全文获取类型
收费全文 | 710篇 |
免费 | 30篇 |
国内免费 | 1篇 |
专业分类
化学 | 392篇 |
晶体学 | 6篇 |
力学 | 67篇 |
数学 | 44篇 |
物理学 | 232篇 |
出版年
2022年 | 7篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 7篇 |
2016年 | 11篇 |
2015年 | 13篇 |
2014年 | 18篇 |
2013年 | 28篇 |
2012年 | 36篇 |
2011年 | 22篇 |
2010年 | 17篇 |
2009年 | 25篇 |
2008年 | 29篇 |
2007年 | 32篇 |
2006年 | 39篇 |
2005年 | 30篇 |
2004年 | 30篇 |
2003年 | 37篇 |
2002年 | 23篇 |
2001年 | 23篇 |
2000年 | 12篇 |
1999年 | 19篇 |
1998年 | 8篇 |
1997年 | 15篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 16篇 |
1993年 | 21篇 |
1992年 | 9篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1989年 | 11篇 |
1988年 | 11篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1980年 | 10篇 |
1979年 | 13篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 10篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1924年 | 2篇 |
1884年 | 2篇 |
排序方式: 共有741条查询结果,搜索用时 15 毫秒
1.
2.
3.
There is a high correlation between molecular surface area (TSA) of triorganotin and triorganolead compounds and their toxicity towards a bacterium (Escherichia coli) and an alga (Selenastrum capricornutum). Parallel attempts to correlate other Group IVA organometals incorporating silicon or germanium were unsuccessful. It was further demonstrated, however, that a high correlation was obtainable between certain series of compounds with the same organic substituent but different metal centers involving all Group IVA elements. In both instances, the inability to obtain a quantitative structure-activity relationship (QSAR) for all systems studied appears to be a function of the solubility of the compounds. While organotin TSA values have been found to correlate well with their toxicities toward various organisms, this study clearly suggests that this type of QSAR can be readily extended to include other organometal systems, provided that there is no solubility problem and the toxicity is a function of the hydrophobicity of the organometal compounds. 相似文献
4.
5.
6.
D. Seweryniak P. J. Woods B. Blank M. P. Carpenter T. Davinson S. J. Freeman J. Grres A. Heinz R. V. F. Janssens H. Mahmud T. L. Khoo Z. Liu G. Mukherjee E. Rehm F. Sarazin J. Shergur M. Shawcross S. Sinha A. Woehr 《Physics letters. [Part B]》2004,590(3-4):170-175
The fusion–evaporation reaction 10B(12C, 2n) was used to make the first observation of in-beam γ decays from the astrophysically important nucleus 20Na, lying adjacent to the proton drip-line. All states below the proton threshold in 20Na were populated and identified in the experiment. These include new levels, previously unresolved levels, and states located with improved energy precision. The level structure of 20Na, and its γ transitions, are compared to the mirror partner 20F measured simultaneously in this experiment. In particular, a high degree of energy stability is found for all negative parity states. These results are discussed in the context of the nuclear shell model. 相似文献
7.
C. Andreoiu D. Rudolph I. Ragnarsson C. Fahlander R.A.E. Austin M.P. Carpenter R.M. Clark J. Ekman R.V.F. Janssens T.L. Khoo F.G. Kondev T. Lauritsen T. Rodinger D.G. Sarantites D. Seweryniak T. Steinhardt C.E. Svensson O. Thelen J.C. Waddington 《The European Physical Journal A - Hadrons and Nuclei》2002,14(3):317-348
High-spin states in 59Cu were populated using the fusion-evaporation reaction 28Si + 40Ca at a beam energy of 122 MeV. The Gammasphere Ge-detector array in conjunction with the 4π charged-particle detector array
Microball allowed for the detection of γ-rays in coincidence with evaporated light particles. The resulting extensive high-spin
decay scheme of 59Cu is presented, which comprises more than 320 γ-ray transitions connecting about 150 excited states. Their spins and parities
have been assigned via directional correlations of γ-rays emitted from oriented states. Average quadrupole moments of rotational
bands have been determined from the analysis of residual Doppler shifts. Shell model calculations in the fp shell are invoked to study some of the low-spin states, while the experimental characteristics of the rotational bands are
analyzed in the configuration-dependent cranked Nilsson-Strutinsky (CNS) approach.
Received: 15 February 2002 / Accepted: 23 April 2002 相似文献
8.
9.
10.
Zusammenfassung Für Elementbestimmungen in Abwasser wird ein Röntgenfluorescenzverfahren beschrieben. Zur Probenvorbereitung werden die Elemente durch Gefriertrocknung auf einem inerten Träger angereichert. Diese Anreicherung ist nicht selektiv und erfaßt praktisch alle in Abwasser gelösten und suspendierten Verunreinigungen. Für die Berechnung der Elementkonzentrationen aus den gemessenen Fluorescenzintensitäten wird ein Matrixkorrekturverfahren angegeben, welches dem unterschiedlichen Absorptionsverhalten der Probenmatrix Rechnung trägt. Die Massenabsorptionskoeffizienten werden durch Messung der diffus gestreuten Bremsstrahlung bzw. der Comptonstreustrahlung ermittelt. Die Selbstabsorption des zu bestimmenden Elementes wird rechnerisch berücksichtigt. Das Korrekturverfahren kann auf alle mit Röntgenfluorescenzanalyse bestimmbaren Elemente angewendet werden.
Determination of elements in waste water by x-ray fluorescence analysis: Sample preparation and matrix correction method
Summary For sample preparation the elements are enriched upon an inert carrier by freeze-drying. This enriching procedure is not selective and collects all dissolved and suspended contaminations from the waste water. In order to calculate the element concentrations from the measured fluorescence intensities a matrix correction method is given which considers the different absorption behaviour of the matrix. The mass absorption coefficients are obtained by measuring the scattered X-ray tube spectrum or a Compton scattered X-ray tube line, respectively. The self-absorption of the element to be determined is taken into account. The correction method is applicable to all elements detectable by X-ray fluorescence.
Herrn Dr. H. Wagner danken wir für das stete Interesse, die zahlreichen konstruktiven Diskussionen und die Hilfe beim Abfassen des Manuskripts. 相似文献