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1.
Bounds are given on the size of the parameter-space decomposition induced by multiple sequence alignment problems where phylogenetic information may be given or inferred. It is shown that many of the usual formulations of these problems fall within the same integer parametric framework, implying that the number of distinct optima obtained as the parameters are varied across their ranges is polynomially bounded in the length and number of sequences. 相似文献
2.
Time resolved chemiluminescence spectra of pure tetramethyldioxetane are obtained for the first time using pulsed infrared laser excitation. The only major product, acetone, is shown to be formed by at least two pathways: a unimolecular, collision free, decomposition and a collision induced mechanism. Spectral and temporal behaviour indicate that neither singlet nor triplet acetone are the primary products. Other possibilities are discussed. 相似文献
3.
The synthesis of the title compound 9 is described. Benz[a]anthracene 8,9-oxide (6) was reacted with sodium azide in aqueous acetone and the trans-9-azido-8,9-dihydrobenz[a]anthr-8-ol (7), so formed, was cyclized by tri-n-butylphosphine. Attempts to dehydrogenate 10,11-dihydrobenz[a]anthracene 8,9-imine (4) with DDQ or by allylic bromination followed by base assisted dehydrobromination was unsuccessful. The N-tosyl derivative of 4, prepared from the free imine, N,O-bis(trimethylsilyl)acetamide and tosyl chloride underwent rapid aziridine-ring cleavage by the silylating agent to give trans-8,9,10,11-tetrahydro-8-(4-methyl)benzensulfon-amido-9- [(trimethyl)oxy]benz[a]anthracene (10). 相似文献
4.
A novel method is suggested to measure the absolute excited single-singlet absorption spectrum of rhodamine by bleaching completely the solution. The molar decadic extinction coefficient of the excited state (? = 4.8 × 104 liter mole?1 cm?1 at 440 nm) is estimated directly from the plateau-like absorption signal at very high excitation intensities. 相似文献
5.
Specific direct mono fluorinations on various sites of the steroidal skeleton of bile acids were achieved by introduction of electronegative groups at selected points. 相似文献
6.
Koltsov Iwona Prześniak-Welenc Marta Wojnarowicz Jacek Rogowska Anna Mizeracki Jan Malysa Maria Kimmel Giora 《Journal of Thermal Analysis and Calorimetry》2018,131(3):2273-2284
Journal of Thermal Analysis and Calorimetry - Industrially relevant nanopowder was synthesised by microwave hydrothermal synthesis to obtain well-controlled composition (ZrO2–AlO(OH) system)... 相似文献
7.
A general study is undertaken of product-wedge-diagonal (=PWD) structures on a space. In part this concept may be viewed as arising from G.W. Whitehead's fat-wedge characterization of Lusternik-Schnirelmann category. From another viewpoint PWD-structures occupy a distinguished position among those structures that provide data allowing Hopf invariants to be defined. Indeed the Hopf invariant associated with a PWD-structure is a crucial component of the structure. Our overall theme addresses the basic question of existence of compatible structures on X and Y with regard to a map X→Y. A principal result of the paper uses Hopf invariants to formulate a Berstein-Hilton type result when the space involved is a double mapping cylinder (or homotopy pushout). A decomposition formula for the Hopf invariant (extending previous work of Marcum) is provided in case the space is a topological join U*V that has PWD-structure defined canonically via the join structure in terms of diagonal maps on U and V. 相似文献
8.
The visible luminescence induced by a high-power CO2 laser in SiF4 occurs within the laser pulse even at pressures as low as 10?2 Torr. The unirnolecular nature of the process is also supported by pressure-dependence studies of the luminescence intensity and the incubation period. A possible assignment of the transition involving inverse electronic relaxation is discussed. 相似文献
9.
Giora Hon 《Physics in Perspective (PIP)》2003,5(2):150-173
10.
Ranking participants in generalized tournaments 总被引:1,自引:0,他引:1
Consider the problem of ranking social alternatives based on the number of voters that prefer one alternative to the other. Or consider the problem of ranking chess players by their past performance. A wide variety of ranking methods have been proposed to deal with these problems. Using six independent axioms, we characterize the fair-bets ranking method proposed by Daniels [4] and Moon and Pullman [14].Received: January 2005 相似文献