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J.R. Cooper 《Journal of Molecular Spectroscopy》2006,239(1):51-58
The ν9 fundamental band of ethane occurs in the 12 μm region. It is the strongest band of ethane in a terrestrial window and is commonly used for the identification of ethane in the Jovian planets. The ν9 + ν4 − ν4 band occurs in the same region; neither can be analysed as an isolated band, since both are embedded in the torsional bath of the ground vibrational state. We report here two global fit models including data from both of these bands as well as the ν3 fundamental and the ν4, 2ν4 − ν4, and 3ν4 torsional transitions. The first is restricted to −5 ? KΔK ? 15 in the hot band and gives an excellent fit to the included data. Three resonant interactions are identified in this fit—a Coriolis interaction with two resonant cases between the ν9 torsional stack and that of the ground vibrational state (gs) and a resonant Fermi interaction between the ν3 fundamental and the gs. Hot band lines with KΔK < −5 are influenced by a fourth perturbation, with a crossing at −11 < KΔK < −10, which has been attributed to an interaction with the ν12 fundamental. A second fit, demonstrating a promising treatment of this interaction, is also presented. 相似文献
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I. M. Kolthoff S. R. Cooper V. J. Tulane F. Reimers H. A. J. Pieters K. Höppner V. H. Matula C. B. Macek W. N. Skworzow J. S. Schepelewa F. Čuta K. Kámen S. Cohen R. E. Oesper D. S. Narayanamurthi T. R. Seshadri H. M. State A. W. Kirssanow W. M. Tscherkassow D. M. Mukherjee T. Akiyama Y. Mine S. Yabe Y. Volmar M. Déribéré 《Analytical and bioanalytical chemistry》1937,111(5-6):192-197
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K Cooper S C Brailsford R Davies 《The Journal of the Operational Research Society》2007,58(2):168-176
Economic evaluation, such as cost effectiveness analysis, provides a method for comparing healthcare interventions. These evaluations often use modelling techniques such as decision trees, Markov processes and discrete event simulations (DES). With the aid of examples from coronary heart disease, the use of these techniques in different health care situations is discussed. Guidelines for the choice of modelling technique are developed according to the characteristics of the health care intervention.The choice of modelling technique is shown to depend on the acceptance of the modelling technique, model ‘error’, model appropriateness, dimensionality and ease and speed of model development. Generally decision trees are suitable for acute interventions but they cannot model recursion and Markov models are suitable for simple chronic interventions. It is further recommended that population based models be used in order to provide health care outcomes for the likely cost, health benefits and cost effectiveness of the intervention. The population approach will complicate the construction of the model. DES will allow the modeller to construct more complex, dynamic and accurate systems but these may involve a corresponding increase in development time and expense. The modeller will need to make a judgement on the necessary complexity of the model in terms of interaction of individuals and model size and whether queuing for resources, resource constraints or the interactions between individuals are significant issues in the health care system. 相似文献
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We establish upper and lower bounds for the metric entropy and bracketing entropy of the class of d-dimensional bounded monotonic functions under Lp norms. It is interesting to see that both the metric entropy and bracketing entropy have different behaviors for p<d/(d-1) and p>d/(d-1). We apply the new bounds for bracketing entropy to establish a global rate of convergence of the MLE of a d-dimensional monotone density. 相似文献
8.
Jon Wilkening 《Linear algebra and its applications》2007,427(1):6-25
We present an efficient algorithm for obtaining a canonical system of Jordan chains for an n × n regular analytic matrix function A(λ) that is singular at the origin. For any analytic vector function b(λ), we show that each term in the Laurent expansion of A(λ)−1b(λ) may be obtained from the previous terms by solving an (n + d) × (n+d) linear system, where d is the order of the zero of det A(λ) at λ = 0. The matrix representing this linear system contains A(0) as a principal submatrix, which can be useful if A(0) is sparse. The last several iterations can be eliminated if left Jordan chains are computed in addition to right Jordan chains. The performance of the algorithm in floating point and exact (rational) arithmetic is reported for several test cases. The method is shown to be forward stable in floating point arithmetic. 相似文献
9.
Using a generalization of the classical ballot theorem, Niu and Cooper [7] established a duality relation between the joint
distribution of several variables associated with the busy cycle inM/G/1 (with a modified first service) and the corresponding joint distribution of several related variables in its dualGI/M/1. In this note, we generalize this duality relation toGI/G/1 queues with modified first services; this clarifies the original result, and shows that the generalized ballot theorem
is superfluous for the duality relation. 相似文献
10.
Ronald H. Nickel Igor Mikolic-Torreira Jon W. Tolle 《Computational Optimization and Applications》2006,35(1):109-126
Deployed US Navy aircraft carriers must stock a large number of spare parts to support the various types of aircraft embarked
on the ship. The sparing policy determines the spares that will be stocked on the ship to keep the embarked aircraft ready
to fly. Given a fleet of ten or more aircraft carriers and a cost of approximately 50 million dollars per carrier plus the
cost of spares maintained in warehouses in the United States, the sparing problem constitutes a significant portion of the
Navy’s resources. The objective of this work is to find a minimum-cost sparing policy that meets the readiness requirements
of the embarked aircraft. This is a very large, nonlinear, integer optimization problem. The cost function is piecewise linear
and convex while the constraint mapping is highly nonlinear. The distinguishing characteristics of this problem from an optimization
viewpoint are that a large number of decision variables are required to be integer and that the nonlinear constraint functions
are essentially “black box” functions; that is, they are very difficult (and expensive) to evaluate and their derivatives
are not available. Moreover, they are not convex. Integer programming problems with a large number of variables are difficult
to solve in general and most successful approaches to solving nonlinear integer problems have involved linear approximation
and relaxation techniques that, because of the complexity of the constraint functions, are inappropriate for attacking this
problem. We instead employ a pattern search method to each iteration of an interior point-type algorithm to solve the relaxed
version of the problem. From the solution found by the pattern search on each interior point iteration, we begin another pattern
search on the integer lattice to find a good integer solution. The best integer solution found across all interations is returned
as the optimal solution. The pattern searches are distributed across a local area network of non-dedicated, heterogeneous
computers in an office environment, thus, drastically reducing the time required to find the solution. 相似文献