Sulfathiazole, sulfadiazine, sulfamethazine, sulfadimethoxine, sulfamethoxazole, and sulfisoxazole were selected as analytes for the experiments. The background electrolyte solution consisted of 70.0 mmol/L borax and 60.0 mmol/L boric acid (including 10% methanol, pH 9.1). The plug was 2.5 mmol/L borax, which was injected into the capillary at a pressure of 0.5 psi for 5 s. Then the sample was injected into the capillary at an injection voltage of –10 kV for 20 s. The electrophoretic separation was carried out under a voltage of +19 kV. The capillary temperature was maintained at 20˚C throughout the analysis, and six sulfonamides were completely separated within 35 min. Compared with pressure injection-CZE, the sensitivity of FASI-CZE was increased by 6.25–10.0 times, and the LODs were reduced from 0.2–0.5 to 0.02–0.05 μg/mL. The method was applied to the determination of sulfonamides in river water and particulate matter samples. The recoveries were 78.59–106.59%. The intraday and interday precisions were 2.89–7.35% and 2.77–7.09%, respectively. This provides a simpler and faster method for the analysis of sulfa antibiotic residues in environmental samples. 相似文献
9.
Hongling Yu Heyong Wang Galia Pozina Chunyang Yin Xiao-Ke Liu Feng Gao 《Chemical science》2020,11(41):11338
Metal halide perovskites have demonstrated impressive properties for achieving efficient monochromatic light-emitting diodes. However, the development of white perovskite light-emitting diodes (PeLEDs) remains a big challenge. Here, we demonstrate a single-emissive-layer all-perovskite white PeLED using a mixed halide perovskite film as the emissive layer. The perovskite film consists of separated mixed halide perovskite phases with blue and red emissions, which are beneficial for suppressing halide anion exchange and preventing charge transfer. As a result, the white PeLED shows balanced white light emission with Commission Internationale de L''Eclairage coordinates of (0.33, 0.33). In addition, we find that the achievement of white light emission from mixed halide perovskites strongly depends on effective modulation of the halide salt precursors, especially lead bromide and benzamidine hydrochloride in our case. Our work provides very useful guidelines for realizing single-emissive-layer all-perovskite white PeLEDs based on mixed halide perovskites, which will spur the development of high-performance white PeLEDs.We demonstrated a single-emissive-layer all-perovskite white light-emitting diode based on a mixed halide perovskite film. 相似文献
10.
We study the full counting statistics of transport electrons through a semiconductor two-level quantum dot with Rashba spin–orbit (SO) coupling, which acts as a nonabelian gauge field and thus induces the electron transition between two levels along with the spin flip. By means of the quantum master equation approach, shot noise and skewness are obtained at finite temperature with two-body Coulomb interaction. We particularly demonstrate the crucial effect of SO coupling on the super-Poissonian fluctuation of transport electrons, in terms of which the SO coupling can be probed by the zero-frequency cumulants. While the charge currents are not sensitive to the SO coupling. 相似文献