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排序方式: 共有166条查询结果,搜索用时 15 毫秒
1.
2.
J. P. Doumerc J. M. Cocciantelli J. C. Grenier M. Pouchard P. Hagenmuller 《无机化学与普通化学杂志》1993,619(4):748-752
Magnetic susceptibility of V2O5 and of the α-, ?-, δ- and γ-LixV2O5 bronzes prepared either at high or at room temperature has been measured between liquid helium and ambient temperature. The results are representative of the localized character of the V4+ ion d-electron and, for high enough x-values, of the existence of antiferromagnetic interactions in a low dimensional system. The intrachain exchange integral J has been determined using the Bonner/Fischer model for Heisenberg chains with S = 1/2 spin. It is larger for the γ- than for the δ-phase. This result as well as the occurrence of long range ordering below TN ≈ 130 K in the γ-phase may be ascribed to ordering of V4+ and V5+ ions in the former bronze and to the random distribution of V4+ ions in the latter one. 相似文献
3.
Jean-Claude Grenier Grard Schiffmacher Paul Caro Michel Pouchard Paul Hagenmuller 《Journal of solid state chemistry》1977,20(4):365-379
In order to check the extended defect model previously proposed for the nonstoichiometric perovskite AnMnO3n−1 (n 2), the Ca2Ti2−2xFe2xO6−x solid solution has been studied by means of X-ray diffraction and electron microscope investigations. The results show the existence of a continuous evolution (0 x 1) with two different regions. Close to the CaTiO3 composition (0 x 0.40) the oxygen vacancies seem to be randomly distributed and the symmetry remains pseudocubic. In the composition range 0.55 x 1, the electron microscope patterns show an ordering of the defects: the oxygen vacancies are ordered in the (0k0) planes in strings parallel to the [101] direction. It is concluded from these observations that perpendicular to the Oy direction isolated planes of tetrahedra arranged in rows separate planes of corner-linked octahedra. The n = 2; 2.5; 3, et 4 terms of the AnMnO3n−1 series have been identified. C.S. planes characteristic of classical nonstoichiometric oxides with small cations do not appear: instead, tetrahedra planes succeed to the previous octahedra planes as the degree of nonstoichiometry increases.
Résumé
Afin de vérifier le modèle de non-stoechiométrie proposé dans un travail précédent pour les perovskites lacunaires AnMnO3n−1 (n 2), la solution solide Ca2Ti2−2xFe2xO6−x a été, étudiée par diffraction X et microscopie électronique. Les résultats montrent l'existence d'une évolution continue (0 x 1) avec deux domaines différents. Pour les compositions proches de CaTiO3 (0 x 0.40), les lacunes oxygénées semblent être distribuées statistiquement et la symétrie demeure pseudocubique. Dans le domaine de compositions 0.55 x 1, les images de microscopie électronique montrent un ordre des défauts: les lacunes d'oxygène sont ordonnées dans les plans (0k0) en rangées parallèles à la direction [101]. Ces observations ont permis de conclure que perpendiculairement à la direction Oy des plans isolés de files de tétraèdres séparent des plans d'octaèdres liés par leurs sommets. Les termes n = 2; 2.5; 3 et 4 des séries AnMnO3n−1 ont été identifiés. Des plans de cisaillement rencontrés dans les oxydes non-stoechiométriques classiques de petits cations n'ont pas été mis en évidence: par contre, des plans de tétraèdres se substituent aux plans d'octaèdres initiaux lorsque le degré de non-stoechiométrie augmente. 相似文献4.
Abe K Akagi T Anthony PL Antonov R Arnold RG Averett T Band HR Bauer JM Borel H Bosted PE Breton V Button-Shafer J Chen JP Chupp TE Clendenin J Comptour C Coulter KP Court G Crabb D Daoudi M Day D Dietrich FS Dunne J Dutz H Erbacher R Fellbaum J Feltham A Fonvieille H Frlez E Garvey D Gearhart R Gomez J Grenier P Griffioen KA Hoibraten S Hughes EW Hyde-Wright C Johnson JR Kawall D Klein A Kuhn SE Kuriki M Lindgren R Liu TJ Lombard-Nelsen RM Marroncle J Maruyama T Maruyama XK McCarthy J Meyer W 《Physical review letters》1995,74(3):346-350
5.
A nearly stoichiometric SrCoO3 phase had been prepared up to now only using high oxygen pressure. A new method for preparing fully stoichiometric SrCoO3 has been proposed using electrochemical oxidation. Brownmillerite-type SrCoO2.50 is oxidized into a completely stoichiometric perovskite at a potential of 500 mV for 180 hours at room temperature in alkaline media (1 M KOH). The oxidized phase has a cubic unit cell (a=383.5 pm). It is metallic and, at temperatures below T=280 K, it shows ferromagnetic behavior. The magnetic moment at 0 K is 2.1 μB. The physical properties of SrCoO3.00 have been explained in terms of partial occupancy of a σ*e band. 相似文献
6.
7.
LoSecco JM Bionta RM Biewitt G Bratton CB Casper D Chrysicopoulou P Claus R Cortez BG Errede S Foster GW Gajewski W Ganezer KS Goldhaber M Haines TJ Jones TW Kielczewska D Kropp WR Learned JG Lehmann E Park HS Reines F Schultz J Seidel S Shumard E Sinclair D Sobel HW Stone JL Sulak L Svoboda R van der Velde JC Wuest C 《Physical review letters》1985,54(21):2299-2301
8.
Marie-Florence Grenier-Loustalot Frderic Joubert Philippe Grenier 《Journal of polymer science. Part A, Polymer chemistry》1993,31(12):3049-3063
The aim of the present work was to identify and follow the main and side reactions involved in the ring dehydration of amic acid prepared from “bridged” dianhydrides whose central substituent is an electron acceptor or donor, and an aromatic diamine. Several isomeric structures may appear as a result of the opening reactivity and selectivity of anhydride groups towards the aromatic amine. Reaction mechanisms and kinetics were thus studied in solvent phase with HPLC and 13C-NMR and in solid molten phase by FTIR and solid 13C-NMR. The experimental conditions (liquid and solid) and the structure of the products (type of central substituent) affecting the mechanisms and kinetics of the reactions were noted. © 1993 John Wiley & Sons, Inc. 相似文献
9.
10.
E. Pollert J. Hejtmnek K. Kní
ek M. Mary
ko J. P. Doumerc J. C. Grenier J. Etourneau 《Journal of solid state chemistry》2003,170(2):368-373
The electric and magnetic properties of the perovskites Nd0.8Na0.2Mn(1−x)CoxO3 (0x0.2) prepared by the usual ceramic procedure were investigated. The insulator-to-metal-like (IM) transition, closely related to a ferromagnetic arrangement, was revealed for the composition of x=0.04 and a similar tendency was detected for x=0. The insulating behavior persists down to low temperatures for higher contents of cobalt ions in spite of the transition to the bulk ferromagnetism. The properties are interpreted in terms of the steric distortion, tilting of the Mn(Co)O6 octahedra and the double-exchange interactions of the type Mn3+–O2−–Mn4+and Mn3.5+δ–O2−–Co2+, respectively. Presence of antiferromagnetic domains in the ferromagnetic matrix for the most of cobalt-substituted samples is supposed. 相似文献