全文获取类型
收费全文 | 650篇 |
免费 | 18篇 |
国内免费 | 2篇 |
专业分类
化学 | 567篇 |
晶体学 | 2篇 |
力学 | 14篇 |
数学 | 15篇 |
物理学 | 72篇 |
出版年
2021年 | 4篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 17篇 |
2015年 | 17篇 |
2014年 | 18篇 |
2013年 | 83篇 |
2012年 | 25篇 |
2011年 | 36篇 |
2010年 | 29篇 |
2009年 | 31篇 |
2008年 | 36篇 |
2007年 | 30篇 |
2006年 | 29篇 |
2005年 | 19篇 |
2004年 | 15篇 |
2003年 | 28篇 |
2002年 | 19篇 |
2001年 | 8篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1995年 | 9篇 |
1994年 | 8篇 |
1992年 | 3篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 11篇 |
1979年 | 5篇 |
1978年 | 9篇 |
1977年 | 6篇 |
1976年 | 12篇 |
1975年 | 6篇 |
1973年 | 7篇 |
1960年 | 14篇 |
1957年 | 4篇 |
1956年 | 6篇 |
1955年 | 3篇 |
1954年 | 5篇 |
排序方式: 共有670条查询结果,搜索用时 15 毫秒
1.
Azizollah Habibi Leyla Mousavifar Issa Yavari Mohammad R. Yazdanbakhsh 《Monatshefte für Chemie / Chemical Monthly》2007,4(8):603-606
Alkyl isocyanides undergo a smooth reaction with alkylidene Meldrum’s acids in the presence of arylhydroxylamines to produce N
1-alkyl-2-(3,5-dioxo-2-aryltetrahydro-4-isoxazolyl)alkanamides in high yields. 相似文献
2.
We propose a normal form for nonlinear control systems with scalar output. We follow an approach proposed by Poincaré and adapted for control systems by Kang and Krener which consists of analyzing, step-by-step, the action of the change of coordinates on the system. To cite this article: I.A. Tall, M. Balde, C. R. Acad. Sci. Paris, Ser. I 341 (2005). 相似文献
3.
Fatma M. Abdel-Gawad Yousry M. Issa Hussein M. Fahmy Hanan M. Hussein 《Mikrochimica acta》1998,130(1-2):35-40
Three simple, quick and sensitive spectrophotometric methods are described for the determination of ciprofloxacin. The methods are based on the reaction of this drug as ann-electron donor with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), 7,7,8,8,-tetracyanoquinodimethane (TCNQ) andp-chloranil (CL) as -acceptors to give highly coloured complex species. The coloured products are quantitated spectrophotometrically at 460, 843 and 550 nm for DDQ, TCNQ and CL, respectively. Optimization of the different experimental conditions is described. Beer's law is obeyed in the concentration ranges 5–50, 1.5–15 and 20–200 g ml–1 ciprofloxacin, but the concentration ranges for best accuracy are 10–48, 2.5–15 and 35– 195 g ml–1 of drug for DDQ, TCNQ and CL, respectively. The relative standard deviations are less than 1.5%. Applications of the suggested methods to ciprofloxacin tablets are presented and compared with the USP method. The stability constants of the 11 DDQ and CL complexes were 1.086 × 104 and 2.581 × 104 lmol–1, respectively, whereas for the 12 TCNQ complex it was 3.62 × 1081. mol–1. 相似文献
4.
A new rapid and accurate method for the spectrophotometric microdetermination of Cu(II) and Pd(II) using some 1,3,5-triphenylformazans (I) is given. The optimum conditions for the formation of the complexes are extensively investigated. The ligands form 1:1 and 1:2 (M:L) complexes with Cu and Pd ions, Beer's law is obeyed up to 3.8 and 6.5 ppm Cu and Pd respectively. The influence of foreign ions is investigated. The ligands were used successfully as indicators in spectrophotometric titration of Cu and Pd ions with EDTA and CDTA. 相似文献
5.
I. M. Issa Dr. K. A. Idriss M. M. Seleim 《Monatshefte für Chemie / Chemical Monthly》1977,108(6):1461-1469
The reaction of 1,4-(2-sulpho-4-methylanilino)anthraquinone (quinizarin green,QG) and its non-sulphonated derivative (NSQG) with Ce(III), Th(IV), and U(VI) was investigated. Spectrophotometric and conductometric studies were carried out to investigate the stoichiometry of the complexes formed. The studies revealed the formation of 11 and 12 (ML) complexes. The apparent stability constants of the different complexes were determined. The structure of the ligand in the solid chelates was studied by IR spectrophotometry which showed that the chelate formation takes place through the oxygen of the C=O group and the -imino nitrogen.
