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1.
Synthesis and Crystal Structure of Ag2(admtrz)2(CF3CO2)2(admtrz=4—amino—3,5—dimethyl—1,2,4—triazole)
1 INTRODUCTION Transition metal complexes bridged by 1, 2, 4-triazole group can produce interesting structures and specific properties[1]. Many attempts have been made to synthesize a variety of complexes with paramagnetic centers by using such ligands, and their structures and magnetic properties have been characterized[2]. However, the polynuclear Ag(I) complexes bridged by 1, 2, 4-triazole have been poorly studied[3]. Recently, we have prepared a series of silver(I) triazole complex… 相似文献
2.
Gui Jia-Cheng Han Lu Du Cai-Xia Yu Xin-Ning Hu Kun Li Lu-Hai 《Journal of Solid State Electrochemistry》2021,25(3):973-982
Journal of Solid State Electrochemistry - Label-free electrochemical immunosensors (EIs) are simple and sensitive in cancer diagnosis. Electrode materials which can offer a large specific area and... 相似文献
3.
以氯化铜、硫脲为反应物,通过溶剂热法合成了具有不同形貌的微纳米分级结构CuS晶体,研究了不同反应介质对材料的形貌、晶体结构以及反应产量等的影响。结果表明,以N,N-二甲基甲酰胺(DMF)为溶剂,可以得到微米级六角花状CuS晶体,以乙二醇或者水/DMF混合物为溶剂,得到的CuS晶体为微米球花状,CuS晶体的产量随着溶剂中水所占比例的增大,呈现先上升后下降的结果,当VDMF:VH2O=1:1时得到CuS的最大产量,为理论产量的64.5%。当VDMF:VH2O=2:1时得到的CuS晶体具有良好的光催化活性,能够在氙灯模拟的自然光照射2.5 h以内使罗丹明B污染物溶液的脱色率达到96.7%。 相似文献
4.
A modified variable-coefficient projective Riccati equation mapping method is applied to (2 + 1)-dimensional Wick-type stochastic generalized Broer-Kaup system. With the help of Hermit transformation, we obtain a series of new exact stochastic solutions to the stochastic Broer-Kaup system in the white noise environment. 相似文献
5.
Jia-Cheng Liu Jing Cao Wen-Ting Deng Bao-Hua Chen 《Journal of chemical crystallography》2011,41(6):806-810
Abstract
A new Ag(I) complex [AgL]n (HL = 1H-1,2,4-triazole-1-methylene-1H-benzimidazole-1-acetic acid) was synthesized, and characterized by elemental analysis, IR spectra. The X-ray crystal structure of the complex was determined. The complex crystallizes in the Monoclinic system, space group p2(1)/n with a = 10.418(4) ?, b = 8.526(3) ?, c = 14.319(5) ?, β = 105.700(5)°, V = 1224.3(8) ?3, Z = 4. The complex has two-dimensional motif. The complex and free ligand display photoluminescence at room temperature. A quasi-reversible redox couple for the complex is observed. 相似文献6.
A free-air ionization chamber in low-energy X-ray has been designed and manufactured at theNational Institute of Metrology (NIM, China) according to the defination of alr-kerma. The results of a preliminary test show that the leakage current of ionization chamber is around 2×10<'-15>A, and the correction factor of ion recombination for the ionization chamber is also obtained. The free-air ionization chamber is suitable for the primary standard in low-energy X-rays. 相似文献
7.
采用H2O2化学预处理石墨毡,并将过渡金属氧化物Ce O2负载到石墨毡上,制备出复合石墨毡阴极材料。研究结果表明H2O2处理可增加石墨毡的含氧官能团,改善表面亲水性,进而提高Ce O2的负载量,XRD分析表明石墨毡表面负载的Ce O2为萤石结构。电化学阻抗谱(EIS)和循环伏安曲线(CV)分析表明修饰后的石墨毡电荷传输阻力变小,氧化还原电流强度显著增强,活性表面积增大8倍,线性扫描(LSV)实验表明改性石墨毡在氧还原过程中具有较大的电流密度,是未改性前的8.5倍。采用改性石墨毡作为阴极,进行电芬顿催化降解甲基橙测试,20 min脱色率达到96.8%,与未改性石墨毡相比,去除率提高133.2%,显著提高了其电催化氧化性能。 相似文献
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介绍了用盐水解制备超细均分散球形 Ti O2 的方法 ,详细讨论了浓度、酸度、阴离子、陈化时间、锻烧温度等因素对制备超细球形 Ti O2 的影响 ,用透射电镜和粒度分析仪分析了 Ti O2 的粒度和形貌 ,得到了均匀分散性好 ,金红石型结构 ,2μm左右的球形 Ti O2 . 相似文献
9.
在Er3+/Yb3+共掺TeO2-WO3-ZnO玻璃中引入Ce3+,研究了Ce3+对Er3+1.5μm发射性能及其上转换发光性能的影响.结果表明,随Ce3+浓度的增加Er3+1.5μm波段的荧光强度先增强后降低,优化的Ce3+掺杂浓度在2.07×1020/cm3左右;1.5μm波段的荧光寿命则随Ce3+浓度的增加有轻微降低,从3.4ms降到3.0ms,但Ce3+浓度的增加对1.5μm波段的荧光半高宽基本无影响;Er3+/Ce3+间的交叉弛豫Er3+(4I11/2+Ce3+(2F5/2→Er3+(4I13/2+Ce3+(2F7/2使玻璃的上转换发光强度大大降低,但在过高的Ce3+浓度下,Er3+/Ce3+间的另一交叉弛豫Er3+(4I13/2+Ge3+(2F5/2→Er3+(4I15/2+Ce3+(2F7/2则使Er3+4I13/2能级粒子数减少,导致1.5μm波段荧光强度和荧光寿命降低. 相似文献
10.
Chen Zhangxu Fu Ming-Lai Huang Xiao-Dan Yuan Baoling Yang Jia-Cheng E. 《Research on Chemical Intermediates》2018,44(10):6369-6385
Research on Chemical Intermediates - To enhance photocatalytic activity spectra area of the TiO2 based photocatalyst, and to separate and recycle photocatalyst easily, magnetic photocatalyst was... 相似文献