全文获取类型
收费全文 | 1513篇 |
免费 | 44篇 |
国内免费 | 13篇 |
专业分类
化学 | 951篇 |
晶体学 | 2篇 |
力学 | 45篇 |
数学 | 343篇 |
物理学 | 229篇 |
出版年
2023年 | 11篇 |
2022年 | 28篇 |
2021年 | 36篇 |
2020年 | 28篇 |
2019年 | 24篇 |
2018年 | 21篇 |
2017年 | 17篇 |
2016年 | 61篇 |
2015年 | 33篇 |
2014年 | 34篇 |
2013年 | 82篇 |
2012年 | 77篇 |
2011年 | 126篇 |
2010年 | 62篇 |
2009年 | 49篇 |
2008年 | 95篇 |
2007年 | 91篇 |
2006年 | 83篇 |
2005年 | 53篇 |
2004年 | 43篇 |
2003年 | 41篇 |
2002年 | 34篇 |
2001年 | 14篇 |
2000年 | 18篇 |
1999年 | 14篇 |
1998年 | 14篇 |
1997年 | 18篇 |
1996年 | 21篇 |
1995年 | 14篇 |
1994年 | 24篇 |
1993年 | 24篇 |
1992年 | 14篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 17篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 14篇 |
1981年 | 18篇 |
1980年 | 13篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1975年 | 6篇 |
1974年 | 8篇 |
1973年 | 8篇 |
1858年 | 7篇 |
排序方式: 共有1570条查询结果,搜索用时 62 毫秒
1.
2.
Daniele Cauzzi Roberto Giordano Enrico Sappa Antonio Tiripicchio Marisa Tiripicchio Camellini 《Journal of Cluster Science》1993,4(3):279-296
The title complex (complex1) was the first alkyne-substituted triruthenium dihydrido cluster to be reported and was characterized by spectroscopy as a triangular cluster with the alkyne parallel to a Ru-Ru edge. Recently, we have found that1 is a key intermediate in the homogeneous hydrogenation of diphenylacetylene catalyzed by tetrahedral Ru4 and FeRu3 clusters. Since the discovery of1, a great number of complexes with alkynes parallel to a cluster edge have been reported; at present this is the more common bonding mode for alkynes on trinuclear clusters. The structural features of1 allow a comparison with those of other ruthenium-containing derivatives and help to draw suggestions of the role of1 in hydrogenation catalysis. 相似文献
3.
4-Vinylphenols, useful compounds for industrial applications, were obtained by decarboxylation of 4-hydroxycinnamic acids under microwave irradiation in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as base and basic aluminum oxide as solid support. The reactions were fast (15-30 min). The selective extraction of the final products with ethyl acetate avoids chromatographic purifications. The conversions are quantitative and the yields are satisfactory. Only the unstable 4-vinylcatechol was obtained in moderate yield. This procedure was successfully extended to a natural sample of ferulic acid extracted from wheat bran to get the corresponding 4-vinylguaiacol, a FEMA GRAS (Flavor and Extract Manufacturer's Association; General Regarded as Safe) approved flavoring agent. 相似文献
4.
Nicola Arcozzi Enrico Casadio Tarabusi Fausto Di Biase Massimo A. Picardello 《Transactions of the American Mathematical Society》2006,358(6):2781-2798
We establish a potential theoretic approach to the study of twist points in the boundary of simply connected planar domains.
5.
Gabor Schmera Adi Bulsara David Pierson Frank Moss Enrico Di Cera 《Journal of statistical physics》1993,71(5-6):1179-1190
We consider the class of experiments which can be characterized by a Fokker-PIanck dynamics corresponding to the overdamped motion of a state point in a suitable stochastic potential. We assume that the general form of the potential is known (or can be guessed with reasonable accuracy), but that its parameters are to be determined experimentally by measurements made with a noisy instrument. This possible method for determining the potential parameters, which exploits the system's own internal stochastic motion in order to explore rapidly its available parameter space, is substantially more efficient than traditional methods involving time averages of single point measurements, and yet does not appear to have been previously considered. The method could be important when, for example, the experiment must be completed in a limited time owing either to the expense of the experimental materials or to the temporary stationarity of the preparation, situations which are commonly encountered in experimental biochemistry and biology. 相似文献
6.
7.
Giovanni Tartarini Alessandra Lena Davide Passaro Lorenzo Rosa Stefano Selleri Pier Faccin Enrico Maria Fabbri 《Optical and Quantum Electronics》2006,38(9-11):869-876
A comprehensive numerical tool has been developed for the evaluation of the performances of Radio over Fiber (RoF) links intended for wireless signal distribution.At the transmitter end an appropriate set of rate equations allows to model the optical source as a solitary laser or as an appropriately injection locked laser. The optical channel is modeled putting into account the combined effect of fiber dispersion, laser source non ideal performances (e.g. non-linear effects, frequency chirp), and quadratic detection of the receiving photodiode. The simulation model developed can be a useful tool at the design stage allowing a preliminary evaluation of the characteristics of real RoF links. 相似文献
8.
Maria Benedetta Fadda Nicoletta Curreli Raffaello Pompei Antonio Rescigno Augusto Rinaldi Enrico Sanjust 《Applied biochemistry and biotechnology》1994,44(3):263-270
A highly active thermostable β-glucosidase was purified to homogeneity from a strain ofTrichoderma sp. The enzyme was an extracellular glycoprotein and showed hydrolytic activity toward several β-glucosides.
Cellobiose was found to be the substrate of choice for this enzyme. This finding could suggest future technological applications
of the purified protein. 相似文献
9.
A simple yet accurate method for calculating electrostatic potentials using the boundary element continuum dielectric method is presented. It is shown that the limiting factor in accuracy is not the evaluation of integrals involving the interaction between boundary elements but rather a proper estimation of the self-polarization of a patch upon itself. We derive a sum rule that allows us to calculate this important self-polarization term in a self-consistent and simple way. Intricate integration schemes used in previous treatments are consequently rendered unnecessary while concurrently achieving at least comparable accuracy over earlier methods. In some model systems for which analytic solutions are available, the computed surface polarization charge and reaction field energy are correct to better than six significant figures. An application of the method to the calculation of hydration free energies is presented. Good agreement with experimental values is obtained. 相似文献
10.
Fabio Fantozzi Sauro Filippeschi Enrico Maria Latrofa 《Superlattices and Microstructures》2004,35(3-6):339
Upward and downward two-phase heat and mass transfer has been considered in the present paper. The heat and mass transfer with the condenser located below the evaporator has been obtained by inserting an accumulator tank in the liquid line of a loop thermosyphon and enforcing a pressure pulsation. In previous papers these heat transfer devices have been called pulsated two phase thermosyphons (PTPT). A mini PTPT has been experimentally investigated. It has shown a stable periodic heat transfer regime weakly influenced by the position of the condenser with respect to the evaporator. In contrast a classical loop mini thermosyphon (diameter of connecting pipes 4 mm) did not achieve a stable functioning for the investigated level differences between evaporator and condenser lower than 0.37 m. The present study shows that the functioning of a PTPT device does not directly depend on the level difference or the presence of noncondensable gas. In order to obtain a natural circulation in mini or micro loops, a periodically operating heat transfer regime should therefore be considered. 相似文献