全文获取类型
收费全文 | 1007篇 |
免费 | 60篇 |
国内免费 | 5篇 |
专业分类
化学 | 777篇 |
晶体学 | 10篇 |
力学 | 33篇 |
数学 | 108篇 |
物理学 | 144篇 |
出版年
2024年 | 3篇 |
2023年 | 9篇 |
2022年 | 33篇 |
2021年 | 40篇 |
2020年 | 38篇 |
2019年 | 35篇 |
2018年 | 28篇 |
2017年 | 24篇 |
2016年 | 70篇 |
2015年 | 33篇 |
2014年 | 42篇 |
2013年 | 124篇 |
2012年 | 54篇 |
2011年 | 59篇 |
2010年 | 43篇 |
2009年 | 36篇 |
2008年 | 51篇 |
2007年 | 42篇 |
2006年 | 42篇 |
2005年 | 39篇 |
2004年 | 37篇 |
2003年 | 28篇 |
2002年 | 15篇 |
2001年 | 12篇 |
2000年 | 11篇 |
1999年 | 10篇 |
1998年 | 2篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 7篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 9篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1963年 | 1篇 |
排序方式: 共有1072条查询结果,搜索用时 0 毫秒
1.
Saleh Z. M. Nasser H. Özkol E. Günöven M. Abak K. Canli S. Bek A. Turan R. 《Journal of nanoparticle research》2015,17(10):1-12
Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting... 相似文献
2.
D-3-Hydroxybutyrate dehydrogenase (BDH) is an NAD(+)-dependent dehydrogenase of the mitochondrial inner membrane involved in the energetic balance between the liver and peripheral organs in mammals. It allows the conversion of ketone bodies (acetoacetate and D-3-hydroxybutyrate) and it is one of the best documented lipid-requiring enzymes with a dependence on lecithins. After release of proteins from the membrane by phospholipase A2 treatment of salt-treated mitochondria, the rat liver enzyme is absorbed on controlled-pore glass beads. After batch washing, the enzyme, devoid of lipids (apoBDH), is specifically eluted at pH 8.05-8.15 with a 0.1 M Tris-1 M LiBr buffer under reducing conditions (5 mM dithiothreitol). It appears that during BDH absorption, the glass beads mimic the phospholipid surface of biomembranes. 相似文献
3.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
4.
Ti(IV) as TiCl3(O3SCF3) and TiO(O2CCF3)2 are used as efficient catalysts for oxidative coupling of aliphatic, aromatic and heteroaromatic thiols to their disulfides in the presence of NaI under air atmosphere. 相似文献
5.
We consider an initial boundary value problem for a nonlinear differential system of two equations. Such a system is formed by the equations of compressible miscible flow in a one-dimensional porous medium. No assumption about the mobility ratio is involved. Under some reasonable assumptions on the data, we prove the existence of a global weak solution. Our basic approach is the semi-Galerkin method. We use the technique of renormalized solutions for parabolic equations in the derivation ofa prioriestimates. 相似文献
6.
M. I. Nasser M. A. Moharram 《International Journal of Infrared and Millimeter Waves》1989,10(1):73-82
In this work, the temperature dependence of the intensities of the IR absorption bands corresponding to the fundamental vibrations, overtones and combination frequencies of diphenyl is presented. A thorough discussion of the interpretation of the fundamental modes of vibration has been made on the basis of the temperature dependence of the intensities of these absorption bands.The structure of the diphenyl molecule has been the subject of numerous investigations. Despite a considerable amount of work on the Raman(1), IR(3,4,5) and ultraviolet (2) spectra, the assignment of the fundamental frequencies has not yet been established with certainty, Some assistance can be obtained from the temperature dependence of the IR spectrum of this material. 相似文献
7.
The interaction between poly(methymethacrylate) (PMMA) and poly(vinyl chloride) (PVC) has been studied indilute urea solutions of dimethylformamide (DMF) at 28℃ using a dilute solution viscometry method. The results show thatthe polymer mixtures are compatible in DMF solution in the absence of urea. The influence of urea addition on the degree ofcompatibility of the polymer mixtures has been studied in terms of the compatibility parameters (△b_m and △[η]_m). It wasfound that the compatibility of the polymer mixtures is decreased with increasing urea addition, passing through a minimumat 0.5 M urea. 相似文献
8.
Nasser R. El-Brollosy Claus Nielsen Erik B. Pedersen 《Monatshefte für Chemie / Chemical Monthly》2005,12(2):1247-1254
A series of Emivirine and GCA-186 analogues substituted at N-1 with indan-1-yloxymethyl (6a–6c) and indan-2-yloxymethyl (6d–6f) were synthesized by reaction of the corresponding bis(indanyloxy)methans with uracils having 5-ethyl or 5-isopropyl and 6-benzyl or 6-(3,5-dimethylbenzyl) substituents. A route to the corresponding N-1 substituted 4-hydroxybut-2-enyloxymethyl analogue was also devised. All newly synthesized compounds showed potent activity against wild-type HIV-1, the most active compound being 5-ethyl-1-(indan-1-yloxymethyl)-6-(3,5-dimethylbenzyl)uracil (6b), which was 50-fold more active than Emivirine. 相似文献
9.
Abdou O. Abdelhamid Cyril Prknyi S. M. Khaledur Rashid Winston D. Lloyd 《Journal of heterocyclic chemistry》1988,25(2):403-405
Substituted 2-arylbenzimidazoles, 2-arylbenzoxazoles and 2-arylbenzothiazoles were obtained in good yield by the reaction of hydroximoyl chlorides with ortho-substituted aromatic amines. The benzo moiety of the benzimidazoles was shown by nmr to be symmetrical, indicating that the N-H group proton of the imidazole ring is exchanging with the water protons in the DMSO-d6 solvent. 相似文献
10.
A. L. M. Nasser L. P. Mazzolin C. A. Hiruma-Lima L. S. Santos M. N. Eberlin A. R. Monteiro de Souza Brito W. Vilegas 《Chromatographia》2006,64(11-12):695-699
The methanolic extract of the bark of the medicinal plant Qualea parviflora (Vochysiaceae) contains new nor-seco-triterpene and pentacyclic triterpenoids. They were separated in a preparative scale using droplet counter-current chromatography. The optimum solvent used was composed of a mixture of CHCl3/MeOH/H2O (43:37:20, v/v) in the descending mode and led to a successful separation of the new compound 28-nor-17, 22-seco-2α, 3β, 19, 22, 23-pentahydroxy-Δ12-oleanane, besides the known triterpenoids bellericagenin B, bellericaside B and arjunglucoside I . Identification was performed by ESI-MS, 1H NMR and 13C NMR analyses. 相似文献