Interesting fluorescence properties of C60-centered dendritic adduct with twelve symmetrically attached pyrenes

A C60-centered dendritic adduct with 12 symmetrically attached pyrene species was synthesized and found to have relatively simple fluorescence emission kinetics, in particular, the mono-exponential decay of the significant pyrene excimer emission.     

响应面方法的硅刻蚀工艺优化分析（英）

利用响应面分析方法优化了用于压力传感器硅敏感芯体的刻蚀操作条件。主要考虑了温度、KOH浓度和腐蚀时间三个操作参数,将它们的范围分别设定为40~60 ℃,0.4~0.48 mol/L 和 5~12.5 h,并设定各向异性腐蚀速率为响应值。通过建立二次方模型,分析这些参数的单独影响以及多个操作条件之间对腐蚀速率的相互交叠作用。分析结果表明：模型可以精确预测99%的响应值,相比于腐蚀时间,溶液浓度和工作温度对刻蚀速率的影响更为明显。     

Cellulosic fiber: mechanical fibrillation-morphology-rheology relationships

Cellulose - This study aims to investigate the relationship between mechanical fibrillation, morphological properties, and rheological behavior of cellulosic fiber. Three types of cellulosic fibers...     

150 kV全固态高压脉冲发生器设计

设计了一种基于全固态MOSFET半导体开关器件的Marx脉冲发生器。充电回路用快恢复二极管代替充电电阻,减小了充电部分功率损耗;将主电路和驱动电路集成在一起,采用自取电模式给驱动电路供电;由光纤传输驱动信号,抑制了放电回路对触发信号的干扰;采用顺/逆时针方向环形分布的紧凑型拓扑结构,不仅减小了回路电感,而且实现了脉冲发生器的小型化与模块化。所设计的Marx发生器充电部分仅需提供900 V低压,用180级单元串联,获得最高幅值为150 kV、脉宽1~5 s可调的高压快脉冲,前沿控制在500 ns以内。利用该脉冲发生器在50 k电阻和5 pF电容并联的等效负载上进行了一系列实验;比较分析了脉冲发生器工作过程中影响脉冲上升沿的几个主要因素,包括回路电感、MOSFET驱动电压及主回路分布电容等,并讨论了提升脉冲前沿的技术措施。     

脉冲压缩电路磁开关动态特性

提出在典型一阶磁脉冲压缩电路的基础上,测取磁芯在实际工作条件下的动态磁滞回线和饱和磁导率等磁参数,再根据所获得的动态参数指导磁开关设计,进行一阶磁压缩实验。实验选取国内外被广泛应用的非晶磁芯和纳米晶磁芯进行测试,根据实测动态磁参数设计磁开关。实测结果表明：用国产非晶磁芯做磁开关可得到上升沿73 ns、电压幅值28.3 kV、半高宽为503 ns的脉冲,用日本产的纳米晶磁芯做磁开关可得到上升沿30 ns、电压幅值28.4 kV、半高宽为193 ns的脉冲。     

Thermal degradation kinetics and heat properties of cellulosic cigarette paper: influence of potassium carboxylate as combustion improver

Accurate determination of the thermal properties of cellulose is of particular significance in studying the mechanism of cellulosic cigarette paper combustion. This paper probes into the influence of four kinds of potassium carboxylates on the thermal degradation kinetics and the heat properties of cigarette paper through simultaneous thermogravimetric analysis (TGA) coupled with differential scanning calorimetry (DSC) measurement under air atmosphere. Reduced mass loss and mass loss rate, and increased solid residue for samples containing four potassium salts implied that potassium carboxylates may retard the formation of levoglucosan and volatiles by inhibiting the depolymerization reaction and simultaneously accelerate char formation by catalyzing the dehydration reaction. Kinetic parameters were analyzed based on three non-isothermal models available in literature. The results indicated that three modeling methods exhibit good consistency. A global activation energy range of 106–155 kJ mol^?1 was proposed for cigarette paper with potassium carboxylates. The four potassium salts studied considerably reduced the activation energy in the following descending order: potassium 1,2,3,4-butane tetracarboxylate (PBTCA) > citrate > gluconate > ascorbate. The heat properties of cigarette paper were also determined by integrating the DSC curves. The results demonstrated that both cellulose degradation and char oxidation have strong exothermic peaks. Cigarette paper samples with potassium salts have lower exothermic cellulose degradation process and higher exothermic char oxidation process, which were further confirmed by greater differences as the amounts of salt citrate or PBTCA increased.     

