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1.
The FRS-ESR facility at GSI provides one of the most efficient methods for direct mass measurements. In the present experiment,
exotic nuclei were produced via fragmentation of 152Sm projectiles in a thick beryllium target at 500-600 MeV/u, separated in-flight with the fragment separator FRS, and injected
into the storage-cooler ring ESR. Time-resolved Schottky Mass Spectrometry was applied for mass measurements of stored and
electron-cooled bare and few-electron ions. 373 different nuclides were identified by means of the spectra of their revolution
frequencies. Masses for 18 nuclides (84Zr, 92Ru, 94Rh, 107,108,110Sb, 111,112,114I, 118Ba, 122,123La, 124Ce, 127Pr, 129Nd, 132Pm, 134Sm, 137Eu) have been determined for the first time. Masses for 111,112I and 113Xe have been obtained via known α-decay energies. The experiment and first results will be presented. 相似文献
2.
C. Scheidenberger K. Beckert P. Beller F. Bosch C. Brandau D. Boutin L. Chen B. Franzke H. Geissel R. Knöbel C. Kozhuharov J. Kurcewicz S. A. Litvinov Yu. A. Litvinov M. Mazzocco G. Münzenberg F. Nolden W. R. Plaß M. Steck B. Sun H. Weick M. Winkler 《Hyperfine Interactions》2006,173(1-3):61-66
One important goal of the ILIMA project at FAIR is the study of masses and decay properties of relativistic isomeric beams
stored and cooled in the planned storage-ring complex. A new scheme is described, where a storage-cooler ring is used for
high-resolution mass separation. Experimental results on the separation of the isobaric pair 140Pr-140Ce are presented.
P. Beller, deceased. 相似文献
3.
Seong J Rohrbacher A Li ZR Janda KC Tao FM Spiegelman F Halberstadt N 《The Journal of chemical physics》2004,120(16):7456-7463
The potential energy surface of He2Ne+ has been reinvestigated using a combination of ab initio and diatomics-in-molecule (DIM) calculations. In contrast to the reports of two recent studies the ion is found to have an asymmetric linear He-Ne-He structure, with no barrier to formation from the separated atoms on the ground-state surface. The He-Ne+ bond lengths at the potential minimum are 1.51 and 1.81 A, and the total bonding energy is 0.717 eV. Comparing the He2Ne+ energy to that of HeNe+, the bonding energy for the second helium atom is 0.06 eV, about 10% of that of the first He atom. The saddle point between the two equivalent minima is a symmetric structure, 0.0074 eV above the potential minimum. A symmetric geometry becomes the overall potential minimum if the 2s hole on the Ne is excluded from the reference states of a multireference configuration interaction calculation. A DIM potential was created for the HenNe+ family of ions. The DIM potential is consistent with the asymmetric He2Ne+ ion serving as a core; it predicts a slightly more asymmetric geometry than the ab initio results. Additional helium atoms form five-membered rings around the bonds of the core ion to fill the first shell and then add to the ends of the cluster. The asymmetric core ion and the highly compact structure help to account for the lack of apparent shell structure in the mass spectrometry of HenNe+ clusters. Finally, we recommend that the value De=0.63+/-0.04 eV be adopted for the ground state of HeNe+. 相似文献
4.
1,3-Dipolar Addition of 2-Benzonitrilio-2-propanid to 7-Methylthieno[2,3-c]pyridine 1,1-Dioxide and Subsequent Reactions The addition of dipole 2 , generated photochemically from 2,2-dimethyl-3-phenyl-2H-azirine ( 1 ), to 7-methylthieno[2,3-c]pyridine 1,1-dioxide yields the pyrroline derivative 4 as a major product and regioisomer 5 in low yield. Compound 4 can be transformed into the pyrrolidine derivative 11 by ring opening, loss of SO2 and hydrogenation. Bromopyrroline derivative 14 gives either by dehydrohalogenation compound 18 or, by substitution, nitrile 17 or ethoxy derivative 19 . Substitution of 14 and ring opening yields methoxypyrrole derivative 20 , which gives access to the unstable hydroxypyrrole and hydroxypyrrolidine derivative 28 resp. 30 . The vinylsulfone 18 is the starting material for addition-ring-cleavage reactions. Oxidation of pyrroline derivative 4 gives epoxy-substituted N-oxide 39 and di-N-oxide 40 ; and oxidative transformation of pyrrolidine derivative 11 yields the (hydroxymethyl)pyridylpyrrolidine derivative 45 . 相似文献
5.
