全文获取类型
收费全文 | 227篇 |
免费 | 10篇 |
专业分类
化学 | 102篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 63篇 |
物理学 | 66篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2017年 | 8篇 |
2016年 | 5篇 |
2015年 | 8篇 |
2014年 | 8篇 |
2013年 | 13篇 |
2012年 | 15篇 |
2011年 | 14篇 |
2010年 | 11篇 |
2009年 | 12篇 |
2008年 | 15篇 |
2007年 | 18篇 |
2006年 | 11篇 |
2005年 | 3篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 1篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1974年 | 3篇 |
1972年 | 1篇 |
1913年 | 2篇 |
排序方式: 共有237条查询结果,搜索用时 15 毫秒
1.
2.
3.
S. Jakobs Ulrike Schulz Angela Duparré Norbert Kaiser 《Analytical and bioanalytical chemistry》1997,358(1-2):242-244
SiO2 protective coatings have been deposited on polycarbonate substrates by plasma ion assisted deposition. The influence of ion energy on the water permeability and the surface topography of the coatings was studied by infrared spectroscopy and atomic force microscopy. Coatings deposited at sufficiently high ion energies show a barrier effect against moisture uptake and considerably reduced film roughness. Both effects are attributed to an increase of the packing densities of the coatings. 相似文献
4.
V. Brüser S. Jakobs H. -H. Möbius U. Schönauer 《Fresenius' Journal of Analytical Chemistry》1994,349(8-9):684-687
Solid electrolyte cells for detecting NO2 with Ba(NO3)2 or Sr(NO3)2 partially replaced by -Al2O3 as solid electrolytes have been studied. The cell tension depends on the NO2- as well as on the NO-concentration. Investigations of the establishment of the NO2-NO-O2-equilibrium by the catalytic effects of the used electrode materials Pt and Au have shown that a decomposition of NO2 below 400°C cannot be expected.17th Communication on oxoanionic solid electrolytes and their possible applications; 16th Communication see Solid State Ionics 51:183–185 (1992)Extension of a part of the lecture of V. Brüser, S. Jakobs, H.-H. Möbius and U. Schönauer Galvanische NO2-Sensoren mit Nitrat-Festelektrolyten given in Feldberg, 3. 6. 1993 相似文献
5.
The multicritical points of the O(N)-invariant N vector model in the large-N limit are re-examined. Of particular interest are the subtleties involved in the stability of the phase structure at critical dimensions. In the limit N → ∞ while the coupling g → gc in a correlated manner (the double scaling limit) a massless bound state O(N) singlet is formed and powers of 1/N are compensated by IR singularities. The persistence of the N → ∞ results beyond the leading order is then studied with particular interest in the possible existence of a phase with propagating small mass vector fields and a massless singlet bound state. We point out that under certain conditions the double scaled theory of the singlet field is non-interacting in critical dimensions. 相似文献
6.
7.
A new strain of the fungusMorchella nov. ES-1 (ATCC 20951) that produces blue pigment in submerged culture has been isolated. The blue pigment was extracted by chloroform or ethyl acetate treatment. The crude extract when chromatographed yielded three fractions; a blue one has been identified by mass spectrometry as indigotin. Fermentation studies using enriched media revealed that maximum accumulation of indigotin in culture was approx 24 mg/L in 168 h. 相似文献
8.
Size‐dependent mechanical properties of glassy polymer nanofibers via molecular dynamics simulations 下载免费PDF全文
Shengwei Deng Arkadii Arinstein Eyal Zussman 《Journal of Polymer Science.Polymer Physics》2017,55(6):506-514
The microstructure of polymer matrix under cylindrical confinement is key to understanding the size‐dependent thermomechanical behavior of electrospun nanofibers. Coarse‐grained molecular dynamics simulation was applied here to probe polymer systems under cylindrical confinement, prepared with or without pre‐stretching. Simulation results showed that below a certain radius, a noticeable increase of the elastic modulus is observed with the decrease of the radius of cylindrical confinement. This size‐dependent mechanical behavior correlated to the degree of polymer chain orientation. Modulation of density and bond orientation in the radial direction was observed: the density and bond orientation began to oscillate, increasing the oscillation amplitudes with decreases in the radius. Such behavior suggests that the cylindrical confinement enhances the bond alignment of the entire fiber and not in the near‐surface layers only. The unstretched fibers had uniform density distribution along the fiber axis, while the stretched fibers demonstrated a fluctuation in density distribution. The crossover radius of size‐dependent behavior was two orders of magnitude smaller than observed in real experiments, demonstrating that the confinement affects some internal fiber scale, which exceeds the scale of individual macromolecules, and this internal scale may be related to supramolecular structures of the polymer matrix rather than the individual macromolecules. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 506–514 相似文献
9.
Dmitriy Alhazov Arkadiusz Gradys Pawel Sajkiewicz Arkadii Arinstein Eyal Zussman 《European Polymer Journal》2013
Analysis of the thermo-mechanical behavior of electrospun thermoplastic polyurethane (TPU) block co-polymer nanofibers (glass transition temperature ∼−50 °C) is presented. Upon heating, nanofibers began to massively contract, at ∼70 °C, whereas TPU cast films started to expand. Radial wide-angle X-ray scattering (WAXS) profiles of the nanofibers and the films showed no diffraction peaks related to crystals, whereas their amorphous halo had an asymmetric shape, which can be approximated by two components, associated with hard and soft segments. During heating, noticeable changes in the contribution of these components were only observed in nanofibers. These changes, which were accompanied with an endothermic DSC peak, coinciding with the start of the nanofibers contraction, can be attributed to relaxation of an oriented stretched amorphous phase created during electrospinning. Such structure relaxation becomes possible when a portion of the hard segment clusters, forming an effective physical network, is destroyed upon heating. 相似文献
10.