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1.
T′相R2CuO4稀土铜氧化合物由于尺度效应而产生弱铁磁性行为已经被人们关注,报导了通过高温高氧压(6GPa,1000℃)合成稀土T′相R2CuO4(R=Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er和Tm)化合物的结构和磁学性能。磁化率曲线显示,在低温下所有的高压增氧R2CuO4样品都出现新的低温弱铁磁性反常行为,转变温度在28K附近。新的低温弱铁磁性行为是由于CuO2面上微量氧空穴的掺入,使处于反铁磁有序CuO2面形成局域化的铁磁性团簇造成。实验证明新发现的低温弱铁磁性行为与尺度效应产生弱铁磁性行为属于完全不同的物理机制。结果还预示T′相R2CuO4稀土铜氧化合物很难通过空穴掺杂而实现超导。 相似文献
2.
Shu Fen Wang Wen Guo Zou Su Wen Liu Dong Xu Duo Rong Yuan Guang Jun Zhou 《Journal of Physics and Chemistry of Solids》2004,65(7):1243-1245
The photoluminescence properties of the Bi3+ in sol-gel derived ZnTiO3 nanocrystals have been investigated. An ultra-violet emission at 360 nm and a visible emission band at 506 nm have been observed, originating from two kinds of emission centers. The former is ascribed to the 3P1-1S0 transition of Bi3+ and the latter to the recombination of the electrons with the photo-generated holes trapped in the zinc vacancies. In all cases the latter contribution is predominant. 相似文献
3.
The constitutive behavior of porous materials (including the yield loci, the void growth rate, the macro stress-strain relation
and the strain to localization instability) is examined based on the lower bound approach proposed by the present authors.
These results are then compared with the experimental and the finite element results as well as those predicted by Gurson's
equations. Emphasis is placed on approaching the real behavior from the upper and the lower bound analysis. Calculation is
also made on the influence of void nucleation on the critical strain to instability and a modified strain-controlled nucleation
criterion is proposed. Finally the instability and fracture of AISI4340 steel in plane strain tension is examined and comparison
is made between theoretical and experimental results. 相似文献
4.
Herein, we report a novel amino acid based reaction system for CO2 capture and utilization (CCU) to produce formates in the presence of the naturally occurring amino acid l-lysine. Utilizing a specific ruthenium-based catalyst system, hydrogenation of absorbed carbon dioxide occurs with high activity and excellent productivity. Noteworthy, following the CCU concept, CO2 can be captured from ambient air in the form of carbamates and converted directly to formates in one-pot (TON > 50 000). This protocol opens new potential for transforming captured CO2 from ambient air to C1-related products.A novel amino acid based reaction system for CO2 capture and utilization (CCU) to produce formates is presented applying a ruthenium-based catalyst. Noteworthy, CO2 can be captured from ambient air and converted to formates in one-pot (TON > 50 000). 相似文献
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本文采用远场光斑法和光强法测量了石英单模光纤的数值孔径.实验结果表明,由光纤耦合条件不同导致的光斑形状变化,对数值孔径的测量影响不大,单模光纤的纤芯直径小,导致出射光存在较强的衍射现象,对数值孔径的测量造成较大的影响,无论采用光斑法还是光强法,需以衍射第1次极大为计算标准,尽量选择光斑中心为亮斑时测量其数值孔径.此外,... 相似文献
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To improve the initial coulombic efficiency and bulk density of ordered mesoporous carbons, active Fe2O3 nanoparticles were introduced into tubular mesopore channels of CMK-5 carbon, which possesses high specific surface area (>1700 m 2 g-1 ) and large pore volume (>1.8 cm 3 g-1 ). Fine Fe2O3 nanoparticles with sizes in the range of 5 7 nm were highly and homogenously encapsulated into CMK-5 matrix through ammonia-treatment and subsequent pyrolysis method. The Fe2O3 loading was carefully tailored and designed to warrant a high Fe2O3 content and adequate buffer space for improving the electrochemical performance. In particular, such Fe2O3 and mesoporous carbon composite with 47 wt% loading exhibits a considerably stable cycle performance (683 mAh g-1 after 100 cycles, 99% capacity retention against that of the second cycle) as well as good rate capability. The fabrication strategy can effectively solve the drawback of single material, and achieve a high-performance lithium electrode material. 相似文献
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