ICP-AES测定金合金中钆和铍含量

通过ICP-AES测定金合金中Gd和Be量各种相关因素的试验研究,建立了一个准确可靠的测定方法以替代原国标方法,适用于AuAgCuMnGd、AuAgCuGd、AuNiGd、AuBe合金中钆、铍量的测定,测定含量范围为:0.2%-2%.方法加标回收率:Gd为95.58%-99.98%,Be为96.11%-103.33%.方法测定精密度结果:Gd为1.02%.Be为4.05%.     

Dynamics of mixed lump-soliton for an extended (2+1)-dimensional asymmetric Nizhnik–Novikov–Veselov equation

A new (2+1)-dimensional higher-order extended asymmetric Nizhnik–Novikov–Veselov (eANNV) equation is proposed by introducing the additional bilinear terms to the usual ANNV equation. Based on the independent transformation, the bilinear form of the eANNV equation is constructed. The lump wave is guaranteed by introducing a positive constant term in the quadratic function. Meanwhile, different class solutions of the eANNV equation are obtained by mixing the quadratic function with the exponential functions. For the interaction between the lump wave and one-soliton, the energy of the lump wave and one-soliton can transfer to each other at different times. The interaction between a lump and two-soliton can be obtained only by eliminating the sixth-order bilinear term. The dynamics of these solutions are illustrated by selecting the specific parameters in three-dimensional, contour and density plots.     

含氮杂环润滑油添加剂抗摩擦和膜化学性能

制备了N-二异辛基-2-苯并噻唑次磺酰胺(DIMB)和2-硫酮-苯并噻唑-3-甲基鄄巯基乙酸异辛酯(MBES)两种含氮杂环抗磨添加剂, 用SRV型高温摩擦磨损试验机评价它们在芋类基础油中的抗磨减摩性能, 对它们在不同条件下形成的摩擦膜进行X射线吸收精细结构光谱(XANES)分析, 用原子力显微镜(AFM)分析摩擦膜的表面形貌. 结果表明, 添加剂DIMB和MBES具有很好的抗磨性能, 但没有减摩性能. XANES分析结果表明, 添加剂MBES形成的摩擦膜完全由硫酸亚铁组成, 而添加剂DIMB形成的摩擦膜的次表面和本体主要由二硫化铁组成, 未测量到硫酸盐或硫化铁, 但摩擦膜表面部分被氧化成硫酸亚铁. AFM 测试结果表明, 与含1.5%(w)二烷基二硫代磷酸锌(ZDDP)抗磨添加剂的钢块磨损表面相比较, 分别含1.5%(w)DIMB 和1.5%(w)MBES添加剂的钢块磨损表面出现了深而宽的“犁沟”.     

高分散的炭载Au纳米催化剂的制备、表征和催化活性

采用柠檬酸钠还原-胶体负载法, 制备了高分散的炭载Au纳米催化剂, 并以液相催化氧化葡萄糖为葡萄糖酸钠的反应评价了Au/C催化剂的活性. 研究结果表明, 金溶胶制备过程中柠檬酸钠的用量对粒子尺寸以及所获催化剂的催化活性有重要影响; 催化剂在多次使用之后活性的降低可能是由于在活性炭表面金粒子活性位点上形成的Au^δ＋-O^δ－化合态减少的缘故. 同时比较了制备的Au/C和商业Pd/C催化剂对葡萄糖的液相催化氧化反应, 证明Au/C催化剂明显优于Pd/C催化剂.     

Analytical solution of transverse oscillation in cyclotron using LP method

We have carried out an approximate analytical solution to precisely consider the influence of magnetic field on the transverse oscillation of particles in a cyclotron.The differential equations of transverse oscillation are solved from the Lindstedt-Poincare method.After careful deduction,accurate first-order analytic solutions are obtained.The analytical solutions are applied to the magnetic field from an isochronous cyclotron with four spiral sectors.The accuracy of these analytical solutions is verified and confirmed from comparison with a numerical method.Finally,we discussed the transverse oscillation at v_0=N/2,using the same analytical solution.