Efficient Synthesis of 3-(4-Carboxyphenyl)pyridine-2,6-dicarboxylic Acid

Russian Journal of Organic Chemistry - An efficient synthetic approach to 3-(4-carboxyphenyl)pyridine-2,6-dicarboxylic acid has been developed on the basis of “1,2,4-triazine”...     

Single-crystal X-ray diffraction analysis of arylamine-containing 2,2′-bipyridine derivatives

The structures of six 2,2′-bipyridine derivatives containing aromatic amine moieties, namely N-aryl-4-aryl-1-(pyridin-2-yl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-amines, were studied by single-crystal X-ray diffraction. The molecular structures and the effect of the substituents of these compounds on the crystal packing are discussed.

     

Substitution of Cyano Group in Position 5 of 1,2,4-Triazines by Carboxylic Acid Hydrazide Residues under Solvent-Free Conditions

Russian Journal of Organic Chemistry - The possibility of substitution of the 5-cyano group in 1,2,4-triazines by carbohydrazide residues under solvent-free conditions with high yields has been...     

One-Pot Preparation Method of 5-Alkyl-3-(benzo)pyridyl-1,2,4-triazines

Russian Journal of Organic Chemistry - Convenient one-pot method was developed for the preparation of 5-alkyl-3-(2-pyridyl)-, 5-alkyl-3-(4-pyridyl)- or 5-alkyl-3-(quinolin-2-yl)-1,2,4-triazines in...     

A PASE-based approach towards 12-(1H-1,2,3-triazol-1-yl)-indolo[2,1-a]isoquinolines via the reaction of 3-(isoquinolin-1-yl)-1,2,4-triazines with benzyne

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Solvent-free reaction of 3-aryl-6-(3-nitrophenyl)-1,2,4-triazines with 4-(cyclohex-1-en-1-yl)morpholine

The aza-Diels–Alder reaction of 3-aryl-6-(3-nitrophenyl)-1,2,4-triazines with 4-(cyclohex-1-en-1-yl)morpholine as dienophile was accompanied by reduction of the nitro group to amino. In the reaction of 3-(4-methoxyphenyl)-6-(3-nitrophenyl)-1,2,4-triazine with 4-(cyclohex-1-en-1-yl)morpholine, 3-[3-(4-methoxyphenyl)-1,2,4-triazin-6-yl)aniline was formed together with the cycloaddition product.     

Reactions of Perylene with Aryne Intermediates

Russian Journal of Organic Chemistry - The Diels-Alder reactions of perylene (diene) with 1,2-didehydrobenzene and 4,5-dimethoxy-1,2-didehydrobenzene (dienophiles) generated in situ by two methods...     

One-Step Synthesis of 5-Methyl-1,2,4-triazines by the Transformation of Their 5-Phenacyl Derivatives

Russian Journal of Organic Chemistry - A convenient one-step synthesis of 5-methyl-1,2,4-triazines by the transformation of 5-phenacyl-1,2,4-triazines under alkaline conditions was developed. The...     

An efficient synthetic approach towards new 5, 5'-diaryl-2, 2'-bipyridine-based fluorophores

An efficient approach has been developed for the synthesis of 5,5'-diaryl-2,2'-bipyridines via their 1,2,4-triazine analogues. The notable advantages of the present method are:The possibility of varying the aromatic substituents in the positions 5 and 5' of bipyridine core and the possibility for obtaining 2,2'-bipyridines bearing a fused cyclopentene core to increase the solubility in organic solvents. These 5,5'-diaryl-2,2'-bipyridines exhibited an intense emission in a range of ca. 422-521 nm in acetonitrile solution; depending on the nature of the aromatic substituents and the presence of annulated cyclopentene fragments. Apart from that, the significant bathochromic shifts of the both absorption and emission maxima were observed in comparison with a number of previously described similar structures. In some cases the significant increasing of the fluorescence quantum yields took place.     

5-Aryl-2,2′-bipyridines bearing fluorinated anilines residues at C6 position: synthesis and photophysical properties

Research on Chemical Intermediates - A convenient synthetic approach to 5-aryl-2,2′-bipyridines bearing a (poly)fluorine-containing aniline residue at position C6 based on sequential...