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排序方式: 共有1224条查询结果,搜索用时 328 毫秒
1.
Dr. Yogesh Kumar Maurya Dr. Pingchun Wei Takahide Shimada Dr. Kazuhisa Yamasumi Dr. Shigeki Mori Prof. Dr. Ko Furukawa Dr. Hajime Kusaba Prof. Dr. Tatsumi Ishihara Prof. Dr. Yongshu Xie Dr. Masatoshi Ishida Prof. Dr. Hiroyuki Furuta 《化学:亚洲杂志》2021,16(7):743-747
A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials. 相似文献
2.
Hiroto Kudo Nobuhito Ito Keiji Nakajima Masami Ochiai Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4421-4429
The polyaddition of fluorine‐containing bis(epoxide)s and fluorine‐containing triazine di(aryl ether)s were examined to give the corresponding fluorine‐containing poly(cyanurate)s. It was observed that the synthesized fluoropolymers had good thermal stabilities and good film‐forming properties. The glass transition temperatures (Tg's) and refractive‐indices (nD's) of synthesized polymers were determined by differential scanning calorimetry and ellipsometry, respectively, and it was found that the values of Tg's and nD's were supported by their fluorine containing ratios and skeletons. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4421–4429, 2007 相似文献
3.
Takeshi Murashige Hideo Fujikake Hiroto Sato Hiroshi Kikuchi Taiichiro Kurita Fumio Sato 《Optical Review》2004,11(6):349-352
We have confirmed light diffraction of aligned polymer fibers obtained by a phase separation of an anisotropic-phase solution of liquid crystal and polymer. He—Ne laser light passing through the polymer fibers was scattered in the axis vertical to the fibers, and had two peaks of light intensity symmetrical to the center of the transmitting laser spot. The two peaks were found to be caused by light diffraction due to the periodic polymer-fiber dispersion because the peaks corresponded to values calculated by intervals between the fibers. The periodical fiber networks are considered to be formed by anisotropic spinodal decomposition. This effect can be used to measure the dispersion order of the polymer fibers. © 2004 The Optical Society of Japan 相似文献
4.
Curved Ferroelectric Liquid Crystal Matrix Displays Driven by Field-Sequential-Color and Active-Matrix Techniques 总被引:1,自引:0,他引:1
Hideo Fujikake Hiroto Sato Takeshi Murashige Yoshihide Fujisaki Taiichiro Kurita Tadahiro Furukawa Fumio Sato 《Optical Review》2006,13(1):14-19
This paper describes a curved field-sequential-color matrix display using fast-response ferroelectric liquid crystal. Black
matrix and transparent electrode patterns were formed on a thin plastic substrate by a transfer method from a glass substrate.
While a composite film of liquid crystal and micro-polymers of walls and fibers was formed between the flexible substrates
by printing, laminating and curing processes of a solution of monomers and liquid crystal, the mechanical stability was enhanced
by use of multi-functional monomers to form large display panels. The image pixels of the matrix panel were driven by an active
matrix scheme using an external switch transistor array at a frequency of 180 Hz for intermittent three-primary-color backlight
illumination. The flexible A4-paper-sized color display with 24 × 16 pixels and 60 Hz field frequency was demonstrated by
illuminating it with sequential three-primary-color lights from light-emitting diodes of the backlight. Our display system
is useful in various information displays because of its freedom of setting and location. 相似文献
5.
H. Sunaoshi Y. Fukashiro M. Furukawa M. Yamauchi S. Hayashibe T. Shinozuka M. Fujioka I. Satoh M. Wada S. Matsuki 《Hyperfine Interactions》1993,78(1-4):241-245
The ground state hyperfine splitting of87Sr+ was measured with a precision of 1×10–8. The experiments were performed with an RF ion trap connected to an ISOL (isotope separator on-line), where all the possible transitions between Zeeman sublevels were observed by a laser-microwave double resonance method. The magnetic dipole hyperfine constant was determined to beA=–1 000 473.673 (11) kHz. 相似文献
6.
