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1.
It is known that under resonance conditions, a group of strongly interacting bosonic atoms, trapped in a double-well potential, mimics a single particle, performing Rabi oscillations between the wells. By implication, all atoms need to tunnel at roughly the same time, even though the Bose–Hubbard Hamiltonian accounts only for one-atom-at-a-time transfers. The mechanism of this collective behavior is analyzed, the Rabi frequencies in the process are evaluated, and the limitation of this simple picture is discussed. In particular, it is shown that the small rapid oscillations superimposed on the slow Rabi cycle result from splitting the transferred cluster at the sudden onset of tunnelling, and disappear if tunnelling is turned on gradually. 相似文献
2.
Dmitri I. Panyushev 《Advances in Mathematics》2004,186(2):307-316
We study Abelian ideals of a Borel subalgebra consisting of long roots. It is shown that methods of Cellini and Papi can be extended to this situation. A uniform expression for the number of long Abelian ideals is given. We also show that there is a one-to-one correspondence between the long Abelian ideals and B-stable commutative subalgebras in the little adjoint representation of the Langlands dual Lie algebra. 相似文献
3.
4.
O. V. Sizova E. P. Sokolova V. I. Baranovskii D. A. Rozmanov O. A. Tomashenko 《Journal of Structural Chemistry》2004,45(5):762-770
Ab initio MP2 calculations with several basis sets proved the existence of a stable benzonitrile dimer with a planar structure and a short contact between the H atom of one molecule and the N atom of another. The structure is greatly stabilized by attraction between the neighboring oppositely directed dipoles and donor-acceptor interaction between the orbital of the lone electron pair of the N′ atom and the vacant antibonding orbital localized on the C-H bond.Original Russian Text Copyright © 2004 by O. V. Sizova, E. P. Sokolova, V. I. Baranovskii, D. A. Rozmanov, and O. A. Tomashenko__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 807–815, September–October, 2004. 相似文献
5.
Dmitri V Sevenard Vyacheslav Ya SosnovskikhAlexander A Kolomeitsev Martin H KönigsmannGerd-Volker Röschenthaler 《Tetrahedron letters》2003,44(41):7623-7627
In a convenient and efficient procedure, the nucleophilic 1,4-trifluoromethylation of several α,β-enones using (trifluoromethyl)trimethylsilane was achieved. The high regioselectivity of the reaction has been reached by blocking the carbonyl moiety of the electrophile with a bulky aluminum-centered Lewis acid. 相似文献
6.
Masanobu Haraguchi David F. P. Pile Toshihiro Okamoto Masuo Fukui Dmitri K. Gramotnev 《Optical Review》2006,13(4):228-230
We have numerically shown the existence of coupled wedge plasmons (CWPs) which propagates along a nano gap of a twin metal
wedge. The CWPs are formed by wedge plasmons which can interact with each other. The dispersion relations of the wavenumber,
propagation distance, and beam area of CWPs, are described and show that the characteristics of CWPs are similar to those
of wedge plasmons and of gap plasmons. We also propose a new plasmon waveguide composed of twin metal wedges with a nano gap. 相似文献
7.
Nikolaií N. Nekhoroshev Dmitrií A. Sadovskií Boris I. Zhilinskií 《Annales Henri Poincare》2006,7(6):1099-1211
We introduce fractional monodromy in order to characterize certain non-isolated critical values of the energy–momentum map
of integrable Hamiltonian dynamical systems represented by nonlinear resonant two-dimensional oscillators. We give the formal
mathematical definition of fractional monodromy, which is a generalization of the definition of monodromy used by other authors
before. We prove that the 1:( − 2) resonant oscillator system has monodromy matrix with half-integer coefficients and discuss
manifestations of this monodromy in quantum systems.
Communicated by Eduard Zehnder
Submitted: February 25, 2005; Accepted: November 17, 2005 相似文献
8.
Claisen condensation of δ-valerolactone and ethyl trifluoroacetate leads to α-trifluoroacetyl-δ-valerolactone, existing completely in CDCl3 solution as an enol. Upon treatment of this cyclic 1,3-ketoester with aqueous HCl, an acyl-lactone rearrangement takes place. The structure of the resulting pyran was confirmed by an X-ray analysis. The ability of the rearrangement product to lose its carboxylic group under unexpected mild conditions was used for the synthesis of the corresponding 3-unsubstituted cyclic hemi-ketal. 相似文献
9.
Zhi C Bando Y Tang C Xie R Sekiguchi T Golberg D 《Journal of the American Chemical Society》2005,127(46):15996-15997
We report for the first time that boron nitride nanotubes (BNNTs) may be dissolved in organic solvents by wrapping them with a polymer. Transmission electron microscopy and cathodoluminescence studies indicate the strong pi-pi interactions between BNNTs and the polymer. A band gap ranging from 5.2 to 5.5 eV was documented for the BNNTs independent of their geometrical characteristics by using ultraviolet-visible absorption experiments on composite films and thin BNNT films prepared from solutions. 相似文献
10.
Talapin DV Shevchenko EV Murray CB Kornowski A Förster S Weller H 《Journal of the American Chemical Society》2004,126(40):12984-12988
We demonstrate the self-organization of CdSe nanorods into nematic, smectic, and crystalline solids. Layered colloidal crystals of CdSe nanorods grow by slow destabilization of a nanocrystal solution upon allowing the diffusion of a nonsolvent into the colloidal solution of nanocrystals. The colloidal crystals of nanorods show characteristic birefringence, which we assign to specific spherulite-like texture of each nanorod assembly. To demonstrate the general character of nanorod self-assembly technique, CdSe/CdS heterostructure nanorods were organized into highly luminescent superlattices. 相似文献