全文获取类型
收费全文 | 635篇 |
免费 | 13篇 |
国内免费 | 1篇 |
专业分类
化学 | 353篇 |
晶体学 | 18篇 |
力学 | 20篇 |
数学 | 117篇 |
物理学 | 141篇 |
出版年
2019年 | 5篇 |
2018年 | 7篇 |
2016年 | 8篇 |
2015年 | 10篇 |
2014年 | 10篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 28篇 |
2010年 | 9篇 |
2009年 | 19篇 |
2008年 | 30篇 |
2007年 | 26篇 |
2006年 | 29篇 |
2005年 | 21篇 |
2004年 | 23篇 |
2003年 | 22篇 |
2002年 | 16篇 |
2001年 | 10篇 |
2000年 | 8篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 13篇 |
1995年 | 13篇 |
1994年 | 9篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 9篇 |
1990年 | 14篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 10篇 |
1985年 | 5篇 |
1984年 | 12篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 10篇 |
1980年 | 12篇 |
1979年 | 10篇 |
1978年 | 16篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 21篇 |
1974年 | 8篇 |
1973年 | 9篇 |
1972年 | 8篇 |
1971年 | 11篇 |
1970年 | 9篇 |
1969年 | 7篇 |
1967年 | 5篇 |
排序方式: 共有649条查询结果,搜索用时 15 毫秒
1.
2.
Haim Gvirtzman Mordeckai Magaritz Eugenia Klein Arie Nadler 《Transport in Porous Media》1987,2(1):83-93
Cold stage Scanning Electron Microscopy (SEM) with a rapid cooling technique makes it possible to investigate the water phase within unsaturated porous media. It is thought that this technique preserves the main features of the micromorphology of the water menisci as it exists in the liquid phase in soils. Saddle-shaped elements, as well as pendular rings of water, were observed with concave and convex curvatures of the water-air interface. The hydraulic conductivity of an unsaturated soil may be inferred from SEM photographs. Observations of isolated water menisci indicate the existence of an immobile water domain. The surface geometry of the water menisci was analyzed quantitatively and surface tension and capillary pressure were determined. 相似文献
3.
4.
Dynamics of changes in microstresses during thermal decomposition of Cu(HCOO)2 crystals and their effect on the thermal decomposition kinetics were studied by IR spectroscopy at 105 to 120 °C. The formation of solid intermediate HCOOCu was observed, and the dynamics of its accumulation was followed. Kinetic regularities of transformation of HCOO groups were compared with those for gas evolution.For Communication 1, see Ref. 1.Translated from Izvestiya va Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 350–354, February, 1996. 相似文献
5.
6.
7.
Michal Shahar Haim Meshulam Shlomo Margel 《Journal of polymer science. Part A, Polymer chemistry》1986,24(2):203-213
Two sytrene derivatives formylstyrene and styrene sulfonylcholoride, were synthesized. Polymeric microspheres in diameters ranging from 0.1 to 2 μm were synthesized by polymerization of chlormoethylstyrene, formylstyrene, and styrene sulfonylcholoride in organic solvents, in the presence of appropriate surfactants. The kinetics of microsphere formation were studied. The molecular weight distribution of the products was determined by gel permeation chromatography. Conditions for binding various amino ligands to the microspheres were also established. 相似文献
8.
The paper shows the ability of the fluorochrome tris(2,2'-bipyridine) ruthenium (II) (Rubipy) to detect heparan sulfate, heparin, and heparinase activity of M3 murine mammary adenocarcinoma cells as well as bacterial heparinases I, II, and III in native polyacrylamide gel electrophoresis (PAGE). The technique is based on the electrophoretic mobility of high molecular weight heparins and subsequent staining with Rubipy (50 micrograms/mL). The minimum content of heparin detected by fluorescence in a UV transilluminator was 25-50 ng. The number of Rubipy molecules bound to heparin, determined in relationship to the number of disaccharide units (DU), showed that two to six heparin disaccharide units are bound by each fluorochrome molecule. Scatchard plot analysis showed one Rubipy-binding site (Kd = (8.56 +/- 2.97) x 10(-5) M). Heparinase activity was determined by densitometric analysis of the fluorescence intensity of the heparin-containing band of the gel. While heparinase I (EC 4.2.2.7.) degraded heparin and, to a lower degree, partially N-desulfated N-acetylated heparin (N-des N-Ac), heparinase II (no EC number) could efficiently degrade heparan sulfate (HS) and partially N-des N-Ac heparin. Finally, heparinase III (EC 4.2.2.8.) degraded HS almost exclusively. Only heparin and N-des N-Ac heparin were substrates for M3 tumor cell heparinases. We describe a qualitative, sensitive and simple method to detect heparinase activity and determine its substrate specificity using Rubipy fluorescence with heparin and heparan sulfate in multiple biological samples tested in parallel. 相似文献
9.
G. V. Gavrilova A. A. Aleshkin V. A. Nikanorov D. P. Krut'ko V. I. Rozenberg O. A. Reutov 《Russian Chemical Bulletin》1995,44(3):502-506
A novel method for the synthesis of the oxime of 4-methyl-2,4,6-cycloheptatrien-1-one (Eschenmoser's oxime) is proposed. The method involves redox enlargement of the ring of 4-dibromomethyl-4-methyl-2,5-cyclohexadien-1-one oxime through the action of Ni(PPh3)4 in DMF (in the presence of Zn). The product is formed as a mixture ofsyn- andanti-forms readily interconverting in solutions. A similar reaction of 4-methyl-4-trichloromethyl-2,5-cyclohexadien-1-one oxime afforded the dimer of agem--centered semiquinoid carbene (1,2-bis-(1-methyl-4-oxyimino-2,5-cyclohexadienyl)-1,2-dichloroethylene), together withsyn- andanti-isomers of 4-chloro-5-methyl-2,4,6-cycloheptatrien-1-one oxime, which are readily separable but also quickly interconverting in solutions. For the latter compounds, the complete1H NMR assignment of the stereoisomeric structures has been carried out.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 519–523, March, 1995.The authors are grateful to the International Science Foundation (Grant MHW000) as well as the Russian Foundation for Basic Research (Project No. 94-03-08873) for the financial support of the work. 相似文献
10.
The synthesis of a new ligand system for mono- and bimetallic complexes based on a calixarene is described. Ligand BBPC (3, bis(bipyridine)-calix[4]arene) is obtained in three steps in 40% overall yield by first brominating one of the methyl groups of the 4,4'-dimethyl-2,2'-bipyridine in two steps and subsequently reacting it with p-tert-butylcalix[4]arene under basic conditions. Reaction of BBPC (3) with 2 equiv of [Rh(NBD)(2)]BF(4) or [Rh(NBD)(CH(3)CN)(2)]BF(4) (NBD = norbornadiene) produces the bimetallic compound BBPC[Rh(NBD)BF(4)](2) (4). Treatment of the ligand with PdCl(2)(CH(3)CN)(2) leads to the isolation of the bimetallic complex BBPC[PdCl(2)](2) (5). When the nickel precursor NiBr(2)(DME) (DME = dimethoxyethane) is reacted with BBPC, the bimetallic complex BBPC[NiBr(2)](2) (6) is isolated which, upon crystallization from methanol, gives the mononuclear bis(bipyridine) complex BBPC[NiBr(OMe)] (7). Full characterization includes X-ray structural studies of complexes 4, 5, and 7. The bimetallic compounds 4 and 5 show metal to metal distances of 4.334 A (for 4) and 3.224 A (for 5). For all three complexes, unique molecular packing arrangements were found, based on hydrophobic/hydrophilic interactions. 相似文献