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排序方式: 共有391条查询结果,搜索用时 15 毫秒
1.
Jean-Christophe Breton 《Comptes Rendus Mathematique》2002,334(2):135-138
We are interested in the laws of multiple stable stochastic integrals defined by LePage series representation (see [1,6]). We continue the study begun in [1] giving conditions ensuring absolute continuity of joint laws of stable integrals. To this way, we apply a stratification method on the Skorokhod space on which we first take back the problem. To cite this article: J.-C. Breton, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 135–138 相似文献
2.
Valérie Michaut Jean-Marc Paris Jean-Christophe Plaquevent 《Journal of fluorine chemistry》2007,128(8):889-895
Herein are studied new transformations of ethyl-4,4,4-trifluoroacetoacetate (ETFAA), giving access to a series of enantiopure chirons bearing both a trifluoromethyl group and an amino moiety. The key intermediate is obtained optically pure by a resolution procedure. 相似文献
3.
István E. MarkóJean-Christophe Vanherck Ali AtesBernard Tinant Jean-Paul Declercq 《Tetrahedron letters》2003,44(16):3333-3336
Upon treatment with tBuOK/H2O, a variety of ω-halo-β-keto-ketals undergo smooth cyclisation, affording in excellent yields mono-protected [n,m] spiro bicyclic diketones. This transformation is highly stereoselective producing, in all cases, the diastereoisomerically pure spiro derivatives. 相似文献
4.
Carlier J Arscott S Thomy V Camart JC Cren-Olivé C Le Gac S 《Journal of chromatography. A》2005,1071(1-2):213-222
We report here on an integrated microfabricated device dedicated to the preparation of biological samples prior to their on-line analysis by electrospray ionization-mass spectrometry (ESI-MS). This microfluidic device is fabricated using the negative photoresist SU-8 by microtechnology techniques. The device includes a chromatographic module plus an ESI interface for MS. The chromatographic module is dedicated to sample purification and is based on a polymer monolithic phase which includes hydrophobic moieties. The ESI interface is integrated onto the chip and is based on a capillary slot. We present here the integration of these different modules onto a single system that is fabricated via a SU-8-based microtechnology route. We present also their testing for the purification of peptide samples. This started with a partial integration step with the combination of at least two of the modules (microsystem + monolith; microsystem + nib) and their test before the fabrication and testing of fully integrated microsystems. 相似文献
5.
The General Rate model has been developed and solved to describe protein adsorption in an expanded bed. The model takes into account axial and local variation of particle size distribution (PSD), external and intra-particle mass transfer resistances, and dispersion in liquid phase. The influence of PSD on breakthrough profiles has been analysed. The simulation results show that for a significantly high expanded bed the lower part of the breakthrough curve profiles, calculated for local particle size distribution (LPSD) and for axial average particle size distribution (APSD) are very similar. However, the upper part of breakthrough profiles calculated for LPSD approaches inlet concentration much more slowly than those calculated for APSD. The retention times of the lower part of uptake curves calculated with average particle diameter are constantly shorter than those obtained from LPSD. For the calculation of the dynamic capacity (DC), the LPSD can be replaced by APSD for large expanded bed heights. Using breakthrough profiles calculated for average particle size, DC values are constantly underestimated. 相似文献
6.
We describe an algorithm for selecting the n-th largest element (where 0<<1), from a totally ordered set ofn elements, using at most (1+(1+o(1))H())·n comparisons whereH() is the binary entropy function and theo(1) stands for a function that tends to 0 as tends to 0. For small values of this is almost the best possible as there is a lower bound of about (1+H())·n comparisons. The algorithm obtained beats the global 3n upper bound of Schönhage, Paterson and Pippenger for <1/3. 相似文献
7.
Jean-Christophe Zwick Pierre Voge Vladimir Mange Gervals Chapuis 《Helvetica chimica acta》1987,70(5):1231-1249
A stereoselective synthesis of tricarbonyl-[((1RS,2RS,4RS,5RS,6RS)-C-5,6,C-η-(5,6,7,8,-tetramethylidenbicyclo[2.2.2]octan-2-ol)]iron ( 11 ),and of its tosylate 12 and benzoate 13 is reported. The bulk of the ‘endo’-Fe(CO))3 moiety and of the ester groups in 13 renders its Diels-Alder additions to methyl propynoate ( 15 )), butynone ( 16 ), and 1-cyanovinyl acetate highly ‘para’ regioselective. The cycloadditions of diene-alcohol 11 are either ‘meta’- or ‘para’-regioselective depending on the nature of the dienophile. In the presence of BF 3. Et 2O, the addition of 11 to methyl vinyl ketone is highly stereo- (Alder mode) and ‘para’-regioselective, giving adduct 52 (tricarbonyl [((1 RS,4RS,8RS,9RS,10RS,12RS)-C,9,10,C-η-(12-hydroxy-9,10-dimethylidenetricyclo[6.2.2.02,7]dodec-2(7)-en-4 yl methyl ketone)]iron) whose structure has been established by single-crystal X-ray crystallography. 相似文献
8.
Bonhommeau S Bréfuel N Pálfi VK Molnár G Zwick A Salmon L Tuchagues JP Sanchez Costa J Létard JF Paulsen H Bousseksou A 《Physical chemistry chemical physics : PCCP》2005,7(15):2909-2914
A quasi-quantitative photo-induced low-spin (LS)-->high-spin (HS) conversion of FeII ions has been observed in the [Fe(TRIM)2]Cl2 complex by irradiating the sample with blue light (488 nm) at 10 K. The time dependence of the HS-->LS relaxation has been studied between 10 K and 44 K by means of magnetic susceptibility measurements. These relaxation curves could be satisfactorily fitted by mono-exponential decays including tunnelling effect except for temperatures below 30 K. The introduction of a distribution of vibrational frequencies into this model improved significantly the fits in the low-temperature range and gave a good agreement with the experimental data in the whole temperature range suggesting a multi-rate relaxation process in this complex. 相似文献
9.
Ynamides react with various azides in the ruthenium-catalyzed Huisgen [3+2] cycloaddition reaction. This ruthenium-catalyzed azide-ynamide cycloaddition reaction yields 1-protected 5-amido 1,2,3-triazoles. 相似文献
10.
Results of ir and Raman investigations on trigonal layer-structured Si2Te3 single crystals are reported. The ir reflection spectrum withEc exhibits seven reststrahl-like bands, whereas the corresponding spectrum withEc shows only one very small bump. Values for
0 and
are given. The Raman spectra are very rich in structure and can only be interpreted qualitatively as being a mixture of single phonon lines and one- and two-phonon density-of-states contributions. One-phonon density-of-states effects are disorder-induced owing to the statistical occurrence of the Si atoms within the regular hexagonal Te sublattice. 相似文献