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Naringenin is a natural widespread flavanone occurring in different foodstuffs that presents several important biological activities. Although its properties are well documented, its mechanisms of action are still controversial. The present article reports a conformational analysis of naringenin, using the semiempirical AM1 and ab initio methods, at the Hartree–Fock level of theory. The 3-21G, 3-21G*, 6-31G, and 6-31G** basis sets were used. The electron correlation effects were included through the Møller–Plesset second-order perturbation theory. The solvation of naringenin has been investigated through the standard SCRF, the supermolecule (SM), and the combined SM/SCRF models. The results have shown that there are two degenerate forms of naringenin, differing mainly by the orientation of a hydroxyl group (C4—OH). The energy barrier for the interconversion between them is ca. 6 kcal.mol–1, suggesting some conjugation between the -system of the aromatic B ring and the hydroxyl group (C4—OH). 相似文献
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This paper focuses on a one-camera/one-shot procedure able to get the whole deformation map of hyperelastic tubular samples. A challenging application of this approach is the investigation of the highly anisotropic and inhomogeneous arterial tissue mechanical response during inflation/extension tests. To address this issue, full field optical methods based on digital correlation (DIC), fringe projection (FP) and stereo-photogrammetry (SP) have been already proposed in literature to overcome limitations of the most widely adopted 2-D video dimension analyzer (VDA) systems.In this paper, the feasibility of a very straightforward full-field procedure that uses radial metrology concepts has been studied. The rationale behind the proposed method relies on the relation existing between image deformation of a world point reflected by a 45° concave conical mirror and the relative position of this point with respect to the specular surface. Under certain assumptions reasonably true for the application of interest, by using simple relationships, it is possible to retrieve the position of markers applied onto the sample surface with great precision. This procedure has several advantages such as the retrieval of the whole 360° surface map in one shot, the ease of application, the use of one single camera, the real-time measurement capability. Conversely, the proposed approach is suitable only for geometries with smooth transversal sections, needs sample preparation and its spatial resolution is limited by the sparsity of the surface control points.The paper describes first the theoretical basis of the procedure; then results of experimental tests on calibration samples and latex tubular specimens are presented and discussed. Further set-up improvements will allow the present procedure to be implemented for in-vitro inflation/extension tests on vascular segments. 相似文献
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Haydar Aygün Keith Attenborough Walter Lauriks Philip A. Rubini Christian M. Langton 《Applied Acoustics》2011,(7):458-463
Comparisons between predictions of a Biot-Allard model allowing for angle-dependent elasticity and angle-and-porosity dependent tortuosity and transmission data obtained at normal incidence on water-saturated replica bones are extended to oblique incidence. The model includes two parameters which are adjusted for best fit at normal incidence. Using the same parameter values, it is found that predictions of the variation of transmitted waveforms with angle through two types of bone replica are in reasonable agreement with data despite the fact that scattering is not included in the theory. 相似文献
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E. Costa A. Emanuele A. Rubini E. Massaro G. Matt G. Medici G. C. Perola M. Salvati 《Il Nuovo Cimento C》1990,13(2):431-436
Summary We describe a high sensitivity X-ray Thomson polarimeter for astrophysical research, particularly designed for the XMM mission.
The efficiency, the modulation factor and the performances of this instrument have been estimated by means of a Monte Carlo
simulation. The predicted sensitivity for the high eccentricity Orbit of XMM should allow the detection of the Crab Nebula
polarization (3σ, (5÷11)keV) in 15 seconds only.
To speed up publication, the proofs were not sent to the authors and were supervised by the Scientific Committee. 相似文献
8.
de Oliveira Thomas Rafael Tannous Katia de Lima Elisangela Cristina Trevisan 《Journal of Thermal Analysis and Calorimetry》2022,147(13):7431-7448
Journal of Thermal Analysis and Calorimetry - This work aims to investigate the thermal decomposition and reaction kinetics of the hybrid energy cane, as well as its thermochemical properties.... 相似文献
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We analyze light self-confinement induced by multiple nonlinear resonances in a two-dimensional chi(2) photonic crystal. With reference to second-harmonic generation in a hexagonal lattice, we show that the system can not only support two-color (1+1)D solitary waves with enhanced confinement and steering capabilities but also enable novel features such as wavelength-dependent soliton routing. 相似文献
10.
Gabriela Pin-Zrate Fernanda Reyes-Riquelme Ma Beatriz Snchez-Monroy Mnica Velasco-Torrez Mariano Martínez-Vzquez Christian Adrian Crdenas-Monroy Beatriz Hernandez-Tllez Katia Jarquín-Yez Miguel ngel Herrera-Enríquez Andrs Eliú Castell-Rodríguez 《Molecules (Basel, Switzerland)》2022,27(4)
Dendritic cells are antigen-presenting cells, which identify and process pathogens to subsequently activate specific T lymphocytes. To regulate the immune responses, DCs have to mature by the recognition of TLR ligands, TNFα or IFNγ. These ligands have been used as adjuvants to activate DCs in situ or in vitro, with toxic effects. It has been shown that some molecules affect the immune system, e.g., Masticadienonic acid (MDA) and 3α-hydroxy masticadienoic acid (3α-OH MDA) triterpenes naturally occurring in several medicinal plants, since they activate the nitric oxide synthase in macrophages and induce T lymphocyte proliferation. The DCs maturation induced by MDA or 3a-OH MDA was determined by incubating these cells with MDA or 3α-OH MDA, and their phenotype was afterwards analyzed. The results showed that only 3α-OH MDA was able to induce DCs maturation. When mice with melanoma were inoculated with DCs/3α-OH MDA, a decreased tumor growth rate was observed along with an extended cell death area within tumors compared to mice treated with DCs incubated with MDA. In conclusion, it is proposed that 3α-OH MDA may be an immunostimulant molecule. Conversely, it is proposed that MDA may be a molecule with anti-inflammatory properties. 相似文献