全文获取类型
收费全文 | 724篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
化学 | 323篇 |
晶体学 | 10篇 |
力学 | 14篇 |
数学 | 161篇 |
物理学 | 232篇 |
出版年
2021年 | 5篇 |
2020年 | 5篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 17篇 |
2015年 | 23篇 |
2014年 | 17篇 |
2013年 | 35篇 |
2012年 | 38篇 |
2011年 | 24篇 |
2010年 | 39篇 |
2009年 | 18篇 |
2008年 | 26篇 |
2007年 | 31篇 |
2006年 | 19篇 |
2005年 | 25篇 |
2004年 | 19篇 |
2003年 | 24篇 |
2002年 | 20篇 |
2001年 | 25篇 |
2000年 | 29篇 |
1999年 | 15篇 |
1998年 | 6篇 |
1997年 | 10篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 12篇 |
1993年 | 17篇 |
1992年 | 24篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1983年 | 10篇 |
1982年 | 9篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1976年 | 8篇 |
1975年 | 7篇 |
1974年 | 5篇 |
1973年 | 7篇 |
1968年 | 4篇 |
1966年 | 4篇 |
排序方式: 共有740条查询结果,搜索用时 11 毫秒
1.
O. Perru F. Ibrahim O. Bajeat C. Bourgeois F. Clapier E. Cottereau C. Donzaud M. Ducourtieux S. Galès D. Guillemaud-Mueller C. Lau H. Lefort F. Le Blanc A. C. Mueller J. Obert N. Pauwels J. C. Potier F. Pougheon J. Proust B. Roussière J. Sauvage O. Sorlin D. Verney 《Physics of Atomic Nuclei》2003,66(8):1421-1427
The PARRNe facility has been used to produce neutron-rich isotopes 83,84Gaby the ISOL method. Their decay has been studied, and β-γ coincidence and γ-γ coincidence data were collected as a function of time. The first two excited levels in 83Ge and the first excited level in 84Ge have been measured for the first time. 相似文献
2.
3.
Hyperfine Interactions - The YFe4Al8 and ErFe4Al8 intermetallics were studied by57Fe Mössbauer spectroscopy between 2 K and room temperature. The spectra are consistent with iron occupying 8f... 相似文献
4.
W. Potzel J. Moser Ulrike Potzel F. J. Litterst G. M. Kalvius J. Gal M. Boge J. Chappert J. Spirlet 《Hyperfine Interactions》1987,34(1-4):391-405
Due to the wider radial extent of 5f electrons when compared to their 4f counterparts, intermetallics of the light actinides show a broad spectrum of magnetic properties ranging from the localized magnetism of the lanthanides to the itinerant magnetism often found in transition metal compounds. One parameter which strongly influences the magnetic character of the compound is the actinide-actinide separation which can experimentally be varied by the application of high pressure. The question of 5f electron delocalization will be reviewed with respect to Moesshauer high pressure data on NpCo2si2, NpAl2, NpOs2 and new results will be presented of NpAs. The connection of hyperfine parameters with results of X-ray diffraction studies will be discussed.Work supported by the Bundesministerium für Forschung und Technologie, Federal Republic of Germany 相似文献
5.
We have demonstrated a temperature switch based on an optically bistable device integrated with an optical fibre. The principle demonstrated here might lead to the development of new types of all-optical temperature sensors. 相似文献
6.
Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co+2FeII) and ferricyanides (Co+2FeIII) in an ozone flow. The CN stretching bands occur at 2085 cm–1 for Co+2FeII and at 2160 cm–1 for Co+2FeIII. After the ozonization process of Co+2FeII, an intense band approximately at 2125 cm–1 is detected. This intermediate band must correspond to a mixed valence state of the type: FeII–CN–Co2+–NC–FeIII Mössbauer spectra recorded in situ during the ozonization of Co+2FeII show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co+2FeII after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable. 相似文献
7.
8.
9.
Böcking T Kilian KA Hanley T Ilyas S Gaus K Gal M Gooding JJ 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10522-10529
Surface modification with oligo(ethylene oxide) functionalized monolayers terminated with reactive headgroups constitutes a powerful strategy to provide specific coupling of biomolecules with simultaneous protection from nonspecific adsorption on surfaces for the preparation of biorecognition interfaces. To date, oligo(ethylene oxide) functionalized monolayer-forming molecules which can be activated for attachment of biomolecules but which can selectively form monolayers onto hydrogen terminated silicon have yet to be developed. Here, self-assembled monolayers (SAMs) containing tetra(ethylene oxide) moieties protected with tert-butyl dimethylsilyl groups were formed by thermal hydrosilylation of alkenes with single-crystal Si(111)-H. The protection group was used to avoid side reactions with the hydride terminated silicon surface. Monolayer formation was carried out using solutions of the alkene in the high-boiling-point solvent 1,3,5-triethylbenzene. The protecting group was removed under very mild acidic conditions to yield a free hydroxyl functionality, a convenient surface moiety for coupling of biological entities via carbamate bond formation. The chemical composition and structure of the monolayers before and after deprotection were characterized by X-ray photoelectron spectroscopy (XPS) and X-ray reflectometry. To demonstrate the utility of this surface for covalent modification, two reagents were compared and contrasted for their ability to activate the surface hydroxyl groups for coupling of free amines, carbonyl diimidazole (CDI), and disuccinimidyl carbonate (DSC). Analysis of XP spectra before and after activation by CDI or DSC, and after subsequent reaction with glycine, provided quantitative information on the extent of activation and overall coupling efficiencies. CDI activated surfaces gave poor coupling yields under various conditions, whereas DSC mediated activation followed by aminolysis at neutral pH was found to be an efficient method for the immobilization of amines on tetra(ethylene oxide) modified surfaces. 相似文献
10.
V. M. Leovac E. Z. Ivegeš K. Mészáros Szécsényi K. Tomor G. Pokol S. Gal 《Journal of Thermal Analysis and Calorimetry》1997,50(3):431-440
Solvate complexes of UO 2 2+ andN(1), N(4)-bis(salicylidene)-S-methylisothiosemicarbazone, (H2Me-L1), of general formula [UO2(Me-L1)S] (S= H2O, MeOH, EtOH, Py, DMF and DMSO) were synthesized. The methanolic UO 2 2+ ” adducts of N(1)-benzoylisopropylidene-N(4)-salicylidene-S-alkylisothiosemicarbazone, (H2R-L2,R=Me, Prn) of general formula [UO2(R-L2)· MeOH], were also prepared. Thermal decomposition of the complexes was investigated in air and argon. The complexes decompose to α-U3O8 in air, while in argon the decomposition is not completed up to 1000 K. The temperature and the mechanism of decomposition of the complexes are a function of the solvent belonging to the inner coordination sphere. 相似文献