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Fettouhi M Ouahab L Boukhari A Cador O Mathonière C Kahn O 《Inorganic chemistry》1996,35(17):4932-4937
The goal of this work was to synthesize new molecular bricks which could be used as precursors of heterobimetallic low-dimensional compounds. Along this line, four compounds have been synthesized and structurally characterized, namely (NBu(4))(2)[Ni(Cl(2)opba)] (1), (NBu(4))(2)[Cu(Cl(2)opba)] (2), (NBu(4))(5)[Mn(Cl(2)opba)(DMSO)(2)](4) (3), and Cu(en)(2)[Mn(Cl(2)opba)(H(2)O)(2)](2).2DMSO (4), with Cl(2)opba = (4,5-dichloro-o-phenylene)bis(oxamato), NBu(4) = tetra-n-butylammonium, en = ethylenediamine, and DMSO = dimethyl sulfoxide. Compounds 1 and 2 are isostructural; they crystallize in the monoclinic system, space group C2/c, Z = 4, with a = 18.708(2) ?, b = 17.525(2) ?, c = 14.763(9) ?, and beta = 92.03(4) degrees for 1 and a = 18.928(2) ?, b = 17.634(2) ?, c = 14.704(9) ?, and beta = 92.38(3) degrees for 2. 3 crystallizes in the tetragonal system, space group P&fourmacr;2(1)c, Z = 2, with a = 26.295(10) ? and c = 12.342(7) ?. The structure shows a random occupation of the metal site by Mn(III) and Mn(II) ions in 3/4 and 1/4 ratios, respectively. 4 crystallizes in the triclinic system, space group P&onemacr;, Z = 1, with a = 7.066(7) ?, b = 11.844(1) ?, c = 14.292(5) ?, alpha = 105.64(2) degrees, beta = 97.67(5) degrees, and gamma = 102.13(3) degrees. The structure consists of Mn(III)Cu(II)Mn(III) trinuclear species, with Cu-O-Mn bridges involving oxygen atoms of the oxamato groups already linked to the metal atom. The magnetic properties of compounds 1-4 have been investigated and quantitatively interpreted. For 3, this magnetic investigation has been performed on a single crystal, which allows us to determine unambiguously the sign of the axial zero-field splitting parameter for the Mn(III) ion. The potentialities of these new molecular bricks have been discussed. 相似文献
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Fayçal Boukhari Nacéra Tigrine‐Kordjani Brahim Youcef Meklati 《Helvetica chimica acta》2013,96(6):1168-1175
Walnut (Juglans regia L.) leaves are used traditionally as an herbal tea indicated for non‐insulin‐dependent diabetics. In recent years, the type‐II diabetes is occurring worldwide with increasing frequency. Thus, there is an urgent need to explore the new beneficial biomolecules on the human health. Our objective was to investigate, for the first time, the volatiles profile of Juglans regia L. leaves from Algiers region. The extraction of essential oil of fresh plant material was performed by microwave‐assisted hydrodistillation (MAHD), for the first time, a relatively recent method, then by the conventional hydrodistillation technique (HD) for comparison. The collected extracts were analyzed by GC‐FID and GC/MS using two capillary columns with different polarity. Extraction time of 1 h by MAHD provided higher yields (0.050±0.001% (w/w)) than by HD (0.030±0.006% (w/w)) after 3 h. A total of 38 compounds were identified using both techniques. Essential oils had similar qualitative but different quantitative composition in terms of chemical compounds. The MAHD method improved yield while reducing the extraction time. The sesquiterpenes were the dominant family in both MAHD and HD essential oils with β‐caryophyllene being the major constituent. Monoterpenes, including hydrocarbon and oxygenated, prevail in HD volatile fraction with β‐pinene and eucalyptol, respectively, as major components. 相似文献
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M. Belaiche J. Aride T. Biaz A. Moqine A. Boukhari M. Drillon 《Phase Transitions》2013,86(1-4):149-155
