层状钙钛矿La1.2Sr1.8Cu0.04Mn1.96O7中的自旋玻璃态和输运性质

用固相烧结的方法成功制备了层状钙钛矿锰氧化物La1.2Sr1.8Cu0.04Mn1.96O7西多晶样品。研究发现，在层状钙钛矿La1.2Sr1.8Mn1.96O7中，用Cu替代Mn对其磁、电的性质影响非常显著。随温度的降低样品表现出从顺磁（PM）到铁磁（FM）及自旋玻璃态（SG）等复杂的磁相变行为。电性测量表明，在整个观察的温区内都表现出绝缘体或半导体的性质。对电阻率．温度曲线进行拟合表明：在低温区采用变程跳跃模型和在高温区采用小极化子模型都得到了较好的线性关系。     

多维定量构效关系及药物分子设计研究进展

本文介绍并综述超分子化学，多维定量构效关系及药物分子设计的发展概况与研究进展，为新药创制和医药工业提供了有用信息。     

Spectral methods for weakly singular Volterra integral equations with pantograph delays

In this paper, the convergence analysis of the Volterra integral equation of second kind with weakly singular kernel and pantograph delays is provided. We use some function transformations and variable transformations to change the equation into a new Volterra integral equation with pantograph delays defined on the interval [-1, 1], so that the Jacobi orthogonal polynomial theory can be applied conveniently. We provide a rigorous error analysis for the proposed method in the L^∞-norm and the weighted L²-norm. Numerical examples are presented to complement the theoretical convergence results.     

塞曼效应对正常金属/d波超导结中微分电导的影响

通过外加塞曼磁场在d波超导中,研究磁场对d波超导及其正常金属/d波超导结中隧道谱的影响。研究表明(1)塞曼磁场能使能隙变小,且随着磁场变大,超导态会变为正常态,产生一级相变;(2)塞曼磁场可导致零偏压电导峰劈裂,劈裂宽度为2h0(h0为塞曼能)。     

有理插值的扩展方程组与约束方程组

Firstly, using the elementary solution, this paper provides the fundammental structure of the general solution of the (m/n)f system of equations in the rational interpolating problem, and points out the significance of the elementary solution. Secondly, it introduces the systems of extended equations and of constrained equations, analyses their properties, gives the structures of their general solution, obtains the relations of both them and the elementary solution, reveals the importance of their describing the elementary solution. And lastly , it computes an example for the two kinds of svstems.     

银,钾掺杂对稀土锰钙钛矿的磁性和电性的影响

用固相反应方法制备了银和钾掺杂稀土锰钙钛矿氧化物Ag-（La0.92K0.04MnO3）n,研究了该系统的电性和磁性。稀土锰钙钛矿系统的电阻-温度曲线呈现双峰结构。根据核壳结构,说明钾的挥发及银的添加对稀土锰钙钛矿颗粒的磁性以及系统的传输性质产生了影响。n=4的样品在很宽的温度范围内表现出很大的磁电阻。实验表明：添加适量的银有利于增大多晶材料的磁电阻并且延展其温度范围。     

Structure and magnetic properties of CoxPb1−x nanowire arrays

Ordered Co_xPb_1−x nanowire arrays embedded in the porous anodic aluminum oxide (AAO) template have been fabricated by electrodeposition. XRD experiments prove that neither hexagonal-close-packed (hcp) nor face-centered-cubic (fcc) Co peaks are detected when the Co component (x) is below 0.91. The coercivity (H_c) and squareness (M_r/M_s) are found to increase with ferromagnetic Co component and the maximum value is at the position x=1 (pure Co nanowires). Annealing effects cause H_c and M_r/M_s increase, which surpasses the pure Co nanowires in the 0.2<x<0.6 at the annealing temperature of 700 °C. Microstructure change during annealing process is proposed to explain the magnetic properties change of samples.     

不同耐热合金上油页岩干馏瓦斯丙烯组分的积炭特性

采用自制的连续流动反应装置,分别以2520及316L不锈钢管为反应器,对不同气体流量(20ml.min_-1,30ml.min_-1,40ml.min_-1)、不同壁温(700℃,750℃,800℃)、恒定反应时间(20min)等条件下干馏瓦斯中丙烯组分在不同反应器内积炭特性进行了实验研究,得出两种管壁上初始积炭温度范围为630℃~650℃及670℃~690℃;结合扫描电子显微镜对积炭微观形态进行观察,结果表明管内积炭都以丝状炭和无定形炭为主;用程序升温氧化方法对不同工况下两种反应管内积炭量进行分析,得出316L耐热合金具有抗金属粉化特性;运用热重及差示扫描量热法对管内剥离炭样活性进行表征,结果验证316L耐热合金内积炭活性高于2520耐热合金内积炭。     

有理插值(m/n)_f方程组的性质与作用

1引言 记Pn为次数不超过n的一元多项式函数类,约定零多项式的次数为-∞,即deg(0)=一∞;记Rm,n为分子属于Pm,分母属于Pn＼{0}的一元有理函数类.在[1-5]的基础上,文[6]引进了有理插值问题的(m-n)f方程组,其为经典(m/n)f方程组的一种等价变换.由于变换之后,使得参数之间地位相同,并且在个数上也与空间自由度一致,因此成为分析有理插值的一个有力工具.文[7]利用(m-n)f方程组,讨论了有理插值的基本特征,给出并证明了关于基本特征的基本关系定理.文[8]则在此基础上解决了有理插值的适定性问题.     

NixPb1-x nanowire arrays: effects of annealing

Ni(x)Pb(1-x) nanowire arrays were successfully fabricated by AC electrodeposition within the nanopores of ordered porous alumina films prepared by a two-step anodization. Transmission electron microscopy analyses showed that the Ni-Pb nanoarrays are polycrystalline with dimension uniformity around 20 nm in diameter and lengths up to several micrometers. X-ray diffraction results revealed that the face-centered-cubic (fcc) Ni and fcc Pb peaks are detected when the Ni component (x) is below 0.71, indicating that the Ni(x)Pb(1-x) nanoarrays do not form metastable phase alloy. Hysteresis loops determined by vibrating sample magnetometer indicated that the Ni(x)Pb(1-x) nanoarrays obtained possess obvious magnetic anisotropy, and the perpendicular coercivity was lower than that of pure Ni nanowries before and after annealing. Annealing under magnetic field was carried out to examine the effect of a magnetic field on magnetic properties using an electromagnet field up to 0.3 T.