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1.
根据拼合原理,以对苯二酚(p-HQ)、间苯二酚(m-HQ)及邻苯二酚(o-HQ)为先导化合物,通过一侧酚羟基的苄基保护、引入溴乙酸甲酯、还原、与3种糖元偶联、脱除保护基得到9种目标化合物。 同样以3-(4-羟基苯基)-1-丙醇为起始物质,通过苄基保护、与3种糖元偶联、脱除保护基得到3种目标化合物。 通过IR、1H NMR、13C NMR、HRMS等波谱分析方法对所合成的12种目标化合物进行了结构表征。 对合成的酚类糖苷缀合物进行了美白活性研究。 结果表明,化合物p-HQ-6a、m-HQ-7a、p-HQ-6b、m-HQ-6b、o-HQ-6b、p-HQ-6c、m-HQ-7c、L-3a和L-4b对酪氨酸酶有抑制作用,其中o-HQ-6b和p-HQ-6c对酪氨酸酶的抑制作用优于阳性对照物α-熊果苷。 相似文献
2.
凝视热成像系统MTF测试不同于扫描系统,必须有解决其空间采样的混淆特性。在传统的线扩展函数法基础上发展起来的方法主要有:缝扫描法、最值法、斜斜法。实际使用中,前两种方法需要精确的定位技术,而斜缝法的数据处理较复杂。本文主要论述斜缝测试法,分析其工作原理,介绍其数据处理技术。 相似文献
3.
Huiyun Lin Yi Shen Defu Chen Lisheng Lin Brian C. Wilson Buhong Li Shusen Xie 《Journal of fluorescence》2013,23(1):41-47
The purpose of this study is to investigate the feasibility for quantitative measurement of singlet oxygen (1O2) generation by using a newly developed 1O2-specific fluorescence probe Singlet Oxygen Sensor Green reagent (SOSG). 1O2 generation from photoirradiation of a model photosensitizer Rose Bengal (RB), in initially air-statured phosphate buffered saline (PBS) was indirectly monitored with SOSG. In the presence of 1O2, SOSG can react with 1O2 to produce SOSG endoperoxides (SOSG-EP) that emit strong green fluorescence with the maximum at 531 nm. The green fluorescence of SOSG-EP is mainly dependent on the initial concentrations of RB and SOSG, and the photoirradiation time for 1O2 generation. Furthermore, kinetic analysis of the RB-sensitized photooxidation of SOSG is performed that, for the first time, allows quantitative measurement of 1O2 generation directly from the determination of reaction rate. In addition, the obtained 1O2 quantum yield of porphyrin-based photosensitizer hematoporphyrin monomethyl ether (HMME) in PBS by using SOSG is in good agreement with the value that independently determined by using direct measurement of 1O2 luminescence. The results of this study clearly demonstrate that the quantitative measurement of 1O2 generation using SOSG can be achieved by determining the reaction rate with an appropriate measurement protocol. 相似文献
4.
5.
通过流水式呼吸仪研究了齐口裂腹鱼(Schizothorax prenanti)幼鱼在不同水温(11,15,20,23℃)和流速(0.00,0.10,0.30,0.50m/s)环境下的呼吸代谢.研究发现,齐口裂腹鱼幼鱼呼吸代谢率(MR)和单位体重呼吸代谢率(MR′)都随着温度的升高而增大.在11~23℃之间,代谢率的变幅为0.85~7.21mg/h,单位体重代谢率的变幅为350.81~1858.16mg/(kg·h).回归方程MR=a.mb能够较好的描述4个温度水平的幼鱼代谢率与体重之间的关系(p<0.05),体重指数b随着温度的升高而降低.并且在11~23℃之间,幼鱼的代谢率与温度、体重间的关系可通过模型MR=0.525m0.788.e0.033T(R2=0.907,p<0.05,n=32)较好地表征.在0.00,0.10,0.30,0.50m/s4个流速下裂腹鱼幼鱼呼吸代谢率的波动范围为0.59~2.35mg/h,单位体重代谢率波动范围为469.93~1281.56mg/(kg.h).各流速平均代谢率的大小顺序为0.937mg/h(0.10m/s)<1.089mg/h(0.00m/s)<1.104mg/h(... 相似文献
6.
