Charmless Hadronic Decays B→VV in the Topcolor-Assisted Technicolor Model

Based. On the effective Hamiltonian with the generalized factorization approach, we calculate the branchingratios and CP asymmetries of B → VV decays in the Topcolor-assisted Technicolor (TC2) model. Within the consideredparameter space we find that: (a) for the penguin-dominated B → K* φ and K*0 φ decays, the new physics enhancementsto the branching ratios are around 40%; (b) the measured branching ratios of B →K* φ and K*0φ decays prefer therange of 3 Neffc 5; (c) the SM and TC2 model predictions for the branching ratio B(B →ρ ρ0) are only about halfof the Belle‘s measurement; and (d) for most B → VV decays, the new physics corrections on their CP asymmetries are generally small or moderate in magnitude and insensitive to the variation of mπ and Neffc.     

κ-卡拉胶热可逆凝胶的非遍历行为研究

采用散射斑纹(speckle)技术,即散射光强涨落法,研究了κ-卡拉胶(KC)热可逆凝胶的非遍历行为.证明了非遍历性的存在,并研究了浓度、温度等条件对该非遍历性的影响.结果表明:该物理凝胶存在非遍历性,并随KC浓度增加,凝胶非遍历性增大;随温度升高,凝胶非遍历性逐渐减小,直至消失.     

Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides

A series of Diels-Alder reaction cross-linked thermosets with recyclability and healability were prepared from furan-containing aromatic polyamide and bismaleimides with different chemical structures.The structures of synthesized bismaleimides were confirmed by 1 H nuclear magnetic resonance(1 H-NMR)spectroscopy;their reversible cross-linking with the furanic polyamide was further detected by 1 H-NMR technique and sol-gel transition behavior.The dynamic mechanical analysis and tensile test revealed the variable thermal and mechanical properties of thermosets cross-linked by different bismaleimides and with different molar ratios of maleimide group to furan group(Ima/fur).The tensile test also demonstrated that the better recyclability and solvent-assisted healability of thermosets cross-linked could be achieved by more flexible bismaleimides.This work is expected to provide valuable information for design of recyclable and healable high-performance thermosets with desired properties.     

环境化学开放性实验设计:重金属污染土壤的化学淋洗*

介绍了一个开放性环境化学实验。该实验以被重金属污染的土壤为研究对象,分别使用稀盐酸、乙二胺四乙酸、氯化钙为淋洗剂,对其进行化学淋洗修复。通过电感耦合等离子体光谱仪分析比较修复前后土壤中铅、镉的含量,用以帮助学生加深理解配合/螯合作用、酸-碱反应、离子交换反应、胶体的性质、土壤重金属形态、土壤性质与组成等相关环境化学知识。实验所用的土壤样品由学生自选,不同类型土壤的理化性质影响淋洗效果,从而增加了实验结果的不确定性。本实验贴近学科前沿且联系工程实际,可激发学生独立思考和探索精神,提高学生的科研能力与解决复杂问题的能力。     

ZnO荧光粉中的紫外发射和绿色发射之间的关系

通过在低氧分压和真空中热处理ZnO粉末, 获得了ZnO荧光粉. ZnO荧光粉有两个发射谱带, 分别位于380 nm(紫外)和510 nm(绿色). 紫外谱带对应于ZnO中的激子发射, 是一个单中心发光过程；绿色谱带是一个复合发光过程, 与ZnO中的本征缺陷相关, 如氧空位、锌空位等. 实验表明, 高密度的激发条件有利于紫外发射, 而低氧分压下的热处理有利于提高绿色发射谱带的强度. 研究结果还表明, 与紫外发射相联系的激子可向与本征缺陷相联系的绿色发光中心传递能量, 这种传递可能是通过激子扩散实现的.     

Fe3O4磁性纳米粒子的超声包金及其表征

超声条件下, 在乙醇分散的3-氨丙基三乙氧基硅烷(APTES)功能化的磁性Fe₃O₄纳米粒子和四氯合金酸的混合溶液中滴加柠檬酸钠, 成功地制备了磁性Fe₃O₄/Au复合纳米粒子. 采用X射线粉末衍射仪(XRD)、紫外吸收可见光谱(UV-Vis)、带有电子能谱仪(EDS)的扫描电子显微镜(SEM)、透射电子显微镜(TEM)、光电子能谱(XPS)、超导量子干涉仪(SQUID)等方法, 对复合粒子的形态、结构、组成以及磁学性质进行了表征. 结果表明: 在此条件下制得的复合粒子粒径在30 nm左右, 室温下磁化强度可达63 emu/g.     

Preparation and characterization of polyphenylene sulfide-based chelating fibers

A series of novel chelating fibers containing sulfur, nitrogen, oxygen heteroatoms were prepared via the functionalization of chloromethylated polyphenylene sulfide （CMPPS）. The structures, micromorpholo- gy and physicochemical properties of these fibrous adsorptive materials were characterized by FT-IR, elementary analysis, TG and SEM-EDS. The results show that chelating fibers had high functional group contents （3.94 mmol/g for thiourea, 3.85 mmol/g for mercapto, 5.00 mmol/g for methylamine and 6.07 mmol/g for ethylenediamine, respectively）. Owing to the unique matrix of polyphenylene sulfide fiber, these fibrous adsorbents possess excellent thermostability. This synthetic method proved a simple and efficient way for the preparation of chelating fibers.     

Artificial Water Channels: Towards Biomimetic Membranes for Desalination

Natural Aquaporin (AQP) channels are efficient water translocating proteins, rejecting ions. Inspired by this masterpiece of nature, Artificial Water Channels (AWCs) with controlled functional structures, can be potentially used to mimic the AQPs to a certain extent, offering flexible avenues toward biomimetic membranes for water purification. The objective of this paper is to trace the historical development and significant advancements of current reported AWCs. Meanwhile, we attempt to reveal important structural insights and supramolecular self-assembly principles governing the selective water transport mechanisms, toward innovative AWC-based biomimetic membranes for desalination.     

Teleportation of an arbitrary mixture of diagonal states of multiqudit

This paper proposes a scheme to teleport an arbitrary mixture of diagonal states of multiqutrit via classical correlation and classical communication. To teleport an arbitrary mixture of diagonal states of N qutrits, N classically correlated pairs of two qutrits are used as channel. The sender （Alice） makes Fourier transform and conditional gate （i.e., XOR（3） gate） on her qutrits and does measurement in appropriate computation bases. Then she sends N ctrits to the receiver （Bob）. Based on the received information, Bob performs the corresponding unitary transformation on his qutrits and obtains the teleported state. Teleportation of an arbitrary mixture of diagonal states of multiqudit is also discussed.