全文获取类型
收费全文 | 351篇 |
免费 | 4篇 |
专业分类
化学 | 239篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 19篇 |
物理学 | 92篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 3篇 |
2013年 | 16篇 |
2012年 | 14篇 |
2011年 | 23篇 |
2010年 | 12篇 |
2009年 | 10篇 |
2008年 | 20篇 |
2007年 | 27篇 |
2006年 | 28篇 |
2005年 | 19篇 |
2004年 | 27篇 |
2003年 | 23篇 |
2002年 | 11篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 9篇 |
1998年 | 4篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 6篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有355条查询结果,搜索用时 15 毫秒
1.
The motion of a moored floating body under the action of wave forces, which is influenced by fluid forces, shape of the floating body and mooring forces, should be analysed as a complex coupled motion system. Especially under severe storm conditions or resonant motion of the floating body it is necessary to consider finite amplitude motions of the waves, the floating body and the mooring lines as well as non-linear interactions of these finite amplitude motions. The problem of a floating body has been studied on the basis of linear wave theory by many researchers. However, the finite amplitude motion under a correlated motion system has rarely been taken into account. This paper presents a numerical method for calculating the finite amplitude motion when a floating body is moored by non-linear mooring lines such as chains and cables under severe storm conditions. 相似文献
2.
3.
Akutsu H Akutsu-Sato A Turner SS Le Pevelen D Day P Laukhin V Klehe AK Singleton J Tocher DA Probert MR Howard JA 《Journal of the American Chemical Society》2002,124(42):12430-12431
Normal state conductivity and superconductivity together with bulk magnetic susceptibility and magnetization measurements have been measured for two molecular charge-transfer salts: beta' '-(ET)4[(H3O)Ga(C2O4)3]G (ET = bis(ethylenedithio)tetrathiafulvalene, G = pyridine for compound I and nitrobenzene for compound II). With the exception of the included guest molecules (G) the crystal structures are almost identical. Both show minima in their electrical transport at 130 K for I and at 160 K for II, but at lower temperatures their behaviors differ markedly. The resistance of I reaches a maximum at 50 K with a further small peak at 2 K and possible superconductivity only below 2 K, whereas that of II increases continuously down to 7.5 K, where an abrupt transition to a superconducting state occurs. 相似文献
4.
Yoshimoto S Ohashi F Ohnishi Y Nonami T 《Chemical communications (Cambridge, England)》2004,(17):1924-1925
Nanocomposites consisting of conducting polyaniline and clay minerals were successfully synthesized from mechanochemically intercalated anilinium fluoride; the nanocomposites prepared by the mechanochemical intercalation method contained much more polyaniline in the clay layers than those prepared by a conventional solution method. 相似文献
5.
Fumihiko Hasumi Yasumitsu Miyamoto Ichiro Okura 《Applied biochemistry and biotechnology》1995,55(1):1-4
Glutamate synthesis by reductive amination of 2-oxoglutarate was performed by the combination of NADH regeneration system
and glutamate dehydrogenase (GluDH). The conversion of 2-oxoglutamate to glutamate was 98% after 3 h, and the turnover number
of NAD+was 17. 相似文献
6.
The density functional theory was employed to investigate Eu(III) complexes with three beta-diketonates and two phosphine oxides (complex M1: Eu(bdk)3(TPPO)2, complex M2: Eu(bdk)3(TMPO)2, and complex M3: Eu(bdk)3(TPPO)(TMPO)) deemed to be the model complexes of the fluorescence compounds for the ultraviolet LED devices we have recently developed. For each complex, two minimum energy points corresponding to two different optimized geometries (structures A and B) have been found, and the difference of the energy between two minimum energy points is found to be quite small (less than 1 kcal/mol). Vertical excitation energies and oscillator strengths for each complex at two optimized geometries have been obtained by the time-dependent density functional theory, and the character of the excited states has been investigated. For complex M3, the absorption edge is red-shifted, and the oscillator strengths are relatively large. The efficiency of intersystem crossing and energy transfer from the triplet excited state to the Eu(III) ion is considered by calculating DeltaE(ISC) (the energy difference between the first singlet excited state and the first triplet excited state) and DeltaE(ET) (the difference between the excitation energy of the complex for the first triplet excited state and the emission energy of the Eu(III) ion for 5D to 7F). 相似文献
7.
8.
Fumihiko Hasuni Katsunori Fukuoka Shuichi Adachi Yasumitsu Miyamoto Ichiro Okura 《Applied biochemistry and biotechnology》1996,56(3):341-344
Alanine synthesis by reductive amination of pyruvate was performed by the combination of NADH regeneration system and alanine
dehydrogenase (AlaDH). The conversion of pyruvate to alanine was 99% after 1 h. Leucine synthesis was also carried out by
the combination of NADH regeneration system and leucine dehydrogenase (LeuDH). The conversion of 4-methyl-2-oxovalerate to
leucine was 60% after 1.5 h. 相似文献
9.
Akutsu H Akutsu-Sato A Turner SS Day P Canadell E Firth S Clark RJ Yamada J Nakatsuji S 《Chemical communications (Cambridge, England)》2004,(1):18-19
Three conducting BEDT-TTF charge-transfer salts with tris(oxalato)metallate anions have unit cells containing both[small alpha] and [small beta][double prime] donor packing motifs. 相似文献
10.