The near-wall transport characteristics, inclusive of mass transfer coefficient and wall shear stress, which have a great
effect on gas–liquid two-phase flow induced internal corrosion of low alloy pipelines in vertical upward oil and gas mixing
transport, have been both mechanistically and experimentally investigated in this paper. Based on the analyses on the hydrodynamic
characteristics of an upward slug unit, the mass transfer in the near wall can be divided into four zones, Taylor bubble nose
zone, falling liquid film zone, Taylor bubble wake zone and the remaining liquid slug zone; the wall shear stress can be divided
into two zones, the positive wall shear stress zone associated with the falling liquid film and the negative wall shear stress
zone associated with the liquid slug. Based on the conventional mass transfer and wall shear stress characteristics formulas
of single phase liquid full-pipe turbulent flow, corrected normalized mass transfer coefficient formula and wall shear stress
formula are proposed. The
calculated results are in good agreement with the experimental data. The shear stress and the mass transfer coefficient in
the near wall zone are increased with the increase of superficial gas velocity and decreased with the increase of superficial
liquid velocity. The mass transfer coefficients in the falling liquid film zone and the wake zone of leading Taylor bubble
are lager than those in the Taylor bubble nose zone and the remaining liquid slug zone, and the wall shear stress associated
falling liquid film is larger than that associated the liquid slug. The mass transfer coefficient is within 10−3 m/s, and the wall shear stress below 103 Pa. It can be concluded that the alternate wall shear stress due to upward gas–liquid slug flow is considered to be the major
cause of the corrosion production film fatigue cracking. 相似文献
7.
8.
Xiaoming Zhang Yinhe Liu Chang’an Wang Defu Che 《Journal of Thermal Analysis and Calorimetry》2012,107(3):935-942
The combustion behaviors and kinetic parameters of three parent coals (A1, A2, and A3) and their blends (A1/A2 and A2/A3)
have been evaluated under oxidizing atmosphere (O2 and N2 mixtures), using a non-isothermal thermo-gravimetric analyzer. The aim of this study is to investigate the interaction between
the blended components during the process of co-combustion, and the effects of blending ratio and oxygen concentration (10,
15, and 21%) on combustion performance of blended coals. When high reactivity and low reactivity coals are co-combusted, double
peaks are observed in the DTG curves, and significant interaction occurs in the temperature range between the two peaks (T
p1 and T
p2). The activation energies obtained by Coats–Redfern method indicate that the activation energies of blended coals are lower
than that of parent coals. The combustibility index S is used to evaluate the combustion performance of blended coals, and the results show the non-additive effects of the combustion
characteristics of blended coals. The increased oxygen concentration results in a significant improvement of combustion performance
of blended coals. In addition, as the blending ratio of high reactivity coal is increased, the oxygen can greatly enhance
the combustion stability of blended coals. 相似文献
9.
The forced convection heat transfer with water vapor condensation is studied both theoretically and experimentally when wet
flue gas passes downwards through a bank of horizontal tubes. Extraordinarily, discussions are concentrated on the effect
of water vapor condensation on forced convection heat transfer. In the experiments, the air–steam mixture is used to simulate
the flue gas of a natural gas fired boiler, and the vapor mass fraction ranges from 3.2 to 12.8%. By theoretical analysis,
a new dimensionless number defined as augmentation factor is derived to account for the effect of condensation of relatively
small amount of water vapor on convection heat transfer, and a consequent correlation is proposed based on the experimental
data to describe the combined convection–condensation heat transfer. Good agreement can be found between the values of the
Nusselt number obtained from the experiments and calculated by the correlation. The maximum deviation is within ±6%. The experimental
results also shows that the convection–condensation heat transfer coefficient increases with Reynolds number and bulk vapor
mass fraction, and is 1∼3.5 times that of the forced convection without condensation. 相似文献
10.
刘德辅 《数学物理学报(B辑英文版)》1995,(1)
(刘德辅)BEHAVIORASt→∞OFTHESOLUTIONSOFTHELINEARSYSTEMOFELASTICTHEORYONNON-STAR-SHAPEDEXTERIORDOMAINS¥LiuDefu(Dept.ofApplMath.,Bei... 相似文献