Mit 6 Abbildungen 相似文献
Mit 6 Abbildungen 相似文献
6.
Mohamed Shaaban Marwa Y. Issa Mohamed A. Ghani Abdelaaty Hamed Ahmed B. Abdelwahab 《Natural product research》2019,33(1):24-33
During our continual searching programme for novel bioactive metabolites from Sarcophyton trocheliophorum, collected from Red Sea, we describe herein the isolation and structural elucidation of further two new pyrane-based cembranoid diterpenes: 9-hydroxy-7,8-dehydro-sarcotrocheliol (1) and 8,9-expoy-sarcotrocheliol acetate (2), along with the well-known sarcotrocheliol acetate (3), (+)-sarcophine (4), (+)-sarcophytoxide (5) and (-)-sarcophytoxide (6). The chemical structures of compounds 1 and 2 were determined on the basis of 1D and 2D NMR (1H, 13C, 1H–1H COSY, HMQC, HMBC and NOE), mass spectra (ESI and HR-ESIMS) and by comparison with related structures. The antimicrobial activities of the reported compounds 1–6 were investigated. According to the molecular docking study of compounds 1–6 using 3D structure of α,β tubulin in complex with taxol (PDB code 1JFF) and epothilone A (PDB code 1TVK), sarcophine (4) displayed the highest affinity towards both crystal structures, followed by 5 and 6, meanwhile pyrane-based cembranoid diterpenes (1–3) showed less affinity. 相似文献
7.
The effects of acidity, fluoride concentration, temperature and concentration of manganese in the reaction between KMnO(4) and Mn(II) were studied potentiometrically. The rate of reaction is increased by increasing the fluoride concentration and/or decreasing the acidity of the solution. The formal redox potentials of the MnO(-)(4)/Mn(III) and the Mn(III)/Mn(II) systems were determined at different pH values. The E degrees values obtained by extrapolation to pH = 0 were 1.58 and 1.52 V respectively. The amount of Mn(II) determined was varied from 5 to 56 mg. The net reaction can be represented as MnO(-)(4) + 10HF(-)(2) + 4Mn(2+) right harpoon over left harpoon 5MnF(-)(4) + 2H(+) + 4H(2)O. 相似文献
8.
Issa Yavari 《Tetrahedron letters》2006,47(9):1477-1481
Alkyl isocyanides react with 2-hydroxybenzaldehyde or 2-hydroxy-5-nitrobenzaldehyde to afford N-alkyl-2-aryl-2-oxoacetamides and N2,N4-dialkyl-2-aryl-4H-1,3-benzodioxine-2,4-dicarboxamides in nearly 1:1 ratios. Treatment of 2,6-dimethylphenyl isocyanide with 2-hydroxy-5-nitrobenzaldehyde affords only the 2-oxoacetamide derivative. 相似文献
9.
Simple, rapid, accurate, and sensitive spectrophotometric methods are described for the determination of dicyclomine hydrochloride. The methods are based on the reaction of this drug as an n-electron donor with 2,3-dichloro-5,6-dicyano-p-benzoqunione (DDQ), p-chloranilic acid (p-CA), and chloranil (CL) as pi-acceptors to give highly colored complex species. The colored products are measured spectrophotometrically at 456, 530, and 650 nm for DDQ, p-CA, and CL, respectively. Optimization of the different experimental conditions were studied. Beer's law was obeyed in concentration ranges of 20-100, 50-250, and 80-600 microg/mL for DDQ, pCA, and CL, respectively. Colored complexes are produced in organic solvents and are stable for at least 1 h. The methods were applied to Spasmorest antispasmotic tablets and ampoules with good accuracy and precision. 相似文献
10.
Issa RM Fayed TA Awad MK El-Kony SM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):980-986
The absorption spectra of mono- and bis-azo-derivatives obtained by coupling the diazonium salts of aromatic amines and 2,7-dihydroxynaphthalene have been studied in six organic solvents. The different absorption bands have been assigned and the effect of solvents on the charge transfer band is also discussed. The diagnostic IR spectral bands and 1H NMR signals are assigned and discussed in relation to molecular structure. Also, semi-empirical molecular orbital calculations using the atom superposition and electron delocalization molecular orbital (ASED-MO) theory have been performed to investigate the molecular and electronic structures of these compounds. According to these calculations, an intramolecular hydrogen bonding is essential for stabilization of such molecules. 相似文献