全文获取类型
收费全文 | 65篇 |
免费 | 1篇 |
专业分类
化学 | 56篇 |
力学 | 1篇 |
数学 | 5篇 |
物理学 | 4篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2015年 | 1篇 |
2013年 | 1篇 |
2011年 | 4篇 |
2010年 | 2篇 |
2009年 | 3篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有66条查询结果,搜索用时 15 毫秒
1.
The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time. 相似文献
2.
Berger A Djukic JP Pfeffer M de Cian A Kyritsakas-Gruber N Lacour J Vial L 《Chemical communications (Cambridge, England)》2003,(5):658-659
In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(eta6-phenyl)tricarbonylchromium]pyridine with mu-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C--N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (eta6-arene)Cr(CO)3 complexes. 相似文献
3.
Moroney C Lehane M Braña-Magdalena A Furey A James KJ 《Journal of chromatography. A》2002,963(1-2):353-361
Azaspiracids have been identified as the cause of a new toxic syndrome called azaspiracid poisoning (AZP) that has led to incidents of human intoxications throughout Europe following the consumption of mussels. Although five AZP toxins have been structurally elucidated to-date, azaspiracid (AZA1), 8-methylazaspiracid (AZA2) and 22-demethylazaspiracid (AZA3) are the predominant toxins. Separation of the three main AZP toxins was achieved using reversed-phase liquid chromatography (LC) and coupled to an electrospray ionisation source of an ion-trap mass spectrometer. Five reversed-phase (C18) and three diol solid-phase extraction (SPE) cartridges were compared for their efficacy in the cleanup of shellfish matrix. The comparison was based on the optimum recoveries of AZA1, AZA2 and AZA3 from extracts of mussel tissues. LC-electrospray MS3 analysis was used to quantify the AZP toxins in wash and eluate fractions in the SPE studies. Good recovery and reproducibility data were obtained for one diol SPE cartridge and two C18 SPE cartridge types. 相似文献
4.
Effect of annealing on hydrophobic stability of plasma deposited fluoropolymer coatings 总被引:1,自引:0,他引:1
Arun Kumar Gnanappa Cian O'Murchu Frank Peters Syed A.M. Tofail 《Polymer Degradation and Stability》2008,93(12):2119-2126
Fluorinated amorphous carbon (a-C:F) films e.g. plasma polymerised perfluorocyclobutane have long attracted much consideration due to their low surface energy, hydrophobicity, low refractive index, good electrical and thermal insulation and good thermal stability. Although a-C:F films have many advantages, hydrophobic stability over time in air and water remains a major concern. In this study, the effects of weathering conditions on the hydrophobicity of fluorocarbon films prepared from perfluorocyclobutane precursors were examined using water contact angle measurements. It was found that the high initial hydrophobicity of as-deposited films degrades rapidly in humid conditions. The stability of hydrophobicity can be significantly improved when a suitable treatment such as annealing is employed. The mechanism of weathering was explained with the help of a number of morphological and chemical characterisation techniques such as Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS). In particular, XPS results demonstrated that a reduction in the overall amount of -CF3 radical, oxygenation of surface fluorides and the formation of an overlayer all influence the degradation of fluorocarbon in aquatic environment. 相似文献
5.
G. J. Goetz-Grandmont J. P. Brunette A. De Cian N. Kyritsakas 《Structural chemistry》2002,13(5-6):459-470
From IR, UV, 31P, 1H, and 13C NMR spectroscopic data, it is shown that the three 3-phenyl-4-acyl-isoxazol-5-ones, HPXI (HPBI, HPTI, and HPtbBI with acyl-, benzoyl-, toluoyl-, and para-(tert-butyl)benzoyl-, respectively), promising extractants of actinides, appear under the same major tautomeric forms, both in the solid and in solutions in various solvents: the diketo-enamine form in methanol, a -ketoenolic form in the solid, and in chloroform, benzene, and toluene. The radiocrystallographic structures of HPTI and HPtbBI have been determined. They appear as 3-phenyl-4-(-hydroxybenzylidene)isoxazol-5-ones, forming intramolecular chelates through H-bonds. -Aryl interactions might influence the relative positions of the -ketoenolic oxygen atoms and, hence, the bite angle and the cone angle of these ligands. Spectroscopic data give evidence of strong TOPO–HPXI interactions (TOPO: tri-n-octylphosphine oxide) in toluene, of the same order of magnitude for the three acylisoxazolones, in the order: HPBI > HPTI > HPtbBI. 相似文献
6.
de Cian A Djukic JP Fischer J Pfeffer M Dötz KH 《Chemical communications (Cambridge, England)》2002,(6):638-639
The reactions of bis-cyclomanganated 2,3-diphenylquinoxaline with diazodiphenylmethane and 9-diazofluorene allowed the formation of a new oligomeric and dinuclear manganospiralene and the ready preparation of a pentacyclic helix comprising two (eta 5-fluorenyl)Mn(CO)3 fragments, whose helicity can be locked upon one-dimensional linear coordination to silver cation. 相似文献
7.
8.
Jean-Pierre Djukic Michel Pfeffer Nathalie Gruber-Kyritsakas André de Cian 《Journal of organometallic chemistry》2011,696(20):3268-3273
A Mn(I) tricarbonyl complex of a 1,3-diferrocenyl-1-oxopentadienyl ligand was synthesised adventitiously by what seems to be an in-situ aldol-like condensation of two acetylferrocene units promoted by benzyl-Mn(CO)5. X-ray structural analysis of this unexpected product confirms the η5 coordination of the 1,3-diferrocenyl-1-oxopentadienyl ligand to the Mn(CO)3 moiety. The nature of the metal-ligand bonding relationship was studied by theoretical calculations; it outlines the charge unbalance (polarisation) at the oxopentadienyl moiety as well as the lack of ketone character of the latter Mn-bound ligand. 相似文献
9.
10.