In the last two decades, many studies have been reported on infinite Id networks of magnetically interacting metal ions. Until now, closed-form expressions for the partition function and related properties were mainly derived for the S = f Ising chain model (Ising, 1925), the XY model (Kastura, 1962) or for the classical limit S –t co with arbitrary spin dimensionality (Fischer, 1964). Recently, experimental and theoretical studies have focused on new Id systems made of alternating spin and/or Lande factors (Georges, Curely and Drillon, 1985; Drillon et al., 1983). This has motivated our interest in the behavior of new systems of copper(II) ions in which the magnetic sites form an exotic stacking in one direction of the crystal. Then, the specific behavior is related to the competition between different interactions, as occurs in the systems reported here, namely A3Cu3(PO4)4, with A = Ca, Sr, Cu3(PO4)2 and Cu2O(SO4). 相似文献
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The ferroelectric compounds Pb2Na1−xLaxNb5−xFexO15 and Pb0.5(5−x)LaxNb5−xFexO15 (0≤x≤1) with the tungsten bronze type structure have been investigated using Raman spectroscopy. The evolution of the spectra as a function of composition at room temperature is reported. In the frequency range 200-1000 cm−1 three main A1 phonons around 240 (υ1), 630 (υ2) and 816 (υ3) cm−1 were observed. The broadening of the Raman lines for high values of x originates from a significant structural disorder. This is in good agreement with the relaxor character of these compositions. The lowest-frequency part of the spectra, below 180 cm−1, reveals a structural change in the studied solid solutions. The behaviour of the Raman shift of the υ1 mode confirms that in Pb2Na1−xLaxNb5−xFexO15, a clear anomaly occurs in the vicinity of x=0.4. 相似文献
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J. Bennazha Ali Boukhari Elizabeth M. Holt 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(7):i87-i89
The crystal structures of two new diphosphates, sodium silver tricobalt bis(diphosphate), (Na1.42Ag0.58)Co3(P2O7)2, and sodium silver copper(II) diphosphate, (Na1.12Ag0.88)CuP2O7, provide examples of the effect of mixing Na and Ag in the same site of known host phosphate compounds. The small differences in ionic radii of the two monocations do not lead to significant differences in the structural details. In the latter compound, the Cu atom lies on an inversion center. 相似文献
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Fatima Erragh Ali Boukhari Brahim Elouadi Elizabeth M. Holt 《Journal of chemical crystallography》1991,21(3):321-326
Na2CoP2O7 may be prepared in two allotropie forms:I, rose,M
r
=278.85, triclinic, P1,a=9.735(2),b=10.940(3),c=12.289(4) Å,=148.78,=121.76(1), =68.38(2)°,V=566.8(2) Å3,Z=4,D
meas=3.28(5) g cm–3,D
calc=3.267 g cm–3, (MoK)=0.71069 Å,=37.12 cm–1, F(000)=540,T=298 K,R=5.4% for 2911 observed reflections; andII, blue,M
r
=278.85, orthorhombic, P21cn,a=7.713(2) Å,b=10.271(4),c=15.378(6)°,V=1218.2(8) Å3,Z=8,D
meas=3.06(5) g cm–3,D
calc=3.040 g cm–1, (MoK
) Å,=34.55 cm–1, F(000)=1080,T=298 K,R=9.9% for 1450 observed reflections. Cobalt displays octahedral coordination to six oxygen atoms in the rose form whereas the metal coordination is tetrahedral in the blue form. 相似文献
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Sihem Hessainia Abbes Boukhari Zinelaabidine Cheraiet 《Journal of heterocyclic chemistry》2020,57(1):218-224
1,2,5-Thiadiazolidine-1,1-dioxide carboxamide derivatives 3a-3n are novel heterocyclic compounds synthesized by multicomponent condensation reaction in one pot of aniline, chlorosulfonyl isocyanate, and 2-chloroethylamine hydrochloride which is used as a useful precursor under mild conditions. This reaction is realized with high atom economy, at room temperature and in a short reaction time. Series of these desired products are obtained from good to excellent yields within 2 hours in all cases. All the synthesized compounds are characterized by 1H, 13C NMR, MS, and HMBC/HSQC spectroscopy. 相似文献
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