全文获取类型
收费全文 | 71篇 |
免费 | 0篇 |
专业分类
化学 | 36篇 |
力学 | 8篇 |
数学 | 3篇 |
物理学 | 24篇 |
出版年
2023年 | 1篇 |
2018年 | 1篇 |
2014年 | 1篇 |
2013年 | 1篇 |
2010年 | 2篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 1篇 |
2006年 | 8篇 |
2005年 | 2篇 |
2003年 | 3篇 |
2001年 | 1篇 |
2000年 | 14篇 |
1999年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1974年 | 3篇 |
排序方式: 共有71条查询结果,搜索用时 15 毫秒
1.
Garcia Ruano JL Alcudia A del Prado M Barros D Maestro MC Fernandez I 《The Journal of organic chemistry》2000,65(10):2856-2862
The addition of the lithium anions derived from (R)- and (S)-methyl and -ethyl p-tolyl sulfoxides to (S)-N-benzylidene-p-toluenesulfinamide provides an easy access route to enantiomerically pure beta-(N-sulfinyl)amino sulfoxides. Stereoselectivity can be achieved when the configurations at the sulfur atoms of the two reagents are opposite (matched pair), thus resulting in only one diastereoisomer, even for the case in which two new chiral centers are created. The N-sulfinyl group primarily controls the configuration of the carbon bonded to the nitrogen, whereas the configuration of the alpha-sulfinyl carbanion seems to be responsible for the level of asymmetric induction, as well as for the configuration of the new stereogenic C-SO carbon in the reactions with ethyl p-tolyl sulfoxides. An efficient method for transforming the obtained beta-(N-sulfinyl)amino sulfoxides into optically pure beta-amino alcohols, based on the stereoselective non-oxidative Pummerer reaction, is also reported. 相似文献
2.
3.
Two polyesters containing rigid biphenyl and hydroquinone bisbenzoate groups and presenting flexible thioether moieties with different lengths (14 elements in the flexible group) have been carried out using a reaction of the Michaël type. The properties of these polyesters have been compared to those of polyesters of the same type presenting shorter flexible groups (11 elements). All these polymers present thermotropic properties: the biphenyl ones are smectic and the bisbenzoate ones are nematic. The biphenyl polyesters present two types of dielectric relaxations: α and β. The bisbenzoate ones show three relaxations, α and two β (β and β′). The lengthening of the flexible group increases significantly the flexibility of the molecular chains. 相似文献
4.
Garcia Ruano JL Alemparte C Martin Castro AM Adams H Rodriguez Ramos JH 《The Journal of organic chemistry》2000,65(23):7938-7943
The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles. 相似文献
5.
6.
The space group of alpha(')-NaV2O5 turns below T(c) = 34 K from Pmmn with all V sites equivalent, into Fmm2 with three independent vanadium sites per layer. This is incompatible with models of charge ordering into V4+ and V5+. Our structure determination indicates that the phase transition consists of a charge ordering with three distinct valence states, formally V4+, V4.5+, and V5+. The singlet formation is not associated with dimerization on the spin ladder, but with the formation of spin clusters. Finally, we ascribe the quadrupling of the c axis to the large polarizability of the V2O5 skeleton. 相似文献
7.
Acoustic performance in ultrasonic transmitters can be improved by means of a suitable electrical driving response and matching/tuning networks. It is important to predict this electrical response, but doing so is not easy because it departs notably from the nominal pattern with the loading probes. In practice, the analysis of HV pulser spikes in NDE applications requires fairly complex models in the transient regime and, in addition, non-linear problems could arise, especially in the case of tuned transmitters. In this paper, the most relevant influences of loading characteristics of NDT ultrasonic probes on the pulser electrical driving responses are evaluated in time and frequency domains. Conventional pulse generators and typical NDE pulsers are considered. Driving responses are analysed across commercial ultrasonic probes and, alternatively, across similar purely electrical loads. Distinct influences on pulser responses from electrical and motional sections of the probes are identified. All these aspects are studied on the basis of experimental and computer results. 相似文献
8.
In order to investigate sizing effect in composite materials, we studied three types of composites, with different sizings. Dynamic mechanical analysis appeared to be a good way to characterize the α relaxation process of composites and their interphases. Results showed that α relaxation temperature shifted to higher temperatures for composites without sizing. Study of sizing extract/resin blend showed too that interphase was a mixture of polyvinyl acetate and cyanate resin. The results allow us to deduce that a plastification effect of resin by sizing could occur, with modification of crosslink density. Moreover, we can think that all resin is affected by sizing and the conversion rate in interphase is not total. 相似文献
9.
Photocrosslinkable telomers based on cinnamoyl derivatives of polyacrylates and methacrylates can be prepared either by reaction of cinnamoyl chloride with telomers of hydroxy-2-ethyl acrylate and methacrylate, or by direct telomerisation of β-cinnamoylethyl acrylate and methacrylate. The first method gives products containing at least 70% of the theoretical maximum olefinic unsaturation but with low n [1–20]; the second method gives telomers of high n with the maximum number of cinnamoyl side-chains. 相似文献
10.