A total synthesis of the optically active tetrahydroesterastin β -lactam analogue 2 using Miller's hydroxamate approach is described (Scheme 2). Significant modification of published procedures has resulted in a short and facile stereospecific preparation of the N-[(benzyloxycarbonyl)methyl]-β -lactam 17 starting from the readily available D -serine. This material served as intermediate for the preparation of a variety of N-[(benzyloxycarbonyl)methyl]tetrahydroesterastin β-lactam analogues (Scheme 5). 相似文献
6.
7.
Ferrocenecarbothioamide (1) and its N-ethoxycarbonyl derivative (2) were synthesised by a Friedel-Crafts type reaction of ferrocene with potassium thiocyanate and ethoxycarbonyl isothiocyanate, respectively, in a strongly acidic medium. The X-ray structure of 1 was determined and shows conjugation between the ferrocene moiety and the thioamido group. Compound 1 reacts with chloroacetylferrocene affording 2,4-diferrocenylthiazole, whose structure was determined by X-ray diffraction and electronic properties studied by cyclic voltammetry. 相似文献
8.
Addition of dimethyl phosphite to racemic 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene-2-carboxaldehyde gives almost exclusively one diastereomer of the corresponding α-hydroxyphosphonate (d.r. ?96:4). Its absolute configuration (S, Rp)-(R, Sp) was established by X-ray diffraction. 相似文献
9.
Claude Aslangul Alain Veillard Raymond Daudel Fernand Gallais 《Theoretical chemistry accounts》1971,23(3):211-225
Résumé On propose un exemple quantitatif de la distinction entre une liaison de covalence et une liaison de coordination; cette différenciation, fondée sur les propriétés de la molécule une fois formée, semble très nette pour les énergies de liaison, les populations de recouvrement et les charges des groupes; en particulier, un critère récent, proposé par deux des auteurs, est remarquablement vérifié. Enfin, on essaie de préciser la signification des symboles chimiques traditionnels.
Les auteurs tiennent à remercier très vivement M. M. Berthier et Millié d'avoir mis à leur disposition le programme de localisation indispensable à ce travail, ainsi que Mademoiselle Le Guen et le C.I.R.C.E. pour la réalisation des calculs sur l'ordinateur IBM 360-75. 相似文献
Quantitative studies of the difference between a covalence and a coordination bond: The molecules of amine-borane and aminoborane
An illustration of the distinction between these two types of chemical bonds is proposed, which is based on the properties of the molecule once built. Bond energies, overlap populations and group charges vary considerably from one compound to the other; more, a recent criterion given by two of the authors seems to be particularly suitable for describing the character of the bond. Lastly, one tries to give an explicit signification to the usual chemical symbols.
Zusammenfassung Es wird ein quantitatives Beispiel der Unterscheidung zwischen einer kovalenten und einer koordinativen Bindung angegeben, die auf den Eigenschaften des vorliegenden Moleküls beruht. Sie erscheint sehr günstig für die Bindungsenergien, die Überlagerungspopulationen und die Gruppenladungen. Insbesondere wird ein Kriterium, das kürzlich von zwei der Autoren angegeben wurde, gut verifiziert. Schließlich wird versucht, die üblichen chemischen Symbole zu präzisieren.
Les auteurs tiennent à remercier très vivement M. M. Berthier et Millié d'avoir mis à leur disposition le programme de localisation indispensable à ce travail, ainsi que Mademoiselle Le Guen et le C.I.R.C.E. pour la réalisation des calculs sur l'ordinateur IBM 360-75. 相似文献
10.
Karolina Chrabąszcz Dr. Andrzej Błauż Martyna Gruchała Marcin Wachulec Dr. Błażej Rychlik Prof. Damian Plażuk 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(20):6254-6262
Two series of the ferrocenyl and ruthenocenyl analogues of etoposide bearing 1,2,3-triazolyl or aminoalkyl linker were synthesized and evaluated for their cytotoxic properties, influence on the cell cycle, ability to induce tubulin polymerization, and inhibition of topoisomerase II activity. We found that the replacement of the etoposide carbohydrate moiety with a metallocenyl group led to organometallic conjugates exhibiting differentiated antiproliferative activity. Biological studies demonstrated that two ferrocenylalkylamino conjugates were notably more active than etoposide, with submicromolar or low-micromolar IC50 values towards SW620, etoposide-resistant SW620E, and methotrexate-resistant SW620M cancer cell lines. Moreover, the simplest ferrocenylmethylamino conjugate exerted dual inhibitory action against tubulin polymerization and topoisomerase II activity while other studied compounds affected only topoisomerase II activity. 相似文献