全文获取类型
收费全文 | 385篇 |
免费 | 14篇 |
专业分类
化学 | 286篇 |
晶体学 | 5篇 |
力学 | 20篇 |
数学 | 58篇 |
物理学 | 30篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 15篇 |
2020年 | 8篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 16篇 |
2014年 | 11篇 |
2013年 | 22篇 |
2012年 | 20篇 |
2011年 | 35篇 |
2010年 | 17篇 |
2009年 | 15篇 |
2008年 | 24篇 |
2007年 | 29篇 |
2006年 | 19篇 |
2005年 | 15篇 |
2004年 | 11篇 |
2003年 | 5篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1965年 | 1篇 |
排序方式: 共有399条查询结果,搜索用时 15 毫秒
1.
Algebras and Representation Theory - We introduce and study the category of twisted modules over a triangular differential graded bocs. We show that in this category idempotents split, that it... 相似文献
2.
In the following we find all of the three-dimensional flat spacetimes which are static and rotationally symmetric. 相似文献
3.
To Professor Guillermo Torres on the occasion of his 70th birthday. 相似文献
4.
Thomas J. Delia Dennis P. Anderson Jennifer M. Schomaker 《Journal of heterocyclic chemistry》2004,41(6):991-993
In a continuation of our studies involving the nucleophilic displacement of one of the chlorines from 2,4,6‐trichloropyrimidine, we now report the initial displacement of one of the fluorine atoms from 2,4,6‐trifluoropyrimidine using both aliphatic and aromatic amines. The monosubstitution products favor 2‐substitution with ammonia and ethanolamine while aniline gave the 4‐substituted derivative as the preferred product. 相似文献
5.
6.
M. A. Bautista C. Pérez Sirvent I. López García M. Hernández Córdoba 《Fresenius' Journal of Analytical Chemistry》1994,350(6):359-364
A flame atomic absorption spectrometric procedure for the rapid determination of manganese, lead, zinc, calcium, magnesium, iron, sodium and potassium in cements is described. For minor components, slurries are prepared in the 0.05–0.25% m/v range by direct suspension of the samples in a medium containing 2% v/v nitric acid, 2% hydrofluoric acid and 30% v/v glycerol. 50–200 l aliquots are injected in a simple flow injection manifold using water as the carrier. When determining major components, the FI manifold includes an easy-to-construct variable volume chamber allowing the on-line dilution of the suspensions. The degree of dilution can be easily modified to obtain signals within the linear response range of the instrument. Aqueous standards are used for calibration. The data obtained for six cements agree with those obtained by conventional procedures based on the compl
M
v£e
w
ete dissolution of the samples. 相似文献
7.
M. Garcia-Vargas J. M. Bautista Rodriguez S. Avila NovsR. Coy-Yll 《Microchemical Journal》1982,27(4):519-529
The formation and extraction into chloroform of iron complex with PASH (λmax = 640 nm) was studied. Beer's law is obeyed between 2.7 and 16.0 μg · ml−1 of iron, in organic phase (10 ml). The method can be applied to volume ratios Vaq.:Vorg. from 1:1 to 20:1. The minimum concentration determinable in aqueous phase is 135 ng ml−1 of iron. The interferences of 73 species were evaluated and eliminated when it was possible. The extraction method of the green complex was applied for the spectrophotometric determination of iron(II) in several standard, geochemical, and bromatological samples. A procedure based on the standard addition method was applied satisfactorily to the determination of as little as 25 ng of iron(II) per milliliter. 相似文献
8.
The peroxyacid oxidation of 6-chloro-2,4-diaminopyrimidine ( 1 ) led to two products, 6-chloro-2,4-diaminopyrimidine 3-N-oxide ( 2 ) and 2,4-diamino-5,6-dichloropyrimidine 3-N-oxide ( 3 ). The assignment of structure of both of these compounds was made on the basis of ir, uv, nmr, and mass spectral data. A discussion of the pathways involved in the formation of 3 is presented. 相似文献
9.
F. M. Bautista J. M. Campelo A. Garcia D. Luna J. M. Marinas A. A. Romero M. R. Urbano 《Reaction Kinetics and Catalysis Letters》1997,62(1):47-54
The vapor-phase catalytic alkylation of phenol with methanol and dimethyl carbonate on a series of differently prepared CrPO4 (Cr/P=1) and CrPO4-AlPO4 (CrAIP) catalysts, has been studied at different temperatures (473–673 K). The reaction is first order in phenol, giving
a mixture of O- and C-alkylated products (C-alkylation taking place preferentially at theortho-position). Moreover, dimethyl carbonate is a better methylating agent than methanol. 相似文献
10.
M. C. Mahedero A. Muñoz De La Peña A. Bautista J.J. Aaron 《Journal of inclusion phenomena and macrocyclic chemistry》2002,42(1-2):61-70
The effect of -cyclodextrin (-CD) and hydroxypropyl--cyclodextrin (HP--CD) upon the photochemically-induced fluorescence (PIF) properties of four phenylurea herbicides, including linuron, diuron, isoproturon and neburon has been studied. Photochemical conversion of these nonfluorescent herbicides into strongly fluorescent photoproducts was shown to occur in -CD and HP--CD aqueous media. The influence of pH, UV irradiation time and photoproduct stability on the fluorescence intensity was also investigated. In addition, the stoichiometry and formation constants of the complexes formed between herbicides and -cyclodextrin (-CD) or 2-hydroxypropyl--cyclodextrin (HP--CD) were determined. The formation constant values, ranging from 184 ± 40 to 1498 ± 245 M-1, were calculated by applying the iterative nonlinear regression (NLR) approach to the PIF data. Linear calibrations graphs were established in the interval 1–12 g/mL, for diuron, linuron and neburon. The IUPAC limits of detection ranged between 580 and 700 ng/mL, according to the compound. Application to the analysis of phenylurea herbicides in spiked river water was also described. 相似文献