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排序方式: 共有482条查询结果,搜索用时 31 毫秒
1.
Xu Mengtao Li Changyou Sun Yang Yang Tianzhi Zhang Hongzhuang Liu Zhendong Liu Haiyang Li Zhenyuan Zhang Yimin 《Nonlinear dynamics》2021,105(4):3061-3092
Nonlinear Dynamics - Investigation of the dynamic characteristics of linear guideway is essential for enhancing structural performance of machine tools. However, few mechanical models are... 相似文献
2.
Nonlinear Dynamics - Based on a mixed control strategy, this study addresses the finite-time stabilization with extended dissipativity for Markov jump systems (MJSs) with unreliable... 相似文献
3.
用激光溅射 分子束技术研究了气相中Ni的等离子体与甲醇分子团簇的反应 .观察到Ni+ (CH3 OH) n、NiO+ (CH3 OH) n、H+ (CH3 OH) n、H3 O+ (CH3 OH) n 四个种类的团簇正离子和CH3 O-(CH3 OH) n(n≤ 2 5 )一种团簇负离子 .详细考察了激光烧蚀等离子体作用于脉冲分子束的不同位置时 ,对团簇产物种类和团簇尺寸大小的影响 .发现NiO+ (CH3 OH) n 是由Ni+ (CH3 OH) n 团簇内的脱甲烷反应生成的 ,而H+ (CH3 OH) n、H3 O+ (CH3 OH) n主要是激光等离子体中的电子与甲醇团簇碰撞电离产生的 相似文献
4.
资源有限网络计划的PRWI启发式优化方法 总被引:1,自引:0,他引:1
本文在综合考虑了有资源约束的网络计划结构特征、资源强度、时间约束等方面因素的基础上,提出了一种新的资源优化的启发式优化方法—PRWI方法,并通过分析证明了该方法处理问题的效果较现有的其它方法好。 相似文献
5.
Two novel dithienylethenes with ferrocene units were synthesized by Wittig reaction. The structure of 2a has been established by X‐ray diffraction studies. They could reversibly interconvert between two thermally stable forms, an open and a closed one, using light of different wavelengths as triggers. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
6.
粘度法研究高分子溶液行为的实验改进(Ⅱ) 总被引:13,自引:0,他引:13
高分子在粘度计毛细管管壁上的吸附不仅会导致毛细管有效管径减小,而且可以导致毛细管界面性质发生显著改变,具体表现为测定高分子溶液流过时间t之前和之后纯溶剂的流过时间t0和t0′与高分子溶液流过时间t对浓度作图外推到浓度为零时的值t0^*并不一致。不同温度时聚乙烯吡咯烷酮(PVP)水溶液粘度测定结果表明,当吸附讷发子显著改变了毛细管界面性质时,需要将高分子溶液粘度测定方法由t/t0′改为t/t0^*。经过改进的粘度测定方法不仅更加普适合理,而且更加简单有效。 相似文献
7.
Haiyang Gao Junkai Zhang Yan Chen Fangming Zhu Qing Wu 《Journal of molecular catalysis. A, Chemical》2005,240(1-2):178-185
Herein reported are investigations of norbornene polymerization by novel anilido–imino nickel complexes [(Ar1NCHC6H4NAr2)NiBr]2 (Ar1 = Ar2 = 2,6-dimethylphenyl, 1; Ar1 = 2,6-dimethylphenyl, Ar2 = 2,6-diisopropylphenyl, 2; Ar1 = Ar2 = 2,6-diisopropylphenyl, 3; Ar1 = 2,6-diisopropylphenyl, Ar2 = 2,6-dimethylphenyl, 4) activated with methylaluminoxane (MAO). It was found that at polymerization temperatures below 50 °C, the average molecular weights of the obtained polynorbornenes catalyzed by these four catalytic systems increase with raising temperature, displaying bimodal distribution in GPC curves. The abnormal influence of polymerization temperature could be attributed to the existence of two kinds of catalytic species: heterobimetallic species LNi(II)(μ-Me)2AlMe2 (I) and monometallic species LNi(II)Me (II) (L = anilido–imino ligand) at lower temperature. The former affords a lower molecular weight polymer and the latter higher molecular weight one. With raising polymerization temperature above 50 °C, the species I disappears and only species II exists in polymerization systems, resulting in a normal relation of molecular weight to polymerization temperature. From a kinetic study of the norbornene polymerization catalyzed by 1/MAO catalyst at 70 °C, the polymerization rate (Rp) can be expressed by the formulation: Rp = k[NBE]1.93[Ni]0.88. Moreover, the mechanism of the norbornene polymerization using the anilido–imino nickel complexes activated with MAO is also presented and discussed. 相似文献
8.
Ying Liu Wenqing Liu Haiyang Li Yong Yang Shuang Cheng 《International journal of quantum chemistry》2007,107(2):396-402
Ab initio molecular orbital and density functional theory (DFT) in conjunction with different basis sets calculations were performed to study the N? H…O and S? H…O blue‐shifted H‐bonds in the HNO…HFSO2 complex. The geometric structures, vibrational frequencies, and interaction energies were calculated by both standard and CP‐corrected methods. Natural bond orbital (NBO) analysis was used to investigate the origin of blue‐shifted H‐bonds, showing that the decrease in the σ*(N? H) and σ*(S? H) is due to the electron density redistribution effect. The structure reorganization effect on the blue‐shifted hydrogen bonds was discussed in detail. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
9.
10.
Tonggang Jiu Yongjun Li Haiyang Gan Yuliang Li Huibiao Liu Shu Wang Weidong Zhou Chunru Wang Xiaofang Li Xiaofeng Liu Daoben Zhu 《Tetrahedron》2007,63(1):232-240
The oligo(p-phenylene vinylene)-porphyrin-oligo(p-phenylene vinylene) (P-OPVn, n=2, 4, where n is the number of phenyl rings) and the complex with Zn2+ based on P-OPVn were synthesized for investigating their photophysical properties via UV-vis, voltammetry, steady-state and time-resolved fluorescence spectra. In these molecules two OPV moieties as energy donors were linked to porphyrin center by virtue of Wittig reaction. The detailed studies of photophysical properties indicate that OPV group can act as an antenna unit for effective intramolecular energy transfer. 相似文献