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1.
Watanabe Sou Senzaki Tatsuya Shibata Atsuhiro Nomura Kazunori Takeuchi Masayuki Nakatani Kiyoharu Matsuura Haruaki Horiuchi Yusuke Arai Tsuyoshi 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(3):1273-1277
Journal of Radioanalytical and Nuclear Chemistry - Extraction chromatography flow-sheet employing octyl(phenyl)-N,N-diisobutylcarbonoylmethylphosphine oxide and bis(2-ethylhexyl) hydrogen phosphate... 相似文献
2.
Atsunori Matsuda Tatsuo Matoda Toshihiro Kogure Kiyoharu Tadanaga Tsutomu Minami Masahiro Tatsumisago 《Journal of Sol-Gel Science and Technology》2004,31(1-3):229-233
Titania nanosheet-precipitated coatings have been prepared by treating SiO2-TiO2 gel films on glass substrates with hot water at 90°C under vibration. Longitudinal vibrations at about 6 Hz during the treatment enhanced the formation of titania nanosheet. The titania nanosheet consisted of several layers with a spacing of about 0.6 nm and was identified as hydrated titania with a lepidocrocite-type structure. The morphology of the titania nanosheet-precipitated coatings is probably achieved by lowering of the concentration of hydrolyzed titania species at the surface due to rapid water flow driven by the vibrations. The coatings were transparent in the visible range and showed high photocatalytic activity and antifogging property. 相似文献
3.
Kiyoharu Nishide Shin-ichi Ohsugi Tetsuo Miyamoto Kamal Kumar Manabu Node 《Monatshefte für Chemie / Chemical Monthly》2004,135(2):189-200
Summary. Development of new odorless thiols (dodecanethiol, 4-n-heptylphenylmethanethiol, 4-trimethylsilylphenylmethanethiol, 4-trimethylsilylbenzenethiol) and an odorless sulfide (1-methylsulfanyldodecane) and their applications to dealkylation, Michael addition, Swern oxidation, and Corey-Kim oxidation are described. 相似文献
4.
Kiyoharu Tadanaga Kazuki Iwashita Tsutomu Minami Noboru Tohge 《Journal of Sol-Gel Science and Technology》1996,6(1):107-111
Nylon-6 substrates were coated with SiO2 thin films by the sol-gel method and their water permeability coefficient was evaluated. Methyltriethoxysilane (MTES) and tetraethoxysilane (TEOS) were used as starting materials. The addition of MTES to TEOS has enabled the formation of crack-free thin films on the substrates. The thin films strongly adhered to the substrates. The water permeability coefficients of nylon-6 substrates coated with these thin films decreased with the increase in the ratio of TEOS to the total alkoxides. The pretreatment of the nylon-6 substrates with -aminopropyltriethoxysilane was found to be effective to suppress the water permeability. The water permeability was suppressed by about 40% under the optimal condition. 相似文献
5.
Kiyoharu Tadanaga Koji Morita Keisuke Mori Masahiro Tatsumisago 《Journal of Sol-Gel Science and Technology》2013,68(2):341-345
Silica nanoparticles with high concentration were prepared by the sol–gel process based on the Stöber method using tetraethoxysilane as a starting material. It was found that silica sol with about 4 wt% in concentration and with a diameter of about 10 nm was obtained by controlling the reaction conditions in the Stöber process. By removing the solvent under a reduced pressure, the particle concentration was increased up to 15 wt% without aggregation. 相似文献
6.
Hirokazu KitauraAkitoshi Hayashi Kiyoharu TadanagaMasahiro Tatsumisago 《Solid State Ionics》2011,192(1):304-307
To improve the electrochemical performance of an all-solid-state In/80Li2S⋅20P2S5 (electrolyte)/LiMn2O4 cell, a lithium-titanate thin film was used to coat LiMn2O4. The interfacial resistance between LiMn2O4 and the electrolyte (measured after initial charging) decreased when the LiMn2O4 particles were coated with lithium-titanate. A cell with lithium-titanate-coated LiMn2O4 had a higher capacity than a cell with noncoated LiMn2O4 for current densities in the range 0.064 to 2.6 mA cm− 2. Additionally, a cell with coated LiMn2O4 retained 96% of the 10th-cycle reversible capacity at a current density of 0.064 mA cm− 2 after 50 cycles. 相似文献
7.
Hiroya Kitahata Kiyoharu Tadanaga Tsutomu Minami Norifumi Fujimura Taichiro Ito 《Journal of Sol-Gel Science and Technology》2000,19(1-3):589-593
Hexagonal YMnO3 has a ferroelectric property with an optimal remanent polarization along the c-axis. The c-axis oriented YMnO3 thin films with a small leakage current were prepared by the sol-gel dipping method. The c-axis orientation of the films was promoted by the addition of diethanolamine to the Mn precursor solution. A heat treatment with multiple steps led to a dense film structure with fine grains. The dense structure resulted in the decrease of the leakage current. Furthermore, when the films were heat-treated in a vacuum, the leakage current became considerably small and the ferroelectricity of the YMnO3 thin films was observed even at room temperature. 相似文献
8.
A redox species was extracted from water (50 x 10(-6) dm3) into a single micro-oil-droplet (30 x 10(-12) dm3) in contact with a microelectrode using microcapillary injection and manipulation techniques. Further, an in situ microanalysis of the solute in a single oil droplet was demonstrated by differential pulse voltammetry. The redox species of 10(-16) mol concentrated in the droplet could be quantitatively analyzed independently of the distribution coefficient of the solute between the oil and water phases. The potential of this technique was considered in terms of the preconcentration and separation as well as a microanalysis and an ultratrace analysis. 相似文献
9.
Formation of Superhydrophobic Alumina Coating Films with High Transparency on Polymer Substrates by the Sol-Gel Method 总被引:6,自引:0,他引:6
Kiyoharu Tadanaga Kaori Kitamuro Atsunori Matsuda Tsutomu Minami 《Journal of Sol-Gel Science and Technology》2003,26(1-3):705-708
Transparent, superhydrophobic coating films have been prepared on polymer substrates at low temperatures through the sol-gel method. Al2O3 gel films were prepared on poly(ethylene terephthalate) substrates from Al(O-sec-C4H9)3 chemically modified with ethyl acetoacetate. A small roughness of about 20–50 nm was found to form on the surface of the Al2O3 gel films dried at room temperature and then immersed in hot water at 60°C. The electron diffraction measurements have shown that this roughened surface consists of pseudoboehmite nanocrystals. The coating of hydrolyzed fluoroalkyltrimethoxysilane on the Al2O3 gel films with the small roughness produced transparent, superhydrophobic films with contact angle for water larger than 150°. 相似文献
10.