Yoshitomo Ono Naoyuki Kawashima Hiroto Kudo Tadatomi Nishikubo Takabumi Nagai 《Journal of polymer science. Part A, Polymer chemistry》2007,45(14):2978-2988
The ring‐opening copolymerization of a glycidyl ester derivative having a benzophenone group and the donor–acceptor norbornadiene (D‐A NBD) dicarboxylic acid, 5‐(4‐methoxyphenyl)‐1,4,6,7,7‐pentamethyl‐2,5‐norbornadiene‐2,3‐dicarboxylic acid, monoglycidyl ester derivatives with D‐A NBD dicarboxylic anhydride using tetraphenylphosphonium bromide as a catalyst proceeded smoothly to give novel self‐photosensitizing NBD polymers in good yields. The molecular weight of these polyesters was about 4,000, and lower than that of analogous NBD polymers having no benzophenone group. All the synthesized NBD polymers isomerized smoothly to the corresponding quadricyclane (QC) polymers upon UV irradiation in tetrahydrofuran (THF) solution and in the film state. The rate of the photoisomerization of the D‐A NBD moieties in these polymers was higher than that of the D‐A NBD moieties in the polymer having no photosensitizing group. Furthermore, the rate of the photoisomerization of the D‐A NBD moieties in these polymers was also higher than that of the NBD polymer with low molecular weight photosensitizer in dilute solution. The photo‐irradiated polymers having QC moieties released thermal energies of 146–180 J/g. The D‐A NBD moieties contained in these NBD polymers possessed fair to good fatigue resistance. The degradation of the NBD moieties in these polymers was 15–30% after 50 repeated cycles of interconversion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2978–2988, 2007 相似文献
7.
Akikazu Matsumoto Daisuke Furukawa Hideyuki Nakazawa 《Journal of polymer science. Part A, Polymer chemistry》2006,44(17):4952-4965
We report the stereocontrol of diene polymers by the topochemical polymerization of alkoxy-substituted benzyl muconates in the solid state. A monomer stacking structure is controlled by the weak intermolecular interactions in the monomer crystals, depending on the structure and position of the alkoxy-substituent. The translational and alternating types of molecular stacking structures in a column provide diisotactic and disyndiotactic polymers, respectively, by the solid-state polymerization under UV and γ-ray irradiation. On the other hand, the meso and racemo structures of the resulting polymers are determined by the molecular symmetry of the used muconate monomers. The various substituted benzyl ester polymers are transformed into the same ethyl ester polymers with the four types of tacticities. The structure and crystallization behavior of the substituted benzyl ester polymers as well as the ethyl ester polymers have been revealed in detail. We clarify the effects of the tacticity on the crystallization property of the stereoregular polymuconates. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4952–4965, 2006 相似文献
8.
9.
Tasuku Nakajima Takayuki Kurokawa Hidemitsu Furukawa Qiu Ming Yu Yoshimi Tanaka Yoshihito Osada Jian Ping Gong 《高分子科学》1996,(1):1-9
Living tissues work with fantastic functions in soft and wet gel-like state. Thus, hydrogels have attracted much attention as excellent soft & wet materials, suitable for making artificial organs for medical treatments.However, conventional hydrogels are mechanically too weak for practical uses. We have created double network (DN) hydrogels with extremely high mechanical strength in order to overcome this problem. DN gels are interpenetrating network (IPN) hydrogels consisting of rigid polyelectrolyte and soft neutral polymer. Their excellent mechanical properties cannot be explained by the standard fracture theories. In this paper, we discuss about the toughening mechanism of DN gels in accordance with their characteristic behavior, such as large hysteresis and necking phenomenon. We also describe the results on tissue engineering application of DN gels. 相似文献
10.
Hiroto Yoshida Yasuhito YamaryoJoji Ohshita Atsutaka Kunai 《Tetrahedron letters》2003,44(8):1541-1544
Base-free oxidative homocoupling reaction of arylboronic esters has been found to proceed using a catalytic amount of a palladium-1,3-bis(diphenylphosphino)propane (DPPP) complex under an oxygen atmosphere, affording a variety of biaryls in modest to excellent yields. Even arylboronic esters bearing a base-sensitive functional group are applicable to the reaction. 相似文献