Nafion-PAN optical chemical sensor: optimization by FIA

A copper-sensitive optical chemical sensor (optrode) is described. The optrode is based on a Nafion membrane and an immobilized organic ligand coupled with a flow injection (FI) system. The FI system includes a flow-through removable measuring cell and a simple spectrophotometer. Owing to the miniature size of the system and the efficient use of optical fibers, this optrode is well suited for monitoring environmental water samples. The success of the described optrode system depends on the effectiveness of the FI reagent delivery system. Optimum contact time with the membrane (as determined by the reagent flow rates) and the injected sample volume are critical. Environmental water samples were analyzed for copper content using the optimized optrode system. To validate the optrode's performance, the same water samples were analyzed using the atomic absorption spectrophotometer.     

The use of a polymer inclusion membrane in a paper-based sensor for the selective determination of Cu(II)

A disposable paper-based sensor (PBS) is described for the determination of Cu(II) in natural and waste waters at approximately 2 cents per measurement. The device makes use of a polymer inclusion membrane (PIM) to provide the selectivity for Cu(II). The PIM consists of 40 wt% di(2-ethlyhexyl) phosphoric acid (D2EHPA) as the carrier, 10 wt% dioctyl phthalate (DOP) as a plasticizer, 49.5 wt% poly(vinyl chloride) (PVC) as the base polymer and 0.5 wt% (m m⁻¹) 1-(2′-pyridylazo)-2-naphthol (PAN) as the colourimetric reagent. High selectivity under mildly acidic conditions (HCl, pH 2.0) is achieved for Cu(II) in the presence of frequently encountered metal ions in natural and waste waters such as Fe(III), Al(III), Zn(II), Cd(II), Pb(II), Ca(II), Mg(II), and Ni(II).     

Kinetics and structural studies of the atmospheric corrosion of carbon steels in Panama

The corrosion of a carbon steel was studied in different atmospheres at sites in the Republic of Panama. The weight loss (corrosion penetration) suffered by the carbon steel is related to time by a bilogarithmic law. Mössbauer spectroscopy indicated the rust was composed of non-stoichiometric magnetite (Fe_3-xO₄), maghemite (γ-Fe₂O₃), goethite (α-FeOOH) of intermediate particle size, lepidocrocite (γ-FeOOH) and superparamagnetic particles. Magnetite formation is related to the alternating dry--wet cycles. Goethite is related to corrosion penetration by a saturation type of behavior, following a Langmuir type of relationship. Goethite in rust protects steel against further atmospheric corrosion.     

The lengths of Hermitian self-dual extended duadic codes

Duadic codes are a class of cyclic codes that generalize quadratic residue codes from prime to composite lengths. For every prime power q, we characterize integers n such that there is a duadic code of length n over F_q² with a Hermitian self-dual parity-check extension. We derive asymptotic estimates for the number of such n as well as for the number of lengths for which duadic codes exist.     

Atomic Proximity Due to Molecular Congestion: Rational Design of Bis(phosphite) Ligands by Restriction of Molecular Motion(1)

The synthesis and conformational analysis of the sterically congested bis(phosphite) ligand {2-{1-{3,5-(t)Bu(2)-2-[2,2'-CHCH(3)(4,6-(t)Bu(2)C(6)H(2)O)(2)PO]C(6)H(2)}Et}-4,6-(t)Bu(2)C(6)H(2)O}(PhO)(2)P (5) are reported. X-ray crystallographic, dynamic (31)P{(1)H} NMR, NOE, DNOE, CP-MAS (31)P NMR, and calculational studies of 5 as well as the structurally related bis(phosphites) 1 and 6 suggest that the conformational freedom of the molecule is severely restricted because of geometric restraints due to steric congestion. A through-space mechanism of coupling is suggested to explain the observed eight-bond P-P J coupling of 27.5 Hz in the (31)P{(1)H} NMR spectrum of 5, which is a result of the proximity of the two phosphorus atoms in 5. The results of this study support the contention that the restriction of molecular motion by steric congestion can be used to rationally design a ligand favoring a particular disposition of phosphorus atoms.     

Nafion-based optical sensor for the determination of selenium in water samples

An optical chemical sensor responsive to selenium (SeO₃²⁻) in water samples was developed. Its matrix was nafion membrane suffused with an organic ligand p-amino-p’-methoxydiphenylamine or variamine blue (VB). The method of analysis was flow injection (FI) where in the membrane was fixed in a flow-through demountable measuring cell and connected to a computer-controlled simple spectrophotometer.

Variamine blue was previously established to determine amounts of selenium in water and other media by means of a spectrophotometer. The method involved reacting selenite with potassium iodide to generate iodine gas, which reacts with variamine blue to form a colored species.

Experimental results showed the optrode to be an effective tool in analyzing the selenium content of water samples particularly for remote or in situ applications. Interference studies proved that the method is free of intervention from tested ions.     

热辐射应力图像分析确定裂纹尖端塑性区

本文借助于热辐应力图像分析技术记录了铝质紧养伤拉伸试件的热辐射应力图像。根据裂尖周围温度变化曲线的分布规律确定其特征区的,从而得以裂尖塑性区的开头曲线,并与理论值比较,符合良好。对裂纹扩展面进行ＳＥＭ分析,得出该试件的断裂特性,对于进行细观损伤研究有重要的意义。     

材料细观结构与构件宏观响应间直接关联分析

本文探讨一种用于材料细观结构与构件宏观响应之间的直接关联分析方法。该方法应用宏现计算,给出细观力学量,并可反映材料细观结构特征,适用于具有细观结构材料制成构件的力学分析。