全文获取类型
收费全文 | 312篇 |
免费 | 7篇 |
国内免费 | 1篇 |
专业分类
化学 | 194篇 |
晶体学 | 4篇 |
力学 | 15篇 |
数学 | 22篇 |
物理学 | 85篇 |
出版年
2021年 | 8篇 |
2019年 | 7篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 14篇 |
2015年 | 17篇 |
2014年 | 5篇 |
2013年 | 26篇 |
2012年 | 13篇 |
2011年 | 17篇 |
2010年 | 14篇 |
2009年 | 21篇 |
2008年 | 19篇 |
2007年 | 28篇 |
2006年 | 20篇 |
2005年 | 13篇 |
2004年 | 16篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2001年 | 2篇 |
1998年 | 2篇 |
1996年 | 2篇 |
1993年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1964年 | 1篇 |
1963年 | 1篇 |
1962年 | 1篇 |
1940年 | 1篇 |
1938年 | 1篇 |
排序方式: 共有320条查询结果,搜索用时 15 毫秒
1.
2.
P. Banu Ganga Radhakrishnan 《Journal of polymer science. Part A, Polymer chemistry》2004,42(2):341-350
The phase‐separation behavior of thermoplastic poly(ester‐imide) [P(E‐I)] multiblock copolymers, (A‐B)n, was investigated by a stepwise variation of the imide content. All the multiblock copolymers were synthesized by solution polycondensation with dimethylformamide as a solvent. P(E‐I)s were prepared with anhydride‐terminated polyester prepolymer and diisocyanates. Polyester prepolymers were prepared by the reaction of pyromellitic dianhydride and two different polyols [poly(tetramethylene oxide glycol) (PTMG) and polycaprolactone diol (PCL)]. Structural determination was done with Fourier transform infrared spectroscopy and Fourier transform NMR, and the molecular weight was determined by gel permeation chromatography. The effect of the imide content on the thermal properties of the synthesized P(E‐I)s was investigated by thermogravimetric analysis and differential scanning calorimetry. The polymers were also characterized for static and dynamic mechanical properties. Thermal analysis data indicated that the polymers based on PTMG were stable up to 330 °C in nitrogen atmosphere and exhibited phase‐separated morphology. Polymers based on PCL showed multistage decomposition, and the films derived from them were too fragile to be characterized for static and dynamic mechanical properties. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 341–350, 2004 相似文献
3.
4.
We find the existence of a quantum thermal effect, “Hawking absorption.” near the inner horizon of the Kerr–Newman black hole. Redefining the entropy, temperature, angular velocity, and electric potential of the black hole, we give a new formulation of the Bekenstein–Smarr formula. The redefined entropy vanishes for absolute zero temperature of the black hole and hence it is interpreted as the Planck absolute entropy of the KN black hole. 相似文献
5.
6.
Polymorphic transformations of CoMoO4 were studied by means of high temperature X-ray measurements within the temperature range 25–1200°C. On heating phase a obtained from low temperature modification b a new modification a′ was discovered. Phase a obtained by thermal decomposition of solvated α-CoMoO4 shows different behaviour. At 700–930°C depending on the conditions of preparation it transforms irreversibly into still another modification a″. On cooling, a mixture of phases a + a″ is obtained, the presence of a″ being responsible for the explosionwise transition into b, observed around the room temperature. 相似文献
7.
A microfabricated device is reported that has been designed to permit the in situ packing of a section of channel with enzyme immobilised onto controlled pore glass (CPG). It is fabricated from glass and polydimethylsiloxane and to prevent dead volumes, has dedicated channels for packing the reactor. The device has the advantage of being simple in design, the flow through enzyme reactor channel being simply a widened section of the analyte channel. The system is suitable for both hydrodynamic and electro-osmotic pumping, and is designed such that when the packing is exhausted it can be repacked. Controlled pore glass provides a reproducible none swelling, high porosity medium onto which the enzyme could be immobilised. The large particle size meant that it was vital to optimise the immobilisation procedure in order to achieve acceptable enzyme activity. The microfabricated device was developed with two enzymes of different molecular masses; alkaline phosphatase and xanthine oxidase. The pore size of the CPG was found to be very important for xanthine oxidase, where the 697 Å pore size (120-200 mesh) CPG was found to give the highest activity (18-20% activity retained after immobilisation). The microfabricated device was used for the assay of p-nitrophenyl phosphate and hypoxanthine with spectrophotometric detection at 405 and 470 nm, respectively. The limits of detection were 5 and 8 μM, respectively. 相似文献
8.
T. A. Przylibski B. Kozłowska J. Dorda B. Kiełczawa 《Journal of Radioanalytical and Nuclear Chemistry》2002,253(1):11-19
This work characterizes the occurrence of radionuclides 222Rn and 226Ra in the mineralized groundwaters of Gorzanów. The village is situated in the Sudeten Mountains, which are known in Poland for having increased concentrations of the aforesaid radionuclides in their groundwaters. However, in Gorzanów, the measured concentrations of 226Ra were low both in the reservoir rocks and mineralized waters. Consequently, the 222Rn concentration in the groundwaters also turned out to be low. The 226Ra content of these waters should mainly be associated with the dissolution of this nuclide, together with other main ions, at large depths, at slightly enhanced temperature. Radon-222, on the other hand, penetrates into the water during its outflow to the surface, in the zones of intensive friable deformations near fault zones. Thus, in the groundwaters of Gorzanów, the concentrations of these nuclides, subsequent in the uranium series, do not have a common genesis and they are not correlated with each other. 相似文献
9.
Mojumdar S. C. Kozánková J. Chocholoušek J. Majling J. Fábryová D. 《Journal of Thermal Analysis and Calorimetry》2004,78(1):73-82
Fluoroapatite containing glass-ceramics were prepared from Li2O-CaO-CaF2-P2O5-SiO2 system. The glass was melted at 1480°C for 1 h. The object of observation was the preparing crystal phase of fluoroapatite
in amorphous glass matrix. The morphology of lithium disilicate glass-ceramics was studied by SEM. The crystal growth and
thermal properties of fluoroapatite were studied by X-ray diffraction and DTA. The more the content of P2O5, the more the presence of fluoroapatite particles. SEM investigation clearly indicated the phase separation and formation
of a primary crystalline phase of fluoroapatite in the studied glass-ceramics. DTA curves of the fluoroapatite samples exhibit
exothermic effects in the temperature range 337-694°C depending on the composition of the materials. The position of exothermic peak for lithium disilicate on DTA curves moves with increasing specific surfacetowards lower temperatures which points on its preferential surface crystallization. As far as physical qualities are concerned,
mainly color and gloss, the best qualities of all observed materials belong to glass-ceramics with 10% P2O5.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
10.
Robert Pietrzak Mieczysław Kozłowski Helena Wachowska Jan Yperman 《Central European Journal of Chemistry》2004,2(2):278-289
Soluble products obtained from the oxidation of four types of coal, each characterised by different degree of coalification
and different degree of sulphur content, are studied. The coals are oxidised with peracetic acid (PAA) and nitric acid. Analyses
are performed by Atmospheric Pressure-Temperature Programmed Reduction (AP-TPR) and Fourier Transform Infrared Spectroscopy
(FTIR). The soluble products contain much more sulphur than the insoluble products of oxidation. The products obtained from
the reaction with HNO3 contain higher amounts of inorganic sulphur compounds, while those obtained from the reaction with PAA are characterised
by an increased content of organic sulphur species. 相似文献