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排序方式: 共有119条查询结果,搜索用时 15 毫秒
1.
Guenter Werth 《Hyperfine Interactions》2006,172(1-3):125-134
Experiments in ion traps on the g factors for the free and the bound electron in low-Z, hydrogen-like ions have provided the most accurate tests of quantum-electrodynamics calculations. Moreover they have been
used to determine new and precise values for fundamental constants. Extensions to more stringent tests using ions of higher
values of the nuclear charge Z are on the way. Also other QED tests such as Lamb shifts or hyperfine structures in H-like ions using traps will be feasible
in the near future. The tests in bound systems, however, will be limited by nuclear structure effects which are difficult
to calculate. Assuming the QED calculations as correct, the experimental results may be used to determine nuclear contributions
and thus support nuclear models.
Contribution presented at the TCP06, Vancouver Island, 2006. 相似文献
2.
Lui Lam Flonnie Dowell Helmut Brand Guenter Ahlers 《Journal of statistical physics》1991,64(5-6):899-901
3.
Certain contaminants at trace concentrations in surface waters can have dramatic effects on the hormonal system of organisms in the aquatic environment. Therefore, immunoanalytical methods at a very low limit of detection (LOD) and a low limit of quantification (LOQ) are becoming more and more important for environmental analysis and especially for monitoring drinking water quality. Environmental monitoring of antibiotics, hormones, endocrine disrupting chemicals, and pesticides in real water samples (e.g. surface, ground or drinking water) with difficult matrices places high demands on chemical analysis. Biosensors have suitable characteristics such as efficiency in allowing very fast, sensitive, and cost-effective detection. Here we describe an assay optimization process with a fully automated immunoassay for estrone which resulted in a LOD below 0.20 ng L−1 and a LOQ below 1.40 ng L−1. In contrast to common analytical methods such as GC-MS or HPLC-MS, the biosensor used requires no sample pre-treatment and pre-concentration. The very low validation parameters for estrone are the result of the continuous optimization of the immunoassay. The basis of our sensitive assay is the antibody with a high affinity constant towards estrone. During the optimization process, we reduced the amount of antibody per sample and improved the chip surface modification. Finally, this proceeding led to a calibration routine with an amount of antibody of only 3.0 ng per sample (sample volume: 1.0 mL). The reduction of the amount of antibody per sample results in better validation parameters (LOD, LOQ, and IC50), but this reduction leads to the current device-related limitation of the River Analyser (RIANA).For some endocrine disrupting compounds, no effect levels (NOELs) in the lower nanogram per liter range are reported. This defines the challenge, which analytical methods have to compete with and our RIANA instrument with its improved sensitivity for the detection of a single hormone in the lower nanogram per liter range is a powerful tool in aquatic analytics in addition to the common analytical methods. 相似文献
4.
Herbert Muffler Guenter Siegemund Werner Schwertfeger 《Journal of fluorine chemistry》1982,21(2):107-132
4.5-Perfluoro-1.3-dioxolanes are available by reaction of 2(α-chloroalkoxy)perfluoro-carbonyl halides or -ketone with fluoride ions. A mechanism for the intramolecular ring- closure-reaction is proposed. Hydrogen atoms at C-2 in can be exchanged photochemically by chlorine. Starting from the 2-monochloro-derivatives the 2-monofluoro-4.5-perfluoro- 1.3-dioxolanes are formed by reaction with triethylamine- hydrofluoride. 相似文献
5.
Franz Heresch Guenter Allmaier Gottfried Heinisch 《Journal of heterocyclic chemistry》1981,18(2):255-258
The electron impact mass spectrometric fragmentation of trans-3- and trans-4-styrylpyridazine is reported in detail, including a comparison with other aza-stilbenes. With regard to a distinction between the two isomeric styrylpyridazines, the intensity ratio of the M+ and [M-1]+ ions, the general degree of fragmentation and the elimination pathways of nitrogen proved to be most characteristic. 相似文献
6.
The iodine—azide reaction catalyzed by sulphur-containing compounds is followed simultaneously by optical and thermometric measurements in closed and flowing systems. In the closed system, thiosulphate can be determined in the range 32.4–324 μg ml-1, by observing the turbidity caused by the nitrogen formed during the reaction and the temperature changes. With the flow apparatus, thiosulphate can be determined in the range 112–1120 μg ml-1 by continuously mixing the sample and reagent solutions. H2S in nitrogen 5–100 ppm) is measured by sweeping the gas into the reaction Cuvette. In a third flow procedure, H2S is liberated continuously from sodium sulphide solutions (0.1–10 μg S2- ml-1) by ascorbic acid, and swept to the measuring cuvette with nitrogen. 相似文献
7.
Immunoanalytical methods at a very low limit of detection (LOD) and a low limit of quantification (LOQ) are becoming more and more important for environmental analysis and especially for monitoring drinking water quality. Biosensors have suitable characteristics such as efficiency in allowing very fast, sensitive, and cost-effective detection. Here we describe a fully automated immunoassay for estrone with a LOD below 0.20 ng L–1 and a LOQ below 1.40 ng L–1. In contrast to common analytical methods such as GC-MS or HPLC-MS, the biosensor used requires no sample pre-treatment and pre-concentration. The basis of our sensitive assay is the antibody with a high affinity constant towards estrone. The very low amount of antibody per sample results in low validation parameters (LOD, LOQ, and IC50), but this assay for estrone represents the current device-related limitation of the River Analyser (RIANA). 相似文献
8.
William R. Cullen Hao Li Spiros A. Pergantis Guenter K. Eigendorf Andrew A. Mosi 《应用有机金属化学》1995,9(7):507-515
The microorganism Apiotrichum humicola (previously known as Candida humicola) grown in the presence of either arsenate, arsenite, methylarsonic acid or dimethylarsinic acid, produces arsenic-containing metabolites in the growth medium. When L-methionine-methyl-d3 is added to the cultures, the CD3 label is incorporated intact into the metabolites to a considerable extent to form deuterated dimethylarsenic and trimethyl-arsenic species, indicating that S-adenosylmethionine, or some related sulphonium compound, is involved in the biological methylation. Conclusive evidence of CD3 incorporation in the arsenicals found in the growth medium was provided by using a specially developed hydride generation-gas chromatography-mass spectrometry system (HG–GC–MS). 相似文献
9.
热耦合型二级高频脉冲管制冷机实验研究 总被引:2,自引:2,他引:0
降低制冷温度至4 K温区是高频脉冲管制冷机的最新发展要求。本文介绍了一套热耦合型二级高频脉冲管制冷机的性能特性,它可以达到低于15 K以下的最低温度,是目前报道的高频二级脉冲管制冷机能获得的最低温度.通过对制冷机一级预冷、二级输入功率、二级冷量、室温条件等影响的分析,从实验角度揭示了该二级制冷系统的复杂影响,为进一步的深入分析和改进提供了基础。 相似文献
10.
Kuehn K Mehta S Fu H Genio E Murphy D Liu F Liu Y Ahlers G 《Physical review letters》2002,88(9):095702
We report new measurements in four cells of the thermal boundary resistance R between copper and (4)He below but near the superfluid-transition temperature T(lambda). For 10(-7)< or =t identical to 1-T/T(lambda))< or =10(-4) fits of R = R(0)t(-x(b))+R(B) to the data yielded x(b) approximately equal to 0.18, whereas a fit to theoretical values based on the renormalization-group theory yielded x(b) = 0.23. Alternatively, a good fit of the theory to the data could be obtained if the amplitude of the prediction was reduced by a factor close to 2. The results raise the question whether the boundary conditions used in the theory should be modified. 相似文献