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1.
Microwave-induced organic reaction enhancement (‘MORE’) chemistry technique (open vessel; controlled microwave energy to stay below the boiling point of the reaction mixture) was used for the N-formylation of aliphatic and aromatic amines and amino heterocycles with aq formic acid (80%) on a multiple gram scale in a few minutes. 相似文献
2.
A four-noded rectangular element with seven degrees of freedom at each node is developed for buckling analysis of laminated plate structures having any number of layers with a constant thickness of individual layers. The displacement model is so chosen that it can explain adequately the parabolic distribution of transverse shear stresses and the non-linearity of in-plane displacements across the thickness. A geometrical stiffness matrix is developed using in-plane stresses. A wide range of plates from thick to thin are examined under uniaxial loading conditions. The results are compared with the existing analytical and numerical solutions. The present formulations confirm its applicability for buckling analysis of a wide range of plates. 相似文献
3.
Raj Gandhi Kamales Kar S. Uma Sankar Abhijit Bandyopadhyay Rahul Basu Pijushpani Bhattacharjee Biswajoy Brahmachari Debrupa Chakraborti M. Chaudhury J. Chaudhury Sandhya Choubey E. J. Chun Atri Desmukhya Anindya Datta Gautam Dutta Sukanta Dutta Anjan Giri Sourendu Gupta Srubabati Goswami Namit Mahajan H. S. Mani A. Mukherjee Biswarup Mukhopadhyaya S. N. Nayak M. Randhawa Subhendu Rakshit Asim K. Ray Amitava Raychaudhuri D. P. Roy Probir Roy Suryadeep Roy Shiv Sethi G. Sigl Arunansu Sil N. Nimai Singh Mark Vagins Urjit Yagnik 《Pramana》2003,60(2):405-409
This is the report of neutrino and astroparticle physics working group at WHEPP-7. Discussions and work on CP violation in
long baseline neutrino experiments, ultra high energy neutrinos, supernova neutrinos and water Cerenkov detectors are discussed. 相似文献
4.
In this paper we present a new method for the solution of optimization problems with PDE constraints. It is based on simultaneous pseudo-time stepping for evolution equations. The new method can be viewed as a continuous reduced SQP method in the sense that it uses a preconditioner derived from that method. The reduced Hessian in the preconditioner is approximated by a pseudo-differential operator, whose symbol can be investigated analytically. We apply our method to a boundary control model problem. The new optimization method needs 3.2-times the overall computational effort of the solution of simulation problem alone. 相似文献
5.
Himansu Sekhar Sahoo S. Mahalakshmi Md. Hedayetullah Mir R. Raghunathan 《Tetrahedron letters》2007,48(5):761-765
A remarkable upfield shift of the pyα protons of complexed 2,2′-bipyridine in [cis-Pd(bpy)(NO3)2] is observed which is considered to originate from the anisotropic influence of suitably positioned coordinated nitrate anions around the Pd(II) centre of the molecule. A typical complexation-induced downfield shift is observed for the NH2 protons in [cis-Pd(en)(NO3)2] where ‘en’ stands for ethylenediamine. 相似文献
6.
The laterally nonsymmetric aza cryptand synthesized by condensing tris(2-aminoethyl)amine (tren) with tris[2-[(3-(oxomethyl)phenyl)oxy]ethyl]mine readily forms mononuclear inclusion complexes with both transition- and main-group-metal ions. The fluorophore 7-nitrobenz-2-oxa-1,3-diazole is attached to one of the secondary amines, to give an integrated fluorophore-receptor configuration. The fluorophoric system does not show any appreciable emission when excited due to an efficient photoinduced intramolecular electron transfer (PET) from the nitrogen lone pair. When a metal ion enters the cavity, the PET is blocked, causing recovery of fluorescence; Cd(II) gives the highest quantum yield. The fluorophore, with pi-accepting ability, drastically alters the binding property of the cryptand. With perchlorate or tetrafluoroborate salts of Cd(II), the metal ion enters the cavity, causing recovery of fluorescence. However, in the presence of coordinating ions such as Cl-, N3-, and SCN-, the metal ion comes out of the cavity, causing PET to take place once again, and the fluorescence is lost. Thus, translocation of Cd(II) between the inside and outside of the cryptand cavity can lead to a reversible fluorescence on/off situation. 相似文献
7.
Catherine Weetman Amelie Porzelt Prasenjit Bag Franziska Hanusch Shigeyoshi Inoue 《Chemical science》2020,11(18):4817
Main group multiple bonds have proven their ability to act as transition metal mimics in the last few decades. However, catalytic application of these species is still in its infancy. Herein we report the second neutral NHC-stabilised dialumene species by use of a supporting aryl ligand (3). Different to the trans-planar silyl-substituted dialumene (3Si), compound 3 features a trans-bent and twisted geometry. The differences between the two dialumenes are explored computationally (using B3LYP-D3/6-311G(d)) as well as experimentally. A high influence of the ligand''s steric demand on the structural motif is revealed, giving rise to enhanced reactivity of 3 enabled by a higher flexibility in addition to different polarisation of the aluminium centres. As such, facile activation of dihydrogen is now achievable. The influence of ligand choice is further implicated in two different catalytic reactions; not only is the aryl-stabilised dialumene more catalytically active but the resulting product distributions also differ, thus indicating the likelihood of alternate mechanisms simply through a change of supporting ligand.Ligand controlled reactivity: a trans-bent and twisted geometry enables dihydrogen activation and enhanced catalytic activity for NHC-stabilised dialumenes. 相似文献
8.
Ajay K. Bose Subhendu N. Ganguly Maghar S. Manhas Vaidyanathan Srirajan Ashoke Bhattacharjee Sochanchingwung Rumthao Anju H. Sharma 《Tetrahedron letters》2004,45(6):1179-1181
A novel dinitro secondary metabolite, 2-nitro-4-(2′-nitroethenyl)phenol from a marine source, has been prepared via highly accelerated, microwave assisted, nitration reactions using mild reagents. ipso-Substitution of a carboxy group by a nitro group is discussed. 相似文献
9.
Ajay K. Bose Maghar S. Manhas Suhas Pednekar Subhendu N. Ganguly Hoang Dang William He Arun Mandadi 《Tetrahedron letters》2005,46(11):1901-1903
An important stage in process development is kilo scale preparation of the target compound. For this reason, a procedure involving water-based biphasic reaction media has been developed for conducting some exothermic reactions on a large scale. This protocol is illustrated by the energy-efficient and rapid preparation of dihydropyrimidinones by a solvent-free, green chemistry procedure applied to the Biginelli reaction using p-toluenesulfonic acid as catalyst. 相似文献
10.
Reliable N-alkylations of secondary amines have been developed. By using DIAD and TPP (or PS-TPP) a variety of secondary amines can be converted to the corresponding tertiary amines in good to excellent yields with diverse alkylhalides; no formation of quaternary amine salts are observed. These protocols are amenable to combinatorial chemistry libraries, and are also useful for the syntheses of secondary amines by an acid lysis of the cleavable tertiary amino resins. 相似文献