Synthesis and optical properties of metal-centered dimeric fullerene macromolecules

Dimeric fullerene macromolecules were prepared via the complexation of two fullerenylated 2,2′:6′,2″-terpyridine ligands with Fe(II) and Co(II) ions. The solubility of these macromolecules in some organic solvents allowed both their structural characterization and a study of their optical properties. The electronic absorption and emission of the macromolecules in solution were evaluated; and the results indicated no meaningful ground-state and excited singlet state intramolecular charge transfer interactions. However, the laser flash photolysis results could be explained in terms of the electron transfer quenching of the excited triplet methanofullerene moiety by the center metal–ligand complex in the macromolecules. The optical limiting properties of the macromolecules in solution were also investigated in comparison with those of the ligands for an evaluation of the complexation effects.     

On the boundary value problem of elastostatics in terms of stresses

The boundary value problem of elastostatics in terms of six components of the stress consists of nine equations and three boundary conditions. In this paper, we distinguished between the possible cases and impossible cases, i.e., the problem is or is not equivalent to a boundary value problem of six equations and six boundary conditions.     

Physical properties and thermal behavior of reconstituted tobacco sheet with precipitated calcium carbonate added in the coating process

Addition of precipitated calcium carbonate (PCC) to cellulosic products can reduce production costs and modify their physical properties. This study investigated the effects of adding PCC on the properties of reconstituted tobacco sheet (RTS), a cellulosic product. Scanning electron microscopy (SEM) analysis showed that adding PCC to the coating could modify the surface microstructure of RTS. With increasing PCC addition, the strength and tar release per cigarette of RTS decreased. However, the filling capacity, bulk, and CO release content in the mainstream smoke reached optimal values when the proportion of PCC in the coating was 8%. Thermogravimetry (TG) and differential thermogravimetry (DTG) analysis indicated that the main thermal pyrolysis stage occurred in the range of 200–400 °C, similar to cellulosic components. The Coats–Redfern equation was used to analyze the thermal pyrolysis mechanism. The fitting results showed that, in the range of 200–280 °C, the best fit model for RTS with 4 or 8% PCC was diffusion-controlled reaction (D1) with fitting correlation coefficient (r ²) of 0.9630 and 0.9576, respectively. Meanwhile, in the range of 280–400 °C, the most reliable fitting model for RTS with 4% PCC was chemical reaction (F2) with r ² = 0.9681. One reaction model could not describe the thermal pyrolysis of RTS with 12% PCC in the main decomposition stage. The thermal kinetic parameters suggested that addition of PCC to RTS coatings could modify the thermal pyrolysis mechanism, but did not change the peak temperatures in the main thermal decomposition stage. This study demonstrates that addition of PCC to RTS coating is a promising method to improve its quality.     

Poisson比为1/2材料中球形空穴突变和球形空穴萌生的分岔问题研究

研究Ｐｏｉｓｓｏｎ比为１／２的Ｈｏｏｋｅ材料中,空穴的突变和萌生现象·求解一个球对称几何非线性弹性力学的移动边界（ｍｏｖｉｎｇｂｏｕｎｄａｒｙ）问题,空穴为球形,远离空穴处为三向均匀拉伸应力状态,在当前构形上列控制方程;在当前构形边界上列边界条件·找到了这个自由边界问题的封闭解并得到空穴半径趋于零时的叉型分岔解·计算结果显示,在位移＿载荷曲线上存在一个切分岔型分岔点（或鞍结点型分岔点、极值型分岔点）,这个分岔点说明在外力作用下空穴会发生突变,即突然“长大”;当球腔半径趋于零时,这个切分岔转化为叉型分岔（或分枝型分岔）,这个叉型分岔可以解释实心球中的空穴萌生现象