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1.
A linear three‐dimensional hydrodynamical numerical model, with the application of the Galerkin Method for the vertical dependence, is here presented. The spherical coordinate system is used, in order to allow large‐scale simulations. The equations and mathematical development of the model are shown in detail, together with the boundary and initial conditions, and the sequence of equations' solution. The model is applied to the South Atlantic Ocean, for estimating typical seasonal circulations, and the results are summarized in maps of currents at surface and 1000 m depth, and in transport values of the Brazil Current between 30°S and 40°S. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
2.
Contribution to the mass spectrometry of substituted α,ω-alkane diamines The main mass spectral fragmentation pattern of compounds of types 1 to 4 is discussed. After loss of C6H5 · CH2 · from the molecular ion the acid correspondin to the N,N-disubstituted residue is splitted off. The mechanism of this fragmentation reaction depends on the member of CH2-groups between the two nitrogen atoms (Schemes 1 and 3) and on the substitution pattern of both nitrogens (Scheme 2). 相似文献
3.
Othmar Leukart Emanuel Escher Domenico Regoli Robert Schwyzer 《Helvetica chimica acta》1979,62(2):546-552
Thirteen peptides, analogues of bradykinin (BK), enkephalin, Substance P (SP) and [Sar1]-angiotensin II ([Sar1]-ATII) have been synthesized by the solid-phase method. In all these peptides the residue Phe and Tyr were substituted with the boron-containing amino-acid L -o-carboranylalanine (Car). The purity and identity of the peptides were established by TLC., cellulose-electrophoresis and amino acid analysis. 相似文献
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Mohammad A. Hai Nigel W. Preston Rolf Kyburz Emanuel Schpp I. Ralph C. Bick Manfred Hesse 《Helvetica chimica acta》1980,63(7):2130-2134
Aristoserratine, a New Indole Alkaloid from Aristotelia serrata W.R.B. OLIVER and from A. peduncularis (LABILL .) HOOK . F. The new indole alkaloid aristoserratine (2) has been isolated from Aristotelia. Its structure and absolute configuration were elucidated on the basis of spectroscopic data. 相似文献
6.
Anthonny Cordero-Díaz Efren Robledo-Leal Eugenio Hernndez-Fernndez Emanuel Hernndez-Núez Mariana Elizondo-Zertuche Susana T. Lpez-Cortina 《Molecules (Basel, Switzerland)》2022,27(12)
The Scedosporium genus is an emerging pathogen with worldwide prevalence and high mortality rates that gives multidrug resistance to antifungals; therefore, pharmacological alternatives must be sought for the treatment of diseases caused by this fungus. In the present project, six new α-aminophosphates were synthesized by the Kabachnik–Fields multicomponent reaction by vortex agitation, and six new monohydrolyzed α-aminophosphonic acids were synthesized by an alkaline hydrolysis reaction. Antifungal activity was evaluated using the agar diffusion method as an initial screening to determine the most active compound compared to voriconazole; then it was evaluated against 23 strains of the genus Scedosporium following the M38-A2 protocol from CLSI (activity range: 648.76–700 µg/mL). Results showed that compound 5f exhibited the highest antifungal activity according to the agar diffusion method (≤1 mg/mL). Cytotoxicity against healthy COS-7 cells was also evaluated by the MTT assay and it was shown that compound 5f exhibits a lower toxicity in comparison to voriconazole at the same concentration (1000 µM). A docking study was conducted afterwards, showing that the possible mechanism of action of the compound is through the inhibition of allosteric 14-α-demethylase. Taking these results as a basis, 5f is presented as a compound with attractive properties for further studies. 相似文献
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Emanuel Knill 《Graphs and Combinatorics》1994,10(2-4):145-157
A family of sets ? islocally k- wide if and only if the width (as a poset ordered by inclusion) of ? is at mostk for everyx. The directed covering graph of a locally 1-wide family of sets is a forest of rooted trees. It is shown that if ? is a locallyk-wide family of subsets of {1,...,n}, then |?|≤(2k) k?1 n. The proof involves a counting argument based on families of closed sets associated with theSperner closures in the filters of ?. The Sperner closure ofU in ? is the intersection of the members of the greatest Sperner antichain of ? U = {V ∈ ?|V ?U}. This closure operation is related to a generalization of maximality in posets. 